# US 11,078,771 B2 · Identification of cement in subterranean borehole regions using a ratio of capture to inelastic gamma rays > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,078,771 B2 - Document ID: US11078771B2 - Status: Granted - Kind: B2 - Application number: 16/231,655 - Filed: 2018-12-24 - Published: 2019-08-08 - Granted: 2021-08-03 - Earliest claimed: 2014-07-25 - Assignees: Carbo Ceramics Inc. - Applicants: Carbo Ceramics Inc. - Inventors: Xiaogang Han; Harry D. Smith, Jr.; Robert Duenckel; Jeremy Zhang - Web page: https://patentgrep.com/patent/US11078771B2 ## CPC - E21B 43/267: reinforcing fractures by propping - E21B 47/11: using tracers; using radioactivity - E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS ## Abstract Methods are provided for determining the location and height of cement in a subterranean borehole region using pulsed neutron capture (PNC) logging tools. The methods include obtaining a pre-cementing data set, placing in the borehole region a cement slurry that includes a liquid a thermal neutron absorbing material, obtaining a post-cementing data set, comparing the pre-cementing data set and the post-cementing data set to determine the location of the cement, and correlating the location of the cement to a depth measurement of the borehole to determine the location and height of the cement placed in the borehole region. ## Claims ### Claim 1 A method for detecting cement placed in a wellbore comprising: obtaining a pre-cementing data set by: emitting neutron pulses from a first neutron source into a borehole, and detecting in the borehole inelastic gamma rays and capture gamma rays; obtaining a first capture gamma ray count rate and a first inelastic gamma ray count rate ratio from the pre-cementing data set; obtaining a post-cementing data set by: emitting pulses of neutrons from the first neutron source or a second neutron source into the borehole, and detecting in the borehole inelastic gamma rays and capture gamma rays; obtaining a second capture gamma ray count rate and a second inelastic gamma ray count rate ratio from the post-cementing data set; and locating cement by combining the first capture gamma ray count rate, the first inelastic gamma ray count rate, the second capture gamma ray count rate, and the second inelastic gamma ray count rate; and correcting a location of the cement based on a change observed between the first and second inelastic gamma ray count rates by calculating a difference in the first capture gamma ray to inelastic gamma ray count ratio and the second capture gamma ray to inelastic gamma ray count ratio. ### Claim 2 (depends on 1) The method of claim 1, wherein the cement comprises thermal neutron absorbing material comprising gadolinium, boron, or samarium or any combinations thereof. ### Claim 3 (depends on 2) The method of claim 2, wherein the thermal neutron absorbing material comprises from about 0.025 wt % to about 4 wt % based on the total weight of the cement including the thermal neutron absorbing material. ### Claim 4 (depends on 1) The method of claim 1, further comprising: obtaining a first capture gamma ray to inelastic gamma ray count ratio from the first capture gamma ray count rate and the first inelastic gamma ray count rate; and obtaining a second capture gamma ray to inelastic gamma ray count ratio from the second capture gamma ray count rate and the second inelastic gamma ray count rate, wherein detecting the cement comprises indicating a difference between the first capture gamma ray to inelastic gamma ray count ratio and the second capture gamma ray to inelastic gamma ray count ratio, and wherein calculating is independent of any changes in neutron output from the pulsed neutron source. ### Claim 5 (depends on 4) The method of claim 4, wherein the difference between the first capture gamma ray to inelastic gamma ray count ratio and the second capture gamma ray to inelastic gamma ray count ratio is directly related to an amount of cement placed in the borehole region. ### Claim 6 (depends on 1) The method of claim 1, wherein the capture gamma rays are detected in a time window between the neutron pulses. ### Claim 7 (depends on 6) The method of claim 6, wherein the time window begins at least about 200 microseconds after the end of each neutron pulse. ### Claim 8 (depends on 6) The method of claim 6, wherein the time window begins 400 microseconds or more after the end of each neutron pulse. ### Claim 9 A method for detecting cement placed in a subterranean borehole region comprising: obtaining a pre-procedure data set by: emitting neutron pulses from a first neutron source into a borehole and a subterranean formation, and detecting in the borehole inelastic gamma rays and capture gamma rays; obtaining a first capture gamma ray count rate and a first inelastic gamma ray count rate ratio from the pre-procedure data set; mixing cement material with a thermal neutron absorbing material to provide a cement slurry. placing the cement slurry in the subterranean borehole region to generate a cemented wellbore; obtaining a post-procedure data set by: emitting pulses of neutrons from the first neutron source or a second neutron source into the cemented borehole; detecting in the cemented borehole inelastic gamma rays and capture gamma rays; obtaining a second capture gamma ray count rate and a second inelastic gamma ray count rate ratio from the post-procedure data set; and detecting cement by combining the first capture gamma ray count rate, the first inelastic gamma ray count rate, the second capture gamma ray count rate, and the second inelastic gamma ray count rate; wherein a change observed between the first and second inelastic gamma ray count rates is used to make a correction to the detection of the cement caused by changes in the neutron output of the first and/or second neutron sources by calculating a difference between the first capture gamma ray to inelastic gamma ray count ratio and the second capture gamma ray to inelastic gamma ray count ratio. ### Claim 10 (depends on 9) The method of claim 9, further comprising: obtaining a first capture gamma ray to inelastic gamma ray count ratio from the first capture gamma ray count rate and the first inelastic gamma ray count rate; and obtaining a second capture gamma ray to inelastic gamma ray count ratio from the second capture gamma ray count rate and the second inelastic gamma ray count rate, wherein detecting the cement comprises indicating a difference between the first capture gamma ray to inelastic gamma ray count ratio and the second capture gamma ray to inelastic gamma ray count ratio, wherein the calculating is independent of any changes in neutron output from the pulsed neutron source. ### Claim 11 (depends on 9) The method of claim 9, wherein the capture gamma rays are detected in a time window between the neutron pulses. ### Claim 12 (depends on 11) The method of claim 11, wherein the time window begins after the end of each neutron pulse. ### Claim 13 (depends on 12) The method of claim 12, wherein the time window ends 400 microseconds or less after the end of each neutron pulse. ### Claim 14 (depends on 13) The method of claim 13, wherein the difference between the first capture gamma ray to inelastic gamma ray count ratio and the second capture gamma ray to inelastic gamma ray count ratio is directly related to an amount of cement placed in the borehole region.