# US 11,078,600 B2 · Method and apparatus for fabricating a fibre array and structure incorporating a fibre array

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- Number: US 11,078,600 B2
- Document ID: US11078600B2
- Status: Granted
- Kind: B2
- Application number: 16/329,954
- Filed: 2017-08-31
- Published: 2019-06-27
- Granted: 2021-08-03
- Earliest claimed: 2016-09-01
- Assignees: Nottingham Trent University
- Applicants: Nottingham Trent University
- Inventors: Robert Stevens; Joseph Chemmarappally
- Web page: https://patentgrep.com/patent/US11078600B2

## CPC

- D01D 5/0084: {Coating by electro-spinning, i.e. the electro-spun fibres are not removed from the collecting device but remain integral with it, e.g. coating of prostheses}
- B32B 3/26: characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids {(foam layer B32B5/18; layer of synthetic resin characterised by fillers that create voids or cavities B32B27/205); characterised by an apertured layer}
- B32B 3/266: {characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12}
- B32B 7/04: Interconnection of layers
- B32B 7/06: permitting easy separation
- B32B 7/12: using interposed adhesives or interposed materials with bonding properties
- B32B 9/045: {of synthetic resin}
- B32B 27/08: of synthetic resin
- B32B 27/12: next to a fibrous or filamentary layer
- B32B 27/281: {comprising polyimides}
- B32B 27/283: {comprising polysiloxanes}
- B32B 27/302: {comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers}
- B32B 27/32: comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)}
- B32B 27/322: {comprising halogenated polyolefins, e.g. PTFE}
- B32B 27/36: comprising polyesters
- B32B 27/40: comprising polyurethanes
- D01D 5/0076: {characterised by the collecting device, e.g. drum, wheel, endless belt, plate or grid (D01D5/0046 takes precedence)}
- B32B 2274/00: Thermoplastic elastomer material
- B32B 2307/206: Insulating
- B32B 2307/54: Yield strength; Tensile strength
- B32B 2307/546: Flexural strength; Flexion stiffness
- B32B 2307/732: Dimensional properties
- B32B 2457/00: Electrical equipment
- B32B 2457/18: Fuel cells
- D01D: MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM

## Abstract

In a method of electrospinning nanofibres, a non-conductive laminate fibre collection structure (22) is placed on the surface of a conductive collector (18, FIG. 1). The laminate structure has a base layer (26) proximal to the collector and a fibre support layer (24). A pair of spaced first apertures (32) and a second aperture (34) located between them are defined through the fibre support layer (24). A pair of spaced third apertures (38) are defined through the base layer (26), each third aperture being aligned with one of the first apertures to define an opening (40) through the laminate structure. During electro spinning, the fibre is attracted to one of the openings (40) where it forms a bridge across the respective first aperture (32). A charge in the collected fibre builds up until the fibre is repelled and it moves to the nearest lowest potential region which is the second opening on the opposite side of the second aperture (34). The nanofibre takes shortest path from the first opening towards the second opening and so creates a fibre which extends across the second aperture (34). The process is repeated to build up an array of aligned nanofibres extending across the second aperture.

## Claims

### Claim 1

An apparatus for electrospinning at least one array of fibres from an electrospinning fluid, the apparatus comprising:
a) a fibre source;
b) a high voltage supply connectable to the fibre source;
c) a conductive collector surface spaced from the fluid source, the apparatus configured to hold at least part of the conductive collector surface at an electrical potential to create a potential difference between said at least part of the conductive collector surface and the fluid source in use; and
d) a non-conductive laminate fibre collection structure covering at least part of the conductive collector surface, the laminate fibre collection structure including a non-conductive base layer proximal to the conductive collector surface and a non-conductive fibre support layer releasably affixed to the base layer, at least one set of apertures defined in the fibre support and base layers, said at least one set of apertures including a first group of apertures defined through the fibre support layer and a second group of apertures defined through the base layer, the first group of apertures including a pair of first apertures spaced apart from one another and a second aperture located between the pair of spaced first apertures, the second group of apertures including a pair of third apertures spaced apart from one another, each of the third apertures being aligned with a corresponding one of the first apertures to define an opening through the non-conductive laminate collection structure.

### Claim 2 (depends on 1)

The apparatus as claimed in claim 1, wherein the apparatus comprises an arrangement for moving the conductive collector surface and the fluid source relative to one another.

### Claim 3 (depends on 1)

The apparatus as claimed in claim 1, wherein a plurality of said sets of apertures are defined in the laminate fibre support structure.

### Claim 4 (depends on 3)

The apparatus as claimed in claim 3, wherein each set is a discreet cell of apertures.

### Claim 5 (depends on 4)

The apparatus as claimed in claim 4, wherein the cells are spaced apart from one another by a distance which is greater than the spacing between the first apertures in each cell.

### Claim 6 (depends on 3)

The apparatus as claimed in claim 3, wherein at least some adjacent sets share common first and third apertures.

### Claim 7 (depends on 1)

The apparatus as claimed in claim 1, wherein each of the first and third apertures is elongate, having a length greater than its width.

### Claim 8 (depends on 7)

The apparatus as claimed in claim 7, wherein the apparatus comprises an arrangement for moving the conductive collector surface and the fluid source relative to one another, the first and third apertures being aligned lengthways parallel to one another and to the relative direction of movement between the conductive surface and the fibre source.

### Claim 9 (depends on 1)

The apparatus as claimed in claim 1, wherein the, or each, second aperture is elliptical.

### Claim 10 (depends on 9)

The apparatus as claimed in claim 9, wherein each of the first and third apertures is elongate, having a length greater than its width and wherein the major axis of the, or each, second aperture is aligned parallel to the longitudinal extents of the first and third apertures.

### Claim 11 (depends on 1)

A method of electrospinning at least one array of fibres using the apparatus as claimed in claim 1, the method comprising:
a) electrospinning fibres from the fibre source towards the conductive collector surface such that the fibres are collected on the fibre support layer of the laminate fibre collection structure without discharging the collected fibres.

### Claim 12

The method as claimed in clam 11, the method comprising, after electrospinning, separating the fibre support layer from the base layer with the collected fibres supported on the fibre support layer.

### Claim 13 (depends on 12)

The method as claimed in claim 12, the method comprising combining a secondary support layer with the fibre support layer with the collected fibres sandwiched in-between the fibre support layer and the secondary support layer.

### Claim 14 (depends on 13)

The method as claimed in claim 13, wherein the secondary support layer defines a plurality of fourth apertures each fourth aperture corresponding to and aligning with a respective first aperture defined in the fibre support layer.

### Claim 15 (depends on 13)

The method as claimed in claim 13, wherein the secondary support layer defines one or more fifth apertures, each fifth aperture corresponding to and aligning with a respective second aperture defined in the fibre support layer.

### Claim 16 (depends on 13)

The method as claimed in claim 13, wherein the secondary support layer and the fibre support layer each define a substantially identical pattern of apertures, corresponding apertures in the two layers being aligned with one another.

### Claim 17 (depends on 11)

The method as claimed in claim 11, wherein the fibres in the at least one array are predominantly aligned with one another.
