# US 11,078,307 B1 · Process for polymerizing olefins in the gas-phase > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,078,307 B1 - Document ID: US11078307B1 - Status: Granted - Kind: B1 - Application number: 16/967,387 - Filed: 2019-02-04 - Published: 2021-07-15 - Granted: 2021-08-03 - Earliest claimed: 2018-02-07 - Assignees: Basell Polyolefine GmbH - Applicants: Basell Polyolefine GmbH - Inventors: Pietro Baita; Maurizio Dorini; Giulia Mei; Gerhardus Meier; Giuseppe Penzo; Riccardo Rinaldi - Web page: https://patentgrep.com/patent/US11078307B1 ## CPC - C08F 10/02: Ethene - B01J 8/26: with two or more fluidised beds, e.g. reactor and regeneration installations - B01J 8/388: {externally, i.e. the particles leaving the vessel and subsequently re-entering it} - B01J 19/2435: {Loop-type reactors} - C08F 2/001: {Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer (C08F295/00, C08F297/00 take precedence)} - C08F 2/01: characterised by special features of the polymerisation apparatus used - C08F 2/34: Polymerisation in gaseous state - C08F 10/00: Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond - C08F 10/06: Propene - C08L 23/0815: {with aliphatic 1-olefins containing one carbon-to-carbon double bond} - B01J 2208/00176: outside the reactor - B01J 2231/122: Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type - C08L 2207/062: HDPE - C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS - C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06) ## Abstract A gas-phase polymerization reactor for the gas-phase polymerization of olefins including a polymerization zone having a recycle line for (a) withdrawing reaction gas from the reactor, (b) leading the reaction gas through a heat-exchanger for cooling, and (c) feeding the reaction gas back to the reactor, wherein the recycle line has the heat-exchanger, a centrifugal compressor having variable guide vanes, and a butterfly valve, and a related process for preparing an olefin polymer in the gas-phase polymerization reactor. ## Claims ### Claim 1 A gas-phase polymerization reactor for the gas-phase polymerization of olefins comprising: a polymerization zone having a recycle line for (a) withdrawing reaction gas from the reactor, (b) leading the reaction gas through a heat-exchanger for cooling and (c) feeding the reaction gas back to the reactor, wherein the recycle line has the heat-exchanger, a centrifugal compressor comprising variable guide vanes, and a butterfly valve, wherein the variable guide vanes are arranged upstream of the centrifugal compressor and the butterfly valve is arranged downstream of the centrifugal compressor. ### Claim 2 (depends on 1) The reactor of claim 1, wherein the recycle line has a side line, wherein the side line branches off the recycle line at a position between the centrifugal compressor and the butterfly valve and is equipped with a control valve for controlling the flow rate of the branched-off recycle gas in the side lines. ### Claim 3 (depends on 1) The reactor of claim 1, wherein the butterfly valve comprises a rotational disc, which has a smaller area than the cross-section of the recycle line at the location of the butterfly valve. ### Claim 4 (depends on 1) The reactor of claim 1, wherein the butterfly valve is arranged downstream of the heat-exchanger. ### Claim 5 (depends on 1) The reactor of claim 1, wherein the centrifugal compressor is arranged upstream of the heat-exchanger. ### Claim 6 (depends on 1) The reactor of claim 1, wherein the recycle line is further equipped with a cyclone upstream of the centrifugal compressor and the heat-exchanger. ### Claim 7 (depends on 1) The reactor of claim 1, wherein the reactor is a fluidized-bed reactor. ### Claim 8 (depends on 1) The reactor of claim 1, wherein the reactor is a multizone circulating reactor, wherein a first polymerization zone is a riser, wherein growing polyolefin particles flow upwards under fast fluidization or transport conditions, and a second polymerization zone is a downcomer, wherein the growing polyolefin particles flow downward in a densified form, wherein the riser and the downcomer are interconnected and polyolefin particles leaving the riser enter the downcomer and polyolefin particles leaving the downcomer enter the riser, thereby establishing a circulation of polyolefin particles through the riser and the downcomer. ### Claim 9 (depends on 1) The reactor of claim 1, wherein the reactor is part of a reactor cascade. ### Claim 10 (depends on 9) The reactor of claim 9, wherein the reactor cascade comprises a first gas-phase reactor and a subsequent second gas-phase reactor having a side line, wherein the side line branches off the recycle line of the second gas-phase reactor, and serves as transfer line for transferring polyolefin particles from the first gas-phase reactor to the second gas-phase reactor. ### Claim 11 (depends on 1) A process for preparing an olefin polymer comprising: homopolymerizing an olefin or copolymerizing an olefin and one or more other olefins at temperatures of from 20 to 200° C. and pressures of from 0.5 to 10 MPa in the presence of a polymerization catalyst, wherein the polymerization is carried out in the gas-phase polymerization reactor of claim 1. ### Claim 12 (depends on 11) The process of claim 11, wherein the polymerization is carried out at a pre-determined pressure differential across the centrifugal compressor and variations of the recycle gas flow rate are carried out by varying the position of the guide vanes and the position of the butterfly valve. ### Claim 13 (depends on 11) The process of claim 11, wherein the recycle line has a side line, wherein (a) the side line branches off the recycle line at a position between the centrifugal compressor and the butterfly valve and is equipped with a control valve for controlling the flow rate of the branched-off recycle gas in the side line and (b) the pressure in the side line upstream of the control valve is from 0.01 MPa to 0.2 MPa higher than the pressure in the recycle line downstream of the butterfly valve. ### Claim 14 (depends on 11) The process of claim 11, wherein the polymerization is a homopolymerization of ethylene or a copolymerization of ethylene and one or more other olefins selected from the group consisting of 1-butene, 1-hexene and 1-octene or the polymerization is a homopolymerization of propylene or a copolymerization of propylene and one or more other olefins selected from the group consisting of ethylene, 1-butene and 1-hexene. ### Claim 15 (depends on 14) The process of claim 14, wherein the resulting polyolefin is a high density polyethylene having a density determined according to ISO 1183 at 23° C. from 0.945 to 965 g/cm3. ### Claim 16 (depends on 11) The process of claim 11, wherein the recycle line has a side line, wherein the side line branches off the recycle line at a position between the centrifugal compressor and the butterfly valve and is equipped with a control valve for controlling the flow rate of the branched-off recycle gas in the side line. ### Claim 17 (depends on 11) The process of claim 11, wherein the reactor is a fluidized-bed reactor. ### Claim 18 (depends on 11) The process of claim 11, wherein the reactor is a multizone circulating reactor, wherein a first polymerization zone is a riser, wherein growing polyolefin particles flow upwards under fast fluidization or transport conditions, and a second polymerization zone is a downcomer, wherein the growing polyolefin particles flow downward in a densified form, wherein the riser and the downcomer are interconnected, the polyolefin particles leaving the riser enter the downcomer, and the polyolefin particles leaving the downcomer enter the riser, thereby establishing a circulation of polyolefin particles through the riser and the downcomer. ### Claim 19 (depends on 11) The process of claim 11, wherein the reactor is part of a reactor cascade. ### Claim 20 (depends on 19) The process of claim 19, wherein the reactor cascade comprises a first gas-phase reactor and a subsequent second gas-phase reactor having a side line, wherein the side line branches off the recycle line of the second gas-phase reactor and serves as the transfer line for transferring polyolefin particles from the first gas-phase reactor to the second gas-phase reactor.