# US 11,078,096 B2 · Sensor with memory storing calibration information

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- Number: US 11,078,096 B2
- Document ID: US11078096B2
- Status: Granted
- Kind: B2
- Application number: 16/450,249
- Filed: 2019-06-24
- Published: 2019-10-24
- Granted: 2021-08-03
- Earliest claimed: 2015-04-08
- Assignees: Digital Concepts of Missouri, Inc.
- Applicants: Digital Concepts of Missouri, Inc.
- Inventors: Jack Greenwood; Christopher Seay Green; Kenneth W. Law
- Web page: https://patentgrep.com/patent/US11078096B2

## CPC

- C02F 1/66: by neutralisation; pH adjustment (for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58)
- C02F 1/76: with halogens or compounds of halogens {(C02F1/4674 takes precedence)}
- G01N 27/4163: {checking the operation of, or calibrating, the measuring apparatus (G01N27/3274, G01N27/4175 and G01N33/0006 take precedence)}
- G01N 27/4166: {measuring a particular property of an electrolyte}
- C02F 2103/42: from bathing facilities, e.g. swimming pools
- C02F 2209/005: Processes using a programmable logic controller [PLC]
- C02F 2209/02: Temperature
- C02F 2209/04: Oxidation reduction potential [ORP]
- C02F 2209/06: pH
- C02F 2209/10: Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
- C02F 2209/29: Chlorine compounds
- C02F 2209/42: Liquid level
- C02F 2303/04: Disinfection
- G01N 27/4165: {for pH meters}
- G01N 27/4167: {pH (electrodes therefor G01N27/302, G01N27/36)}
- G01N 27/4168: {Oxidation-reduction potential, e.g. for chlorination of water (water analysis G01N33/18)}
- G01N 33/182: {Specific anions in water}
- C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes)
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

A sensor is configured to sense a parameter of an aqueous liquid. The sensor has an analog output port configured to provide an analog signal indicative of a sensed parameter, and a calibration memory device storing individual digital information indicative of a calibration of the sensor. A digital output port provides a digital signal indicative of the digital information. A treatment system and method is matched to the sensor.

## Claims

### Claim 1

A treatment system for treating an aqueous liquid comprising:
a conduit for channeling the aqueous liquid to be treated;
a treatment device in fluid communication with the conduit, the treatment device configured to supply one or more treatments to the aqueous liquid via the conduit for altering the aqueous liquid and having an input port for receiving a treatment signal indicative of an extent to which the treatment device alters the aqueous liquid;
a sensor sensing a first parameter of the aqueous liquid and having an analog output port providing a first analog signal indicative of the sensed first parameter, said sensor sensing a second parameter of the aqueous liquid and providing a second analog signal at the analog output port indicative of the sensed second parameter, said sensor having a calibration memory device storing digital information, said digital information stored in the calibration memory device indicative of a calibration of the first parameter relative to the second parameter, and said sensor having a digital output port providing a digital signal indicative of the digital information stored in the calibration memory device; and
a controller having a digital input port connected to the digital output port of the sensor, said controller receiving the digital signal from the sensor via the digital input port and determining a calibration of the sensor in response to the received digital signal,
said controller having an analog input port connected to the analog output port of the sensor, said controller receiving the first and second analog signals via the analog input port and determining an adjusted first parameter of the aqueous liquid relative to the second parameter based on the received analog signals and based on the calibration of the sensor,
said controller having an output port connected to the treatment device providing the treatment signal to the input port of the treatment device, said treatment device responsive to the treatment signal and configured to control the extent to which the treatment device alters the aqueous liquid as a function of the determined adjusted first parameter.

### Claim 2 (depends on 1)

The treatment system of claim 1 wherein the sensor comprises at least one of:
(a) a chlorine sensor so the first parameter is current signal indicative of a free chlorine of the aqueous liquid,
(b) an ORP sensor so that the first parameter is a voltage signal indicative of free chlorine of the aqueous liquid, or
(c) a pH sensor so that the first parameter is current signal indicative of a pH of the aqueous liquid; and
wherein the sensor further comprises a temperature sensing device so that the second parameter is a signal indicative of a temperature of the aqueous liquid.

### Claim 3 (depends on 2)

The treatment system of claim 2 wherein the sensor comprises a thermistor so that the second parameter is a signal indicative of a resistance of the thermistor which is indicative of a temperature of the aqueous liquid.

### Claim 4

A sensing device comprising a sensor configured to sense a first parameter and a second parameter of a liquid and having an analog output port configured to provide a first analog signal indicative of the sensed first parameter and configured to provide a second analog signal indicative of the sensed second parameter, said sensor having a calibration memory device storing individualized digital information specific to the calibration memory, said individualized digital information stored in the calibration memory device indicative of a calibration of the first parameter relative to the second parameter, and said sensor having a digital output port providing a digital signal indicative of the individualized digital information stored in the calibration memory device.

### Claim 5 (depends on 4)

The device of claim 4 in combination with a treatment system for treating an aqueous liquid, said treatment system comprising:
a conduit for channeling the aqueous liquid to be treated;
a treatment device associated with the conduit for altering the aqueous liquid and having an input port for receiving a treatment signal indicative of an extent to which the treatment device alters the aqueous liquid; and
a controller having a digital input port connected to the digital output port of the sensor, said controller receiving the digital signal via the digital input port and determining a calibration of the sensor,
said controller having an analog input port connected to the analog output port of the sensor, said controller receiving the analog signals via the analog input port and determining the first parameter relative to the second parameter based on the received analog signals and based on the calibration of the sensor,
said controller having an output port connected to the treatment device providing the treatment signal to the input port of the treatment device, said treatment signal configured to control the treatment device as a function of the determined parameter by controlling the extent to which the treatment device alters the aqueous liquid.

### Claim 6 (depends on 4)

The device of claim 4 wherein the liquid is an aqueous liquid and wherein the sensor comprises a thermistor sensing temperature providing the second analog signal and a chlorine sensor providing the first analog signal comprising a gold cathode and a platinum anode, the platinum anode being sealed within a tube comprising a proton exchange membrane, wherein the tube provides a barrier to oxygen and anions from the environment exterior to the tube except as may pass through the tube.

### Claim 7 (depends on 4)

The device of claim 4 wherein the liquid is an aqueous liquid and wherein the sensor comprises a thermistor sensing temperature providing the second analog signal and a pH sensor providing the first analog signal comprising:
(i) a gel-filled reference electrode; and
(ii) a sensing electrode of antimony/antimony oxide or bismuth/bismuth oxide having an electroactive surface sealed within a tube comprising a proton exchange membrane that provides a barrier for the sensing electrode to both oxygen and anions from the environment exterior to the tube.

### Claim 8 (depends on 4)

The device of claim 4 wherein the liquid is an aqueous liquid and wherein the sensor comprises a thermistor sensing temperature providing the second analog signal and a halogen sensor providing the first analog signal comprising a metal anode shielded by a low electrical resistance, water-permeable, oxygen barrier comprising a tube comprising a proton exchange membrane that provides a barrier to both oxygen and anions from the environment exterior to the tube.

### Claim 9 (depends on 4)

The device of claim 4 wherein the liquid is an aqueous liquid and wherein the sensor comprises a total dissolved solids (TDS) sensor comprising: a pair of spaced-apart electrodes configured to be excited by a sine wave voltage; a current amplifier and rectifier electrically responsive to the pair of spaced-apart electrodes configured to generate a voltage indicative of the voltage between the spaced-apart electrodes; a converter electrically responsive to the voltage indicative of the voltage between the spaced-apart electrodes configured to convert the indicative voltage for at least one of display and processing; a display electrically responsive to the converter configured to display a total dissolved solids measurement in aqueous liquid in which the pair of spaced apart electrodes is placed.

### Claim 10 (depends on 4)

The device of claim 4 wherein the liquid is an aqueous liquid and wherein the sensor comprises a thermistor sensing temperature providing the second analog signal and an ORP sensor providing the first analog signal comprising a gold cathode and a platinum anode, the platinum anode being sealed within a tube comprising a proton exchange membrane, wherein the tube provides a barrier to oxygen and anions from the environment exterior to the tube except as may pass through the tube.