Substrate processing apparatus

A substrate processing apparatus, comprising:

• a processing liquid supply mechanism configured to generate a Sulfuric Acid Hydrogen Peroxide Mixture (SPM) liquid by mixing sulfuric acid and hydrogen peroxide and supply the generated SPM liquid to a central zone of a substrate;
• a temperature adjusting unit configured to adjust a temperature of the SPM liquid at a time when the SPM liquid is supplied to the substrate from the processing liquid supply mechanism;
• an acquisition unit configured to acquire temperature information of the SPM liquid on a surface of the substrate;
• and
• a control unit configured to set an adjustment amount of the temperature adjusting unit based on the temperature information acquired by the acquisition unit,
• wherein the temperature adjusting unit adjusts, based on the adjustment amount set by the control unit, the temperature of the SPM liquid at the time when the SPM liquid is supplied to the substrate from the processing liquid supply mechanism, and
• wherein the processing liquid supply mechanism comprises:
• a first path through which the sulfuric acid is flown;
• a second path through which the hydrogen peroxide is flown;
• a mixing unit configured to generate the SPM liquid by mixing the sulfuric acid from the first path and the hydrogen peroxide from the second path at a preset mixing ratio;
• a storage unit configured to store a relationship between a mixing ratio and the temperature of the SPM liquid supplied on the substrate;
• and
• a discharging unit configured to discharge the SPM liquid generated by the mixing unit toward the substrate,
• wherein the temperature adjusting unit serves as the mixing unit and is configured to adjust the temperature of the SPM liquid by varying the mixing ratio based on the temperature information of the SPM liquid acquired by the acquisition unit,
• wherein the acquisition unit is implemented by a temperature sensor configured to measure a temperature distribution of the SPM liquid on the substrate, and
• the control unit is configured to:
• calculate a difference value between a required temperature of the SPM liquid and the temperature of the SPM liquid on the central zone of the substrate based on a temperature distribution characteristic obtained from the acquired temperature information;
• estimate a temperature decrement from the central zone to a periphery zone of the substrate;
• and
• set the preset mixing ratio of the mixing unit based on the calculated difference value, the relationship stored in the storage unit, and the estimated temperature decrement.