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US 11,033,892 B2Granted
Methods for reacting chemical streams with catalysts comprising silica, alumina, and tungsten
AssigneeSaudi Arabian Oil Company
InventorsBrian Hanna, Michele Ostraat
Life of this patent
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Abstract
One or more embodiments presently disclosed is directed to a method for reacting a chemical stream which may include contacting the chemical stream with a catalyst to produce a product stream. The catalyst may include alumina, silica, and a catalytically active compound such as tungsten.
Claims16
A method for reacting a chemical stream, the method comprising:
- contacting the chemical stream with a catalyst to produce a product stream, wherein the chemical stream comprises at least 2-butene and the product stream comprises at least propylene which is the result of both isomerization and metathesis of at least the 2-butene;
- wherein the contacting of the chemical stream with the catalyst is at a temperature of less than 500° C.;
- and
- wherein the catalyst is produced by a method comprising:
- generating an aerosolized flow of catalyst support particles, wherein the catalyst support particles comprise from 0.1 weight percent to less than 5 weight percent alumina and from 95 weight percent to 99.9 weight percent silica based on the total weight of the catalyst support particles;
- heating a catalytically active compound precursor comprising tungsten to produce a catalytically active compound precursor vapor;
- contacting the aerosolized flow of catalyst support particles with the catalytically active compound precursor vapor;
- and
- condensing the catalytically active compound precursor to produce the catalyst comprising a catalytically active compound deposited on surfaces of the catalyst support particles.
6 more elements
A method for reacting a chemical stream, the method comprising:
- contacting the chemical stream with a catalyst to produce a product stream, wherein
- the chemical stream comprises at least 2-butene and the product stream comprises at least propylene which is the result of both isomerization and metathesis of at least the 2-butene of the chemical stream;
- the catalyst comprises a silica and alumina support and less than 5 weight percent tungsten, based on the total weight of the catalyst;
- the tungsten is distributed within the silica and alumina support;
- the contacting of the chemical stream with the catalyst is at a temperature of less than 500° C.;
- and
- the catalyst is produced by a process comprising:
- forming a catalyst precursor mixture comprising a diluent and a catalyst precursor, the catalyst precursor comprising a tungsten precursor, an alumina precursor, and a silica precursor;
- aerosolizing the catalyst precursor mixture;
- drying the aerosolized catalyst precursor mixture to form a dried catalyst precursor;
- and
- reacting the dried catalyst precursor to yield the catalyst, the catalyst comprising a silica or silica and alumina support comprising tungsten distributed within the silica and alumina support, and wherein the weight ratio of alumina to silica is from 0.1:99.9 to less than 5:95.
9 more elements
Dependencies are inferred from the claim text.