# US 11,029,551 B2 · Light control device > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,029,551 B2 - Document ID: US11029551B2 - Status: Granted - Kind: B2 - Application number: 16/791,678 - Filed: 2020-02-14 - Published: 2020-06-11 - Granted: 2021-06-08 - Earliest claimed: 2017-08-15 - Assignees: Toppan Printing Co., Ltd. - Applicants: Toppan Printing Co., Ltd. - Inventors: Tetsushi Yoshida - Web page: https://patentgrep.com/patent/US11029551B2 ## CPC - G02F 1/133365: {Cells in which the active layer comprises a liquid crystalline polymer} - G02F 1/1334: based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals - C09K 19/544: {as dispersing or encapsulating medium around the liquid crystal} - G02F 1/133528: {Polarisers} - G02F 1/13737: {in liquid crystals doped with a pleochroic dye} - G02F 1/13347: {working in reverse mode, i.e. clear in the off-state and scattering in the on-state} - G02F 2203/48: Variable attenuator - G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS - C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE ## Abstract A light control device including a first transparent electrode, a second transparent electrode, a light control layer sandwiched vertically between the first transparent electrode and the second transparent electrode and including a polymer network in which domains each filled with a liquid crystal composition are dispersed, and a pair of polarizing layers sandwiching the light control layer and positioned in a crossed Nicols relationship. The liquid crystal composition includes liquid crystal molecules that change to a vertical orientation upon application of a driving voltage to the light control layer. ## Claims ### Claim 1 A light control device, comprising: a first transparent electrode; a second transparent electrode; a light control layer sandwiched vertically between the first transparent electrode and the second transparent electrode; a first orientation layer formed on a first surface of the light control layer and positioned between the first transparent electrode and the light control layer; a second orientation layer formed on a second surface of the light control layer and positioned between the second transparent electrode and the light control layer; and a pair of polarizing layers sandwiching the light control layer and positioned in a crossed Nicols relationship, wherein the light control layer includes a polymer network and a liquid crystal composition forming a plurality of domains in the polymer network such that at least one of the domains is in contact with at least one of the first and second orientation layers and that the liquid crystal composition includes a plurality of liquid crystal molecules that change to a vertical orientation upon application of a driving voltage to the light control layer, the plurality of domains is dispersed in the polymer network such that the plurality of domains are connected each other through adjacent ones of the domains and that the liquid crystal composition is continuous through the plurality of domains, and the light control layer is formed such that the liquid crystal composition is in a form of the plurality of domains having an average domain diameter in a range of 0.1 μm to 5 μm. ### Claim 2 (depends on 1) The light control device according to claim 1, wherein the liquid crystal molecules in the light control layer without application of the driving voltage have a horizontal orientation perpendicular to the vertical orientation. ### Claim 3 (depends on 1) The light control device according to claim 1, wherein the liquid crystal molecules in the light control layer without application of the driving voltage have a twisted orientation. ### Claim 4 A light control device, comprising: a first transparent electrode; a second transparent electrode; a polarizing layer formed on one of the first and second transparent electrodes; a light control layer sandwiched in a vertical direction between the first transparent electrode and the second transparent electrode; a first orientation layer formed on a first surface of the light control layer and positioned between the first transparent electrode and the light control layer; a second orientation layer formed on a second surface of the light control layer and positioned between the second transparent electrode and the light control layer, wherein the light control layer includes a polymer network and a liquid crystal composition forming a plurality of domains in the polymer network such that at least one of the domains is in contact with at least one of the first and second orientation layers and that the liquid crystal composition includes a plurality of liquid crystal molecules and a dichroic dye, the liquid crystal molecules have an orientation that changes to a horizontal orientation perpendicular to the vertical direction upon application of a driving voltage to the light control layer such that an absorption axis of the dichroic dye intersects with an absorption axis of the polarizing layer, the plurality of domains is dispersed in the polymer network such that the plurality of domains are connected each other through adjacent ones of the domains and that the liquid crystal composition is continuous through the plurality of domains, and the light control layer is formed such that the liquid crystal composition is in a form of the plurality of domains having an average domain diameter in a range of 0.1 μm to 5 μm. ### Claim 5 (depends on 4) The light control device according to claim 4, wherein the liquid crystal molecules in the light control layer without application of the driving voltage have a vertical orientation parallel to the vertical direction. ### Claim 6 (depends on 4) The light control device according to claim 4, wherein the liquid crystal molecules in the light control layer without application of the driving voltage have a hybrid orientation. ### Claim 7 (depends on 1) The light control device according to claim 1, wherein the polymer network includes a liquid crystal polymer. ### Claim 8 (depends on 2) The light control device according to claim 2, wherein the polymer network includes a liquid crystal polymer. ### Claim 9 (depends on 3) The light control device according to claim 3, wherein the polymer network includes a liquid crystal polymer. ### Claim 10 (depends on 1) The light control device according to claim 1, wherein the polymer network includes an optically isotropic liquid crystal polymer. ### Claim 11 (depends on 2) The light control device according to claim 2, wherein the polymer network includes an optically isotropic liquid crystal polymer. ### Claim 12 (depends on 3) The light control device according to claim 3, wherein the polymer network includes an optically isotropic liquid crystal polymer. ### Claim 13 (depends on 1) The light control device according to claim 1, wherein a difference between a maximum refractive index and a minimum refractive index is 0.16 or less among a refractive index of the polymer network, an extraordinary refractive index of the liquid crystal molecules and an ordinary refractive index of the liquid crystal molecules. ### Claim 14 (depends on 2) The light control device according to claim 2, wherein a difference between a maximum refractive index and a minimum refractive index is 0.16 or less among a refractive index of the polymer network, an extraordinary refractive index of the liquid crystal molecules and an ordinary refractive index of the liquid crystal molecules. ### Claim 15 (depends on 3) The light control device according to claim 3, wherein a difference between a maximum refractive index and a minimum refractive index is 0.16 or less among a refractive index of the polymer network, an extraordinary refractive index of the liquid crystal molecules and an ordinary refractive index of the liquid crystal molecules. ### Claim 16 (depends on 1) The light control device according to claim 1, further comprising: a first transparent substrate positioned between the first transparent electrode and one of the pair of polarizing layers; and a second transparent substrate positioned between the second transparent electrode and the other one of the pair of polarizing layers. ### Claim 17 A light control device, comprising: a first transparent electrode; a second transparent electrode; a light control layer sandwiched vertically between the first transparent electrode and the second transparent electrode; a first orientation layer formed on a first surface of the light control layer and positioned between the first transparent electrode and the light control layer; a second orientation layer formed on a second surface of the light control layer and positioned between the second transparent electrode and the light control layer; and a pair of polarizing layers sandwiching the light control layer and positioned in a crossed Nicols relationship, wherein the light control layer includes a polymer network and a liquid crystal composition forming a plurality of domains in the polymer network such that at least one of the domains is in contact with at least one of the first and second orientation layers and that the liquid crystal composition includes a plurality of liquid crystal molecules that change to a vertical orientation upon application of a driving voltage to the light control layer, and the plurality of domains is dispersed in the polymer network such that the plurality of domains are connected each other through adjacent ones of the domains and that the liquid crystal composition is continuous through the plurality of domains, and the light control layer is formed such that a thickness of the light control layer satisfies mλ=Δnd=(ne−no)d and λ/2=Δnd, where m is an integer, λ is a wavelength of light incident on the light control layer 12, ne is an extraordinary refractive index, no is an ordinary refractive index, and d is the thickness of the light control layer. ### Claim 18 (depends on 1) The light control device according to claim 1, wherein the light control layer is formed such that the polymer network includes a liquid crystal polymer and that the light control layer satisfies Δndr≤0.25, where Δn is a refractive index difference of the liquid crystal polymer, d is a thickness of the light control layer, and r is a ratio of the liquid crystal molecules. ### Claim 19 A light control device, comprising: a first transparent electrode; a second transparent electrode; a light control layer sandwiched vertically between the first transparent electrode and the second transparent electrode; a first orientation layer formed on a first surface of the light control layer and positioned between the first transparent electrode and the light control layer; a second orientation layer formed on a second surface of the light control layer and positioned between the second transparent electrode and the light control layer; and a pair of polarizing layers sandwiching the light control layer and positioned in a crossed Nicols relationship, wherein the light control layer includes a polymer network and a liquid crystal composition forming a plurality of domains in the polymer network such that at least one of the domains is in contact with at least one of the first and second orientation layers and that the liquid crystal composition includes a plurality of liquid crystal molecules that change to a vertical orientation upon application of a driving voltage to the light control layer, and the plurality of domains is dispersed in the polymer network such that the plurality of domains are connected each other through adjacent ones of the domains and that the liquid crystal composition is continuous through the plurality of domains, and the light control layer is formed such that the polymer network includes a liquid crystal polymer, and that a difference between a maximum refractive index and a minimum refractive index is 0.16 or less among a refractive index of the polymer network, an extraordinary refractive index of the liquid crystal molecules and an ordinary refractive index of the liquid crystal molecules. ### Claim 20 (depends on 1) The light control device according to claim 1, wherein the light control layer is formed such that the liquid crystal composition is in a form of the plurality of domains having an average domain diameter in a range of 0.2 μm to 3 μm.