# US 11,029,086 B2 · Method and apparatus for reducing process disturbances during pressurization of an adsorber in an air separation unit

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- Number: US 11,029,086 B2
- Document ID: US11029086B2
- Status: Granted
- Kind: B2
- Application number: 16/229,473
- Filed: 2018-12-21
- Published: 2020-06-25
- Granted: 2021-06-08
- Earliest claimed: 2018-12-21
- Assignees: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
- Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
- Inventors: Paul Kong; Minh Huy Pham
- Web page: https://patentgrep.com/patent/US11029086B2

## CPC

- F25J 3/04181: {Regenerating the adsorbents}
- B01D 53/04: with stationary adsorbents {(B01D53/025 takes precedence)}
- B01D 53/0423: {Beds in columns}
- B01D 53/047: Pressure swing adsorption
- B01D 53/053: with storage or buffer vessel
- F25J 3/04018: {of main feed air}
- F25J 3/04024: {of purified feed air, so-called boosted air}
- B01D 2256/10: Nitrogen
- B01D 2256/12: Oxygen
- B01D 2257/504: Carbon dioxide
- B01D 2257/80: Water
- B01D 2258/06: Polluted air
- B01D 2259/40013: Pressurization
- F25J 2205/72: Pressurising or depressurising the adsorption vessel
- F25J 2245/40: the recycled stream being air
- F25J 2290/62: Details of storing a fluid in a tank
- Y02C 20/40: of CO2
- F25J: LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS {OR LIQUEFIED GASEOUS} MIXTURES BY PRESSURE AND COLD TREATMENT {OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE (cryogenic pumps F04B37/08; gas storage vessels, gas holders F17; filing vessels with, or discharging from vessels, compressed, liquefied or solidified gases F17C; refrigeration machines, plants, or systems F25B)}
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- Y02C: CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]

## Abstract

A method for reducing process disturbances during pressurization of an adsorber in an air separation unit is provided, in which the air separation unit includes a front end purification unit and an air buffer tank. In one embodiment, the method can include the steps of: pressurizing a first adsorber while a second adsorber operates in an adsorption cycle, wherein the step of pressurizing the first adsorber further includes the steps of withdrawing a pressurized air stream from the air buffer tank and introducing the pressurized air stream to the first adsorber until the first adsorber is at a target pressure, wherein the air buffer tank is in fluid communication with the booster air compressor, wherein the method further includes the step of continually sending a first portion of air flow from the booster air compressor to the air buffer tank and continually sending a second portion of air flow from the booster air compressor to a system of columns within a cold box for rectification therein.

## Claims

### Claim 1

A method for reducing process disturbances during pressurization of an adsorber in an air separation unit, wherein the air separation unit comprises a front end purification unit, a main air compressor, a cold box having a main heat exchanger and a distillation column system disposed therein, a booster air compressor, and an air buffer tank, wherein the front end purification unit comprises a first adsorber and a second adsorber, the method comprising the steps of:
pressurizing the first adsorber while the second adsorber operates in an adsorption cycle, wherein the step of pressurizing the first adsorber further comprises the steps of withdrawing a pressurized air stream from the air buffer tank and introducing the pressurized air stream to the first adsorber until the first adsorber is at a target pressure,
wherein the air buffer tank is in fluid communication with the booster air compressor, wherein the method further comprises the step of continually sending a first portion of air flow from the booster air compressor to the air buffer tank and continually sending a second portion of air flow from the booster air compressor to the cold box for rectification therein.

### Claim 2 (depends on 1)

The method as claimed in claim 1, wherein the first portion of air flow from the booster air compressor is between 0.3% to 1% of total air flowing into the booster air compressor.

### Claim 3

A method for reducing process disturbances during pressurization of an adsorber in an air separation unit, wherein the air separation unit comprises a front end purification unit, a main air compressor, a cold box having a main heat exchanger and a distillation column system disposed therein, a booster air compressor, and an air buffer tank, wherein the front end purification unit comprises a first adsorber and a second adsorber, the method comprising the steps of:
compressing an air stream in a main air compressor to form a compressed main air stream;
purifying the compressed main air stream in the front end purification unit to remove water and carbon dioxide to form a dry main air stream;
sending a first portion of the dry main air stream to the cold box for cooling and rectification therein;
boosting a second portion of the dry main air stream to a higher pressure PH in the booster air compressor to produce a boosted air stream;
sending a first portion of the boosted air stream to the cold box for cooling and rectification therein; and
sending a second portion of the boosted air stream to the air buffer tank,
wherein each of the adsorbers of the front end purification unit undergoes a processing cycle comprising a regeneration cycle, a pressurization cycle, and an adsorption cycle,
wherein during the pressurization cycle, a pressurized air stream is withdrawn from the air buffer tank and introduced to the adsorber that is undergoing pressurization.

### Claim 4 (depends on 3)

The method as claimed in claim 3, wherein the pressurized air stream is only withdrawn from the air buffer tank and introduced to the adsorber during the pressurization cycle.

### Claim 5 (depends on 3)

The method as claimed in claim 3, wherein the flow rate of the second portion of the boosted air stream sent to the air buffer tank is between 0.3% to 1% of the flow rate of the second portion of the dry main air stream boosted by the booster air compressor.

### Claim 6 (depends on 3)

The method as claimed in claim 3, wherein the second portion of the boosted air stream is sent to the air buffer tank at a constant rate during the entire processing cycle of the front end purification unit.

### Claim 7

An apparatus for reducing process disturbances during pressurization of an adsorber in an air separation unit, wherein the apparatus comprises:
a main air compressor configured to compress an air stream to form a compressed main air stream;
a front end purification unit configured to purify the compressed main air stream of water and carbon dioxide to form a dry main air stream, wherein the front end purification unit comprises two adsorbers, wherein each adsorber is configured to operate with an adsorption cycle, a regeneration cycle, and a pressurization cycle;
a booster air compressor in fluid communication with the front end purification unit, wherein the booster air compressor is configured to boost a second portion of the dry main air stream to a higher pressure PH to form a boosted air stream;
an air buffer tank having an air inlet in fluid communication with an outlet of the booster air compressor, wherein the air buffer tank is configured to receive a second portion of the boosted air stream, wherein an outlet of the air buffer tank is in fluid communication with the front end purification unit;
a cold box in fluid communication with the front end purification unit and the outlet of the booster air compressor, wherein the cold box is configured to receive the first portion of the dry main air stream and the first portion of the boosted air stream, wherein the cold box houses a main heat exchanger and a distillation column system, wherein the main heat exchanger is configured to cool the first portion of the dry main air stream and the first portion of the boosted air stream to a cryogenic temperature suitable for rectification of air, wherein the distillation column system is configured to receive the first portion of the dry main air stream and the first portion of the boosted air stream from the main heat exchanger after cooling, wherein the distillation column system is configured to separate the dry main air stream and the boosted air stream into nitrogen and oxygen;
wherein during a pressurization cycle of each adsorber, a valve located between the air buffer tank and the front end purification unit is configured to open to allow for dry air to flow from the air buffer tank to the adsorber,
wherein the valve is configured to close, thereby stopping the flow of dry air to the adsorber, once the pressurization cycle is completed.

### Claim 8 (depends on 7)

The apparatus as claimed in claim 7, further comprising means for regulating the flow rate of the second portion of the boosted air stream sent to the air buffer tank.

### Claim 9 (depends on 8)

The apparatus as claimed in claim 8, wherein the flow rate of the second portion of the boosted air stream sent to the air buffer tank is between 0.3% to 1% of the flow rate of the second portion of the dry main air stream boosted by the booster air compressor.