# US 11,028,342 B2 · Use of an ionic liquid and alcohol blend to modify the rheology of polyethoxylated alcohol sulfates

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- Number: US 11,028,342 B2
- Document ID: US11028342B2
- Status: Granted
- Kind: B2
- Application number: 15/831,500
- Filed: 2017-12-05
- Published: 2019-06-06
- Granted: 2021-06-08
- Earliest claimed: 2017-12-05
- Assignees: Henkel IP & Holding GmbH
- Applicants: Henkel IP & Holding GmbH
- Inventors: Daniel Thomas Piorkowski; David S. Stott, II
- Web page: https://patentgrep.com/patent/US11028342B2

## CPC

- C11D 1/831: of sulfonates with ethers of polyoxyalkylenes without phosphates
- C11D 1/29: Sulfates of polyoxyalkylene ethers
- C11D 3/2006: {Monohydric alcohols}
- C11D 3/30: Amines; Substituted amines {; Quaternized amines}
- C11D 3/3409: {Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates}
- C11D 3/3463: {containing thio sulfate or sulfite groups}
- C11D 17/042: {Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions}
- C11D 1/123: {derived from carboxylic acids, e.g. sulfosuccinates}
- C11D 1/146: {Sulfuric acid esters}
- C11D 1/62: Quaternary ammonium compounds
- C11D 1/72: Ethers of polyoxyalkylene glycols
- C11D 3/201: {linear}
- C11D 3/2013: {fatty or with at least 8 carbon atoms in the alkyl chain}
- C11D 3/2017: {branched}
- C11D 11/0094: {Process for making liquid detergent compositions, e.g. slurries, pastes or gels}
- C11D 2111/12: Soft surfaces, e.g. textile
- C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

## Abstract

In one embodiment, a polyethoxylated alcohol sulfate composition is provided which includes a polyethoxylated alcohol sulfate, such as sodium laureth ether sulfate (SLES), water, an ionic liquid, and an alcohol. The ionic liquid and the alcohol form a synergistic blend, enabling a significant reduction of the viscosity of the polyethoxylated alcohol sulfate composition. Also provided is an embodiment of a method for modifying the rheology of polyethoxylated alcohol sulfate by use of an ionic liquid and alcohol blend. Finally provided is an embodiment of a detergent composition which is prepared by use of the polyethoxylated alcohol sulfate composition described herein, in addition to other commonly known ingredients.

## Claims

### Claim 1

A polyethoxylated alcohol sulfate blend consisting essentially of:
sodium laureth ether sulfate (SLES),
ethanol,
tris(2-hydroxyethyl) methyl-ammonium methyl sulfate, and
water;
wherein the sodium laureth ether sulfate is present in an amount ranging from about 20% to about 80% by weight of the blend,
wherein the ethanol is present with the tris(2-hydroxyethyl) methyl-ammonium methylsulfate in a weight ratio of about 6:12 to about 6:18, and
wherein the blend does not include any component other than the sodium laureth ether sulfate, the water, the ethanol, and the tris(2-hydroxyethyl) methyl-ammonium methyl sulfate.

### Claim 2 (depends on 1)

The polyethoxylated alcohol sulfate blend according to claim 1, wherein the sodium laureth ether sulfate (SLES) and water have a weight ratio of 7:3.

### Claim 3 (depends on 1)

A detergent composition comprising the polyethoxylated alcohol sulfate blend according to claim 1.

### Claim 4 (depends on 3)

The detergent composition according to claim 3, wherein the detergent composition is enclosed in a pouch made of a water-soluble polymer film.

### Claim 5 (depends on 1)

The polyethoxylated alcohol sulfate blend according to claim 1, wherein the sodium laureth ether sulfate is present in an amount of about 60% by weight of the blend.

### Claim 6 (depends on 5)

The polyethoxylated alcohol sulfate blend according to claim 5, wherein the ethanol is present with the tris(2-hydroxyethyl) methyl-ammonium methylsulfate in a weight ratio of about 6:12.

### Claim 7 (depends on 5)

The polyethoxylated alcohol sulfate blend according to claim 5, wherein the ethanol is present with the tris(2-hydroxyethyl) methyl-ammonium methylsulfate in a weight ratio of about 6:18.

### Claim 8 (depends on 1)

The polyethoxylated alcohol sulfate blend according to claim 1, wherein the ethanol is present with the tris(2-hydroxyethyl) methyl-ammonium methylsulfate in a weight ratio of about 6:12.

### Claim 9 (depends on 1)

The polyethoxylated alcohol sulfate blend according to claim 1, wherein the ethanol is present with the tris(2-hydroxyethyl) methyl-ammonium methylsulfate in a weight ratio of about 6:18.

### Claim 10 (depends on 3)

The detergent composition according to claim 3, wherein the sodium laureth ether sulfate is present in the blend in an amount of about 60% by weight of the blend.

### Claim 11 (depends on 10)

The detergent composition according to claim 10, wherein the ethanol is present with the tris(2-hydroxyethyl) methyl-ammonium methylsulfate in a weight ratio of about 6:12.

### Claim 12 (depends on 10)

The detergent composition according to claim 10, wherein the ethanol is present with the tris(2-hydroxyethyl) methyl-ammonium methylsulfate in a weight ratio of about 6:18.

### Claim 13 (depends on 3)

The detergent composition according to claim 3, wherein the ethanol is present with the tris(2-hydroxyethyl) methyl-ammonium methylsulfate in a weight ratio of about 6:12.

### Claim 14 (depends on 3)

The detergent composition according to claim 3, wherein the ethanol is present with the tris(2-hydroxyethyl) methyl-ammonium methylsulfate in a weight ratio of about 6:18.

### Claim 15 (depends on 2)

A detergent composition comprising the polyethoxylated alcohol sulfate blend according to claim 2 that is enclosed in a pouch made of a water-soluble polymer film.

### Claim 16 (depends on 5)

A detergent composition comprising the polyethoxylated alcohol sulfate blend according to claim 5 that is enclosed in a pouch made of a water-soluble polymer film.

### Claim 17 (depends on 6)

A detergent composition comprising the polyethoxylated alcohol sulfate blend according to claim 6 that is enclosed in a pouch made of a water-soluble polymer film.

### Claim 18 (depends on 7)

A detergent composition comprising the polyethoxylated alcohol sulfate blend according to claim 7 that is enclosed in a pouch made of a water-soluble polymer film.

### Claim 19 (depends on 8)

A detergent composition comprising the polyethoxylated alcohol sulfate blend according to claim 8 that is enclosed in a pouch made of a water-soluble polymer film.

### Claim 20 (depends on 9)

A detergent composition comprising the polyethoxylated alcohol sulfate blend according to claim 9 that is enclosed in a pouch made of a water-soluble polymer film.
