# US 11,028,331 B2 · Process for recovering hydrocarbon from hydroprocessed gaseous stream

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- Number: US 11,028,331 B2
- Document ID: US11028331B2
- Status: Granted
- Kind: B2
- Application number: 16/662,142
- Filed: 2019-10-24
- Published: 2020-04-30
- Granted: 2021-06-08
- Earliest claimed: 2018-10-26
- Assignees: Uop LLC
- Applicants: Uop LLC
- Inventors: Richard K. Hoehn; Olga I. Griswold
- Web page: https://patentgrep.com/patent/US11028331B2

## CPC

- C10G 67/14: including at least two different refining steps in the absence of hydrogen
- C10G 2300/202: Heteroatoms content, i.e. S, N, O, P
- C10G 2300/207: Acid gases, e.g. H2S, COS, SO2, HCN
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

## Abstract

A process for recovery of C5+ hydrocarbons from a stripper gaseous hydroprocessed stream by contacting it with a stripper liquid stream. The stripper liquid stream absorbs C5+ hydrocarbons predominantly over other hydrocarbons thereby increasing C5+ yield and enabling the stripper gaseous stream to meet hydrocarbon limits. The rich absorbent stream may be sent to recovery with the stripper liquid from whence it came.

## Claims

### Claim 1

A process for recovering hydrocarbons comprising:
hydroprocessing a hydrocarbon feed stream in a hydroprocessing reactor to provide a hydroprocessed effluent stream;
stripping a hydroprocessed stream taken from said hydroprocessed effluent stream to provide a stripper gaseous stream and a stripped liquid stream; and
absorbing C5+ hydrocarbons from said stripper gaseous stream by contact with an absorbent stream to provide a C5+-rich absorbent stream, wherein said absorbent stream is taken from said stripped liquid stream.

### Claim 2 (depends on 1)

The process of claim 1 wherein C5+ hydrocarbons are a predominant material absorbed from the stripper gaseous stream in the rich absorbent stream.

### Claim 3 (depends on 1)

The process of claim 1 wherein said stripping step comprises condensing a stripper overhead stream and separating said stripper gaseous stream from a stripped liquid overhead stream.

### Claim 4 (depends on 1)

The process of claim 1 further comprising scrubbing acid gases from said stripper gaseous stream by contact with a solvent to provide a scrubbed stripper gaseous stream and absorbing C5+ hydrocarbons from said scrubbed stripper gaseous stream.

### Claim 5 (depends on 3)

The process of claim 3 further comprising washing amines from said scrubbed stripper gaseous stream to provide a washed, scrubbed stripper gaseous stream and absorbing C5+ hydrocarbons from said washed, scrubbed stripper gaseous stream.

### Claim 6 (depends on 1)

The process of claim 1 further comprising adding said rich absorbent stream to said stripped liquid stream.

### Claim 7 (depends on 6)

The process of claim 6 further comprising splitting said stripped liquid stream into an absorbent stream and a remaining stripped liquid stream and said rich absorbent stream is added to said remaining liquid stream.

### Claim 8 (depends on 1)

The process of claim 1 further comprising separating said hydroprocessed effluent stream in a separation section comprising a separator to provide a separated liquid hydroprocessed stream comprising said hydroprocessed stream and a separated gaseous hydroprocessed stream.

### Claim 9 (depends on 8)

The process of claim 8 wherein said separation step further comprises separating a process stream taken from said hydroprocessed effluent stream in a separator to provide a separated gaseous hydroprocessed stream and a separated liquid hydroprocessed stream and taking said hydroprocessed stream from said separated liquid hydroprocessed stream.

### Claim 10 (depends on 9)

The process of claim 9 wherein said separation step further comprises separating said hydroprocessed effluent stream in a hot separator to provide a hot separated liquid hydroprocessed stream and a hot separated gaseous stream comprising said process stream taken from said hydroprocessed effluent stream.

### Claim 11 (depends on 1)

The process of claim 1, further comprising at least one of:
sensing at least one parameter of the process, and
generating or transmitting a signal or data from the sensing.

### Claim 12

A process for recovering hydrocarbons comprising:
hydroprocessing a hydrocarbon feed stream in a hydroprocessing reactor to provide a hydroprocessed effluent stream;
stripping a hydroprocessed stream taken from said hydroprocessed effluent stream to provide a stripper gaseous stream and a stripped liquid stream;
condensing a stripper overhead stream;
separating said stripper gaseous stream from a stripped liquid overhead stream;
scrubbing acid gases from said stripper gaseous stream by contact with a solvent to provide a scrubbed stripper gaseous stream and
absorbing C5+ hydrocarbons from said scrubbed stripper gaseous stream by contact with an absorbent stream taken from said stripped liquid stream to provide a rich absorbent stream.

### Claim 13 (depends on 12)

The process of claim 12 wherein Cb 5+ hydrocarbons are a predominant material absorbed from the stripper gaseous stream in the rich absorbent stream.

### Claim 14 (depends on 12)

The process of claim 12 further comprising washing amines from said scrubbed stripper gaseous stream to provide a washed, scrubbed stripper gaseous stream and absorbing C5+ hydrocarbons from said washed, scrubbed stripper gaseous stream.

### Claim 15 (depends on 12)

The process of claim 12 further comprising adding said rich absorbent stream to said stripped liquid stream.

### Claim 16 (depends on 15)

The process of claim 15 further comprising splitting said stripped liquid stream into an absorbent stream and a remaining stripped liquid stream and said rich absorbent stream is added to said remaining liquid stream.

### Claim 17 (depends on 12)

The process of claim 12 further comprising separating said hydroprocessed effluent stream in a separation section comprising a separator to provide a separated liquid hydroprocessed stream comprising said hydroprocessed stream and a separated gaseous hydroprocessed stream.

### Claim 18 (depends on 17)

The process of claim 17 wherein said separation step further comprises: separating said hydroprocessed effluent stream in a hot separator to provide a hot separated liquid hydroprocessed stream and a hot separated gaseous hydroprocessed stream; separating said hot separated gaseous hydroprocessed stream in a cold separator to provide a cold separated gaseous hydroprocessed stream and a cold separated liquid hydroprocessed stream and taking said hydroprocessed stream from said cold separated liquid hydroprocessed stream.

### Claim 19

A process for recovering hydrocarbons comprising:
hydroprocessing a hydrocarbon feed stream in a hydroprocessing reactor to provide a hydroprocessed effluent stream;
stripping a hydroprocessed stream taken from said hydroprocessed effluent stream to provide a stripper gaseous stream and a stripped liquid stream; and
absorbing C5+ hydrocarbons from said stripper gaseous stream by contact with an absorbent stream taken from said stripped liquid stream to provide a rich absorbent stream, wherein C5+ hydrocarbons are a predominant material absorbed from the stripper gaseous stream in the rich absorbent stream.
