# US 11,028,280 B2 · Composition, cured product, composition stored container, image forming apparatus, and image forming method

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- Number: US 11,028,280 B2
- Document ID: US11028280B2
- Status: Granted
- Kind: B2
- Application number: 16/355,756
- Filed: 2019-03-17
- Published: 2019-09-19
- Granted: 2021-06-08
- Earliest claimed: 2018-03-19
- Assignees: Ricoh Company, Ltd.
- Applicants: Yuuki Matsushita
- Inventors: Yuuki Matsushita
- Web page: https://patentgrep.com/patent/US11028280B2

## CPC

- B41J 11/00214: {using UV radiation}
- B29C 64/112: using individual droplets, e.g. from jetting heads
- B33Y 70/00: Materials specially adapted for additive manufacturing
- B41M 5/0023: {Digital printing methods characterised by the inks used (inks per se C09D11/00)}
- B41M 7/0081: {using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams}
- C09D 11/101: Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
- C09D 11/102: containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D 11/107: from unsaturated acids or derivatives thereof
- C09D 11/30: Inkjet printing inks
- C09D 11/38: characterised by non-macromolecular additives other than solvents, pigments or dyes
- B33Y 80/00: Products made by additive manufacturing
- B41J: TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00)
- B33Y: ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B41M: PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING, (correction of typographical errors B41J; processes for applying transfer pictures or the like B44C1/16; fluid media for correction of typographical errors by coating C09D10/00; printing textiles D06P)
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)

## Abstract

A composition is provided including an acrylamide compound having an ester structure and a molecular weight of 150 to 200, and a polysilane as a polymerization initiator.

## Claims

### Claim 1

A composition comprising:
an acrylamide compound having an ester structure and a molecular weight of 150 to 200; and
a polysilane as a polymerization initiator,
wherein the polysilane comprises the following structure (1) or (2):
where n represents an integer of 2 to 100, and R represents a straight or branched alkyl group.

### Claim 2 (depends on 1)

The composition according to claim 1, wherein acrylamide compound having an ester structure comprises a straight or branched alkyl ester group having 1 to 4 carbon atoms.

### Claim 3 (depends on 1)

The composition according to claim 1, wherein the acrylamide compound having an ester structure is represented by the following general formula (1) or (2):
CH2═CH—CO—N(R1)—R2—CO—O—R3 general formula (1)
where R1 represents hydrogen atom or a straight or branched alkyl group having 1 to 4 carbon atoms, R2 represents a straight or branched alkylene group having 1 to 4 carbon atoms, R3 represents a straight or branched alkyl group having 1 to 4 carbon atoms, and a total number of carbon atoms in R1, R2, and R3 is 2 to 6;
where a ring X represents a ring structure having 2 to 5 carbon atoms and a nitrogen atom, R4 represents a single bond or a straight or branched alkylene group having 1 to 3 carbon atoms, and R5 represents a straight or branched alkyl group having 1 to 3 carbon atoms, and a total number of carbon atoms in the ring X, R4, and R5 is 3 to 6.

### Claim 4 (depends on 3)

The composition according to claim 3, wherein the acrylamide compound having an ester structure is represented by general formula (1), and R3 represents an alkyl group having 1 to 2 carbon atoms.

### Claim 5 (depends on 1)

The composition according to claim 1, wherein the polysilane has a weight average molecular weight of 500 to 100,000.

### Claim 6 (depends on 1)

A cured product obtained by curing the composition according to claim 1.

### Claim 7 (depends on 1)

A composition stored container comprising:
a container; and
the composition according to claim 1 stored in the container.

### Claim 8 (depends on 7)

An image forming apparatus comprising:
the composition stored container according to claim 7;
a discharging device to discharge the composition contained in the container; and
an irradiator to irradiate the discharged composition with an active energy ray.

### Claim 9 (depends on 1)

An image forming method comprising:
discharging the composition according to claim 1; and
irradiating the discharged composition with an active energy ray to cure the composition.
