# US 11,027,972 B2 · Process comprising exothermal catalytic reaction of a synthesis gas and related plant > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,027,972 B2 - Document ID: US11027972B2 - Status: Granted - Kind: B2 - Application number: 16/482,553 - Filed: 2018-01-31 - Published: 2020-01-30 - Granted: 2021-06-08 - Earliest claimed: 2017-02-14 - Assignees: Casale SA - Applicants: Casale SA - Inventors: Pietro Moreo; Fabio Sassi - Web page: https://patentgrep.com/patent/US11027972B2 ## CPC - C01B 3/38: using catalysts - C01B 3/384: with external heating of the catalyst - B01J 19/0013: {Controlling the temperature of the process} - B01J 19/245: {placed in series} - C07C 29/1518: {one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis} - B01J 2219/00024: Revamping, retrofitting or modernisation of existing plants - B01J 2219/00092: Tubes - B01J 2219/00128: by evaporation of reactants - C01B 2203/0233: the reforming step being a steam reforming step - C01B 2203/0244: the reforming step being an autothermal reforming step, e.g. secondary reforming processes - C01B 2203/0495: the impurity being water - C01B 2203/061: Methanol production - C01B 2203/0844: the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294 - C01B 2203/0883: by indirect heat exchange - C01B 2203/0894: Generation of steam - C01B 2203/1276: Mixing of different feed components - C01B 2203/1294: Evaporation by heat exchange with hot process stream - C01B 2203/143: Three or more reforming, decomposition or partial oxidation steps in series - C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C} - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS - C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS ## Abstract A synthesis process comprising steam reforming a gaseous hydrocarbon feedstock; exothermically reacting the resulting synthesis gas; removing heat from said exothermal reaction by producing steam; using said steam as heat input to the steam reforming, wherein the steam reforming comprises: a) forming a mixture containing steam and hydrocarbons by at least the step of adding a first stream of water to the hydrocarbon feedstock; b) heating said mixture by indirect heat exchange with synthesis gas; c) reforming said mixture after said heating step b). ## Claims ### Claim 1 A synthesis process, comprising: steam reforming a gaseous hydrocarbon feedstock, thereby obtaining a synthesis gas; exothermically reacting said synthesis gas in the presence of a catalyst, thereby obtaining a synthesis product; removing heat from said exothermal reaction by producing steam, wherein at least part of said steam provides a heat input to the reforming of said hydrocarbon feedstock; wherein the steam reforming of the hydrocarbon feedstock includes: a) forming a mixture containing steam and hydrocarbons by at least a step of adding a first stream of water to the hydrocarbon feedstock in a saturating tower, said stream of water being pre-heated by indirect heat exchange, prior to admission into said tower, with at least a portion of the steam produced by removing heat from the exothermal synthesis reaction; b) heating said mixture by indirect heat exchange with at least part of said synthesis gas; and c) reforming said mixture after said heating step b). ### Claim 2 (depends on 1) The synthesis process of claim 1, wherein the formation of said mixture further includes mixing an effluent of said tower with a second stream of water, and said second stream is pre-heated by indirect heat exchange with said synthesis gas. ### Claim 3 (depends on 2) The synthesis process of claim 2, wherein a stream of synthesis gas transfers heat to said mixture during the heating step b), and the synthesis gas effluent of said heating step b) transfers heat to said second stream of water. ### Claim 4 (depends on 1) The synthesis process of claim 1, wherein excess water is drawn off from the saturating tower during said step a) and at least a portion of said excess water is recirculated into the tower, said portion being pre-heated, prior to admission into said tower, with a portion of the steam produced by removing heat from the exothermal synthesis reaction. ### Claim 5 (depends on 2) The synthesis process of claim 2, wherein excess water is drawn off from the tower during said step a) and said second stream of water includes a portion of said excess water. ### Claim 6 (depends on 1) The synthesis process of claim 1, wherein excess water is drawn off from the step b) and at least a portion of said excess water is added to the hydrocarbon feedstock in said saturating tower. ### Claim 7 (depends on 1) The synthesis process of claim 1, wherein said synthesis product includes methanol. ### Claim 8 (depends on 7) The synthesis process of claim 7, wherein the step of reacting the synthesis gas includes an isothermal reactive step, providing a methanol-containing stream, and wherein a stream of boiling water acts as cooling medium that removes heat of the exothermic reaction of the synthesis gas and generates said steam. ### Claim 9 (depends on 8) The synthesis process of claim 8, wherein said step of reacting the synthesis gas further includes subjecting said methanol-containing stream to a further isothermal reactive step, providing said methanol product, and wherein a stream of fresh synthesis gas acts as cooling medium.