Dispersant for calcium sulphate-based compositions
AssigneeSika Technology AG
InventorsJürg Weidmann, Christina Hampel, Jörg Zimmermann
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Abstract
The present invention relates to the use of a copolymer as a dispersant for binder compositions based on calcium sulfate, the copolymer having a polymer backbone and sidechains bound thereto, and at least one ionizable monomeric unit M1 and at least one sidechain-carrying monomeric unit M2, characterized in that the copolymer has, in a direction along the polymer backbone, a non-random distribution of the monomeric units M1 and/or of the monomeric units M2.
Claims10
A method comprising introducing a copolymer as a dispersant into a binder composition that includes at least one mineral binder, the binder composition being based on calcium sulfate, wherein
- the copolymer comprises a polymer backbone and side chains bonded thereto and there are at least one ionizable monomer unit M1 and at least one side chain-bearing monomer unit M2,
- the copolymer has a nonrandom distribution of the monomer units Ml and/or the monomer units M2 in a direction along the polymer backbone in that the copolymer has a gradient structure in at least one section AA in a direction along the polymer backbone with respect to the ionizable monomer unit M1 and/or with respect to the side chain-bearing monomer unit M2, and the copolymer, in addition to the at least one section AA having a gradient structure, has a further section AB, wherein there is essentially a constant local concentration of the monomers and/or a statistical or random distribution of the monomers over the entire section AB,
- a proportion of the calcium sulfate, based on all the mineral binder in the binder composition, is at least 30% by weight,
- a molar ratio of the monomer units Ml to the monomer units M2 in the copolymer is in the range of 0.5-6,
- the ionizable monomer unit M1 in the copolymer has a structure of the formula I
- the side chain-bearing monomer unit M2 includes a structure of the formula II
- where
- R1 forms a ring together with R4 to give —CO—O—CO—, or R1, in each case independently, is —COOM and/or —SO2-0M, and R4, in each case independently, is H, —COOM or an alkyl group having 1 to 5 carbon atoms;
- M, independently of one another, represents H+, an alkali metal ion, an alkaline earth metal ion, a di- or trivalent metal ion, an ammonium ion or an organic ammonium group;
- R2, R3, R5 and R6, in each case independently, are H or an alkyl group having 1 to 5 carbon atoms;
- R7, in each case independently, is H, —COOM or an alkyl group having 1 to 5 carbon atoms;
- m=0, 1 or 2;
- p=0 or 1;
- X, in each case independently, is —O— or —NH—;
- R8 is a group of the formula -[AO]n—Ra, where A=C2− to C4-alkylene, Ra is H, a Cl- to C20-alkyl group, -cycloalkyl group or -alkylaryl group;
- and
- n=2-250.
Dependencies are inferred from the claim text.