A system for producing benzene and xylenes comprising a pyrolysis unit, a hydroprocessing unit, an optional first aromatics separating unit, a reforming unit, a second aromatics separating unit, a third aromatics separating unit, and a disproportionation and transalkylation unit;
- wherein the pyrolysis unit is configured to receive a plastic waste and to produce a hydrocarbon liquid stream and a pyrolysis gas stream;
- wherein the hydroprocessing unit comprises a hydroprocessing catalyst, wherein the hydroprocessing unit is configured to receive hydrogen and at least a portion of the hydrocarbon liquid stream and to produce a hydrocarbon product and a first gas stream, wherein the hydrocarbon product comprises C5+ hydrocarbons, wherein the hydrocarbon product comprises equal to or greater than about 90 wt. % C10− hydrocarbons, based on the total weight of the hydrocarbon product, and wherein the hydrocarbon product comprises less than about 1 wt. % olefins, based on the total weight of the hydrocarbon product;
- wherein the optional first aromatics separating unit is configured to receive at least a portion of the hydrocarbon product and to produce a saturated hydrocarbons stream and a first aromatics stream, wherein the saturated hydrocarbons stream comprises C5+ saturated hydrocarbons, and wherein the first aromatics stream comprises C6+ aromatic hydrocarbons;
- wherein the reforming unit comprises a reforming catalyst, wherein the reforming unit is configured to receive at least a portion of the hydrocarbon product and/or at least a portion of the saturated hydrocarbons stream and to produce a reforming unit product, a second gas stream, and a hydrogen stream, wherein an amount of C6 to C8 aromatic hydrocarbons in the reforming unit product is greater than an amount of C6 to C8 aromatic hydrocarbons in the saturated hydrocarbons stream;
- wherein the second aromatics separating unit is configured to receive at least a portion of the reforming unit product and to produce a non-aromatics recycle stream and a second aromatics stream, and wherein the second aromatics stream comprises C6+ aromatic hydrocarbons;
- wherein the third aromatics separating unit is configured to receive at least a portion of the first aromatics stream and/or the second aromatics stream and to produce a first C6 aromatics stream, a C7 aromatics stream, a C8 aromatics stream, a C9 aromatics stream, a C10 aromatics stream, and a C11+ aromatics stream, wherein the first C6 aromatics stream comprises benzene, wherein the C7 aromatics stream comprises toluene, wherein the C8 aromatics stream comprises xylenes and ethylbenzene, and wherein at least a portion of the C11+ aromatics stream is recycled to the hydroprocessing unit;
- and
- wherein the disproportionation and transalkylation unit comprises a disproportionation and transalkylation catalyst, wherein the disproportionation and transalkylation unit is configured to receive at least a portion of the C7 aromatics stream, at least a portion of the C9 aromatics stream, at least a portion of the C10 aromatics stream, or combinations thereof and to produce a third aromatics stream, wherein the third aromatics stream comprises benzene and xylenes, and wherein a C9+ aromatic hydrocarbons content of the combined first C6 aromatics stream, C8 aromatics stream, and third aromatics stream is less than about 5 wt. %, based on the weight of the combined first C6 aromatics stream, C8 aromatics stream, and third aromatics stream.