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US 10,975,235 B2Granted
Method for producing amino methylated bead polymerizates
AssigneeLANXESS Deutschland GmbH
InventorsBernd Koop, Areski Rezkallah, Georg Martin, Pierre Vanhoorne, Reinhold Klipper, Sladjana Baljak
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Abstract
The invention relates to a process for preparing aminomethylated bead polymers using condensed formaldehydes and carbonyl halides.
Claims18
A process for preparing aminomethylated bead polymers, the process comprising:
- a) converting monomer droplets comprising at least one monovinylaromatic compound, at least one polyvinylaromatic compound, and at least one initiator to a bead polymer,
- b) contacting the bead polymer with:
- at least one compound of the formula (I) or salts thereof
- where R1=C1-C3-alkyl or H, and
- at least one compound of the formula (II) or the cyclic condensates thereof
- where n=2 to 100,
- in a reaction mixture comprising at least one Friedel-Crafts catalyst, at least one aliphatic saturated or unsaturated carbonyl halide, and additional aliphatic saturated or unsaturated carboxylic acids,
- to give a phthalimidomethylated bead polymer, and
- c) hydrolyzing the phthalimidomethylated bead polymer to give an aminomethylated bead polymer.
6 more elements
Dependencies are inferred from the claim text.