Process to remove olefins from light hydrocarbon stream by mercaptanization followed by MEROX removal of mercaptans from the separated stream
AssigneeSaudi Arabian Oil Company
InventorOmer Refa Koseoglu
Life of this patent
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Abstract
A light naphtha feedstock containing olefins is introduced with hydrogen sulfide into a mercaptanization zone for conversion of the olefins into a mercaptan stream that is substantially free of olefins, after which the mercaptans are sent with an alkali caustic solution into a mercaptan oxidation treatment unit (MEROX) to produce a spent caustic stream and sweet light naphtha product stream that is substantially free of olefins and of mercaptans. Disulfide oils are produced from the wet air oxidation of the spent caustic, and the disulfide oils can be further processed to provide high purity olefin building blocks.
Claims7
A process for treating an olefin-containing light naphtha feedstock, the process comprising:
- a. introducing the light naphtha feedstock containing olefins, an internally-produced mercaptan stream and an alkali caustic solution into a mercaptan oxidation treatment zone to produce a spent caustic and alkali metal alkane thiolate mixture stream and sweet light naphtha product stream that is substantially mercaptan free and comprises olefins;
- b. passing the spent caustic and alkali metal alkane thiolate mixture stream, catalyst, and air into a wet air oxidation zone to produce a regenerated spent caustic stream and a disulfide oils product stream;
- c. recovering the disulfide oils product stream;
- d. passing the sweet light naphtha product stream and hydrogen sulfide into a mercaptanization zone containing a catalyst and catalytically reacting hydrogen sulfide with the olefins to produce a treated effluent stream that is substantially free of olefins;
- e. passing the treated effluent stream to a fractionation zone and recovering a sweet light naphtha product stream and the internally-produced mercaptan stream of step (a).
Dependencies are inferred from the claim text.