Olefin polymerization catalyst systems and methods of use thereof

An olefin polymerization catalyst system comprising a procatalyst component selected from metal-ligand complexes of Formula (I):

• wherein M is titanium, zirconium, or hafnium;
• wherein each X is independently a monodentate or polydentate ligand that is neutral, monoanionic, or dianionic, wherein n is an integer, and wherein X and n are chosen in such a way that the metal-ligand complex of Formula (I) is overall neutral;
• wherein each R1 and R10 independently is selected from the group consisting of (C6-C40)aryl, substituted (C6-C40)aryl, (C3-C40)heteroaryl, and substituted (C3-C40)heteroaryl;
• wherein each R2, R3, R4, R7, R8, and R9 independently is selected from a group consisting of hydrogen;
• (C1-C40)hydrocarbyl;
• substituted (C1-C40)hydrocarbyl;
• (C1-C40)heterohydrocarbyl;
• substituted (C1-C40)heterohydrocarbyl;
• halogen;
• and nitro (NO2);
• wherein each R5 and R6 independently is selected from the group consisting of a (C1-C40)alkyl;
• substituted (C1-C40)alkyl;
• [(Si)1—(C+Si)40] substituted organosilyl;
• optionally, two or more of the R1-5 groups are combined together to form a ring structure, with such ring structure having from 5 to 16 atoms in the ring excluding any hydrogen atoms;
• and
• optionally, two or more of the R6-10 groups are combined together to form a ring structure, with such ring structure having from 5 to 16 atoms in the ring excluding any hydrogen atoms.