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US 10,962,522 B2Granted
Method for predicting physical properties of polymers
AssigneeLG Chem, Ltd.
InventorsYoon Ki Hong, Hyuck Ju Kwon, Eun Kyoung Song, Dae Sik Hong, Ye Jin Lee, Joong Soo Kim, Eun Young Shin, Young Suk You, Ki Soo Lee
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Abstract
The present invention relates to a method for predicting the physical properties of polymers. More specifically, the present invention relates to a method for predicting the processability of polymers using a molecular weight distribution curve.
Claims5
A method for manufacturing a pipe comprising:
- polymerizing one or more olefin monomers in a presence of a catalyst,
- forming a polymer resin,
- measuring a molecular weight distribution curve of the polymer resin using a gel permeation chromatography (GPC) at a temperature of 160° C., wherein a log value of a molecular weight MW (log MW) is denoted by x-axis, and a molecular weight distribution to the log value (dwt/dlog MW) is denoted by y-axis;
- dividing a section between 3.0 and 7.0 on the x-axis of the molecular weight distribution curve into four equal parts to obtain an integral value of the molecular weight distribution curve at each section;
- and
- calculating a predicted value of a die swell ratio value from the integral value, and
- manufacturing the pipe using the polymer resin,
- wherein the calculating the predicted value of the die swell ratio is performed according to following Equation 1 using the integral value:
- Die swell ratio, PV=(−0.136)*A1+(−0.1152)*A2+(−0.1033)*A3+(−0.181)*A4+13.97 [Equation 1]
- A1 is an integral value of a molecular weight distribution curve in the section where log MW is 3.0 to 4.0,
- A2 is an integral value of a molecular weight distribution curve in the section where log MW is 4.0 to 5.0,
- A3 is an integral value of a molecular weight distribution curve in the section where log MW is 5.0 to 6.0,
- A4 is an integral value of a molecular weight distribution curve in the section where log MW is 6.0 to 7.0, and
- the integral value of A1 to A4 means relative values when an integral value of entire molecular weight distribution curve is 100.
11 more elements
Dependencies are inferred from the claim text.