Back to results
US 10,954,319 B2Granted
Production of a PMMA foam using cross-linking agents, regulators and blowing agents
AssigneeEvonik Operations GmbH
InventorsThomas Richter, Christoph Seipel, Kay Bernhard, Sivakumara K Krishnamoorthy, Sebastian Buehler
Life of this patent
Estimating the term…
Abstract
The present invention relates to novel types of PMMA foams and also to the production thereof. The recipes used in the production process include particularly crosslinkers and chain transfer agents as recipe constituents, mostly in low concentrations, in addition to suitable blowing agents. It was found that, surprisingly, the invention provides a simple-to-produce stable PMMA foam having very good properties.
Claims8
A process for producing a polymethacrylate foam, said process comprising:
- polymerizing at a temperature between 20° C. and 100° C. a composition comprising from 0.01 to 2.0 wt % of an initiator, from 2 to 20 wt % of a blowing agent, and from 75 to 97.9 wt % of a mixture to obtain a polymerized composition, and
- subsequently foaming the polymerized composition at a temperature between 130° C. and 250° C.,
- wherein
- said mixture comprises
- from 79.70 to 99.995 mol % of MMA monomers, polymers, oligomers or a combination of polymers and oligomers of MMA,
- from 0 to 20 mol % of one or more MMA-copolymerizable monomers polymers, oligomers or a combination of polymers and oligomers of the MMA-copolymerizable monomers,
- from 0.002 to 0.5 mol % of crosslinker, and
- from 0.003 to 1.5 mol % of chain transfer agent, and
- a total amount of the polymers, oligomers or combination of polymers and oligomers of MMA and the polymers, oligomers or combination of polymers and oligomers of the MMA-copolymerizable monomers in said mixture is up to 80 wt %,
- wherein the chain transfer agent comprises pentaerythritol tetrathioglycolate.
7 more elements
Dependencies are inferred from the claim text.