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US 10,948,839 B2Granted
Toner having a toner particle with a binder resin containing a copolymer of a styrenic polymerizable monomer, and at least one of an acrylic or methacrylic polymerizable monomer
AssigneeCanon Kabushiki Kaisha
InventorsKeiichiro Tsubaki, Naoya Isono, Yasuaki Murai
Life of this patent
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Abstract
The toner contains a toner particle that has a binder resin, wherein an amount of a tetrahydrofuran THF-insoluble matter A collected when a THF dispersion of the binder resin is passed through a first filter having an average pore diameter of 8 μm, is not more than 10 mass % of the binder resin, and an amount of a THF-insoluble matter B collected when the THF dispersion that has been passed through the first filter is passed through a second filter having an average pore diameter of 0.8 μm, is from 5 mass % to 50 mass % of the binder resin.
Claims2
A toner comprising;
- a toner particle comprising a binder resin, said binder resin containing a copolymer of a crosslinking agent, a styrenic polymerizable monomer, and at least one member selected from the group consisting of acrylic polymerizable monomers and methacrylic polymerizable monomers;
- the crosslinking agent being provided by a Michael addition reaction of a polyvalent mercapto compound represented by formula (2) to a multifunctional (meth)acrylate compound represented by formula (1)
- where R1 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms,
- L1 represents an m-valent linear or branched aliphatic hydrocarbon group optionally having a hydroxy group, or an ether bond-containing m-valent linear or branched aliphatic hydrocarbon group optionally having a hydroxy group, and
- m is an integer of 3 to 6, and
- where L2 represents an alkylene group,
- L3 represents an n-valent linear or branched aliphatic hydrocarbon group optionally having a hydroxy group, or an ether bond-containing n-valent linear or branched aliphatic hydrocarbon group optionally having a hydroxy group, and
- n is an integer from 3 to 6, wherein
- an amount of a tetrahydrofuran-insoluble matter A collected when a tetrahydrofuran dispersion of the binder resin is passed through a first filter having an average pore diameter of 8 μm is not more than 10 mass % of the binder resin, and
- an amount of a tetrahydrofuran-insoluble matter B collected when the tetrahydrofuran dispersion that has been passed through the first filter is passed through a second filter having an average pore diameter of 0.8 μm is 5 to 50 mass % of the binder resin.
7 more elements
Dependencies are inferred from the claim text.