Nitride fluorescent material, method of producing nitride fluorescent material and light emitting device
AssigneeNichia Corporation
InventorsHiroyuki Watanabe, Shoji Hosokawa
Life of this patent
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Abstract
Provided is a method of producing a nitride fluorescent material containing silicon nitride particles containing Eu, at least one alkaline earth metal selected from the group consisting of Mg, Ca, Sr, and Ba, Al, and fluorine in a composition of the silicon nitride particles. The method includes heat treating a raw material mixture containing an Eu source, a source of the alkaline earth metal, an Al source, an Si source, and an alkaline earth metal fluoride containing at least one selected from the group consisting of Mg, Ca, Sr, and Ba, wherein a molar content ratio of fluorine atom to Al is from 0.02 to 0.3.
Claims7
A nitride fluorescent material comprising silicon nitride particles comprising Eu, at least one alkaline earth metal selected from the group consisting of Mg, Ca, Sr, and Ba, Al, and fluorine in a composition of the silicon nitride particles,
- wherein the silicon nitride particles have a needle degree, which is an average of a ratio of major diameter to minor diameter, ranging from 1.4 to 1.8, a volume average particle diameter of 10 μm or more, and a molar content ratio of fluorine atom to Al of 6×10−2 or less,
- wherein the silicon nitride particles have a composition represented by formula (I) below:
- MasSrtEuuSivAlwNxOyFz (I)
- wherein Ma is at least one element selected from the group consisting of Ca, Ba and Mg, and s, t, u, v, w, x, y, and z satisfy 0<s≤1, 0≤t<1, 0<u≤0.04, 0.8≤s+t+u≤1.1, 0.8≤v≤1.2, 0.8≤w≤1.2, 1.8≤v+w≤2.2, 2.5≤3.2, 0≤y≤0.5, 0<z≤0.06, and 2.5≤x+y+z≤3.2.
Dependencies are inferred from the claim text.