Gold-coloured effect pigments having high chroma and high brilliancy, method for the production and use thereof
AssigneeEckart GmbH
InventorsMichael Grüner, Günter Kaupp, Ralph Schneider
Life of this patent
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Abstract
The present invention relates to gold-colored effect pigment including a nonmetallic substrate in platelet form and a coating applied thereto, wherein the coating includes at least one spacer layer. The invention further relates to a process for production of and to the use of the gold-colored effect pigment.
Claims18
A gold-colored effect pigment comprising a nonmetallic substrate in platelet form and a coating applied to the substrate, wherein the coating comprises:
- a) optionally a layer 1 comprising or consisting of at least one of tin oxide, tin hydroxide or tin oxide hydrate,
- b) a layer 2 comprising at least one of metal oxide, metal hydroxide or metal oxide hydrate, where the metal ion comprises or is at least one metal ion selected from the group of metals consisting of Fe, Sn, Ti and Zr, and
- c) a layer 3 comprising at least one of metal oxide, metal hydroxide or metal oxide hydrate, where the metal ion comprises or is at least one metal ion selected from the group of metals consisting of Fe, Sn, Ti and Zr, at least one of layers 2 and 3 comprises at least two different metal ions and at least one of the two different metal ions is an iron ion, and layers 2 and 3 are interrupted by a spacer layer,
- wherein the spacer layer includes connections and cavities and wherein the spacer layer has a standard deviation of a relative height of σRma in a range of 0.2 to 18%, wherein the relative height hRma is defined as a ratio of a height hma to a layer thickness of an overall coating and hma refers to a sum total of a layer thickness of optional layer 1, layer 2 and half of a mean height ha of the spacer layer.
A gold-colored effect pigment comprising a nonmetallic substrate in platelet form and a coating applied to the substrate, wherein the coating comprises
- a) optionally a layer 1 comprising or consisting of at least one of tin oxide, tin hydroxide or tin oxide hydrate,
- b) a layer 2 comprising at least one of metal oxide, metal hydroxide or metal oxide hydrate, where the metal ion comprises or is at least one metal ion selected from the group of metals consisting of Fe, Sn, Ti and Zr, and
- c) a layer 3 comprising at least one of metal oxide, metal hydroxide or metal oxide hydrate, where the metal ion comprises or is at least one metal ion selected from the group of metals consisting of Fe, Sn, Ti and Zr, at least one of layers 2 and 3 comprises at least two different metal ions and at least one of the two different metal ions is an iron ion, and layers 2 and 3 are interrupted by a spacer layer, wherein the spacer layer includes connections and cavities and wherein the spacer layer has a network density of <85%, wherein the network density is defined as the number of connections or spacers per number of lines in %, determined from a grid of parallel lines drawn at 50 nm intervals at a 90° angle from a baseline drawn onto each scanning electron micrograph of a transverse section along the surface of a longer side of the nonmetallic substrate.
Dependencies are inferred from the claim text.