Catalyst composition including novel transition metal compound
AssigneeLG Chem, Ltd.
InventorsIk Je Choe, Seul Ki Kim, Ki Won Han, Eun Jung Lee, Choong Hoon Lee
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Abstract
The present invention relates to a catalyst composition including a transition metal compound represented by the following Formula 1; and one or more of a compound represented by the following Formula 2, a compound represented by the following Formula 3 and a compound represented by the following Formula 4. The catalyst composition according to the present invention has excellent copolymerization properties, and can be usefully used as a catalyst for a polymerization reaction for preparing an olefin-based polymer having a high molecular weight.
Claims12
A catalyst composition, comprising:
- a transition metal compound represented by the following Formula 1;
- and
- one or more of a compound represented by the following Formula 2, a compound represented by the following Formula 3 and a compound represented by the following Formula 4:
- —[Al(R10)—O]a— [Formula 2]
- A(R11)3 [Formula 3]
- [L-H]+[WD4]− or [L]+[WD4]− [Formula 4]
- in Formula 1,
- R1 to R9 are each independently selected from the group consisting of hydrogen, a halogen, an alkyl having 1 to 20 carbon atoms, an alkenyl having 2 to 20 carbon atoms, a cycloalkyl having 3 to 20 carbon atoms, an aryl having 6 to 20 carbon atoms, an arylalkyl having 7 to 20 carbon atoms, an alkylaryl having 7 to 20 carbon atoms, an alkoxy having 1 to 20 carbon atoms, an aryloxy having 6 to 20 carbon atoms, a silyl, and a combination thereof, or two or more adjacent functional groups of R1 to R9 are connected to each other to form an aliphatic ring having 6 to 20 carbon atoms or an aromatic ring having 3 to 20 carbon atoms;
- X1 and X2 are each independently selected from the group consisting of a halogen, an alkyl having 1 to 20 carbon atoms, an alkenyl having 2 to 20 carbon atoms, a cycloalkyl having 3 to 20 carbon atoms, an aryl having 6 to 20 carbon atoms, an alkylaryl having 7 to 20 carbon atoms, an arylalkyl having 7 to 20 carbon atoms, an alkylamino having 1 to 20 carbon atoms, an arylamino having 6 to 20 carbon atoms, and an alkylidene having 1 to 20 carbon atoms;
- where the cycloalkyl and aryl are optionally independently substituted with 1 to 5 substituents selected from the group consisting of a halogen, —CF3, —NO2, —OH, —SH, —CN, an alkoxy having 1 to 6 carbon atoms, an alkyl having 1 to 8 carbon atoms, an alkenyl having 2 to 8 carbon atoms, and an alkynyl having 2 to 8 carbon atoms;
- M is a Group 4 metal;
- Y is a Group 16 element;
- and
- n is an integer of 3 to 20;
- in Formulas 2 to 4,
- R10 and R11 are the same or different and are each independently selected from the group consisting of a halogen, a hydrocarbyl having 1 to 20 carbon atoms, and a hydrocarbyl having 1 to 20 carbon atoms substituted with a halogen;
- A is aluminum or boron;
- D independently represents an aryl having 6 to 20 carbon atoms or an alkyl having 1 to 20 carbon atoms in which at least one hydrogen atom is optionally substituted with a substituent, and the substituent is at least one selected from the group consisting of a halogen, a hydrocarbyl having 1 to 20 carbon atoms, an alkoxy having 1 to 20 carbon atoms and an aryloxy having 6 to 20 carbon atoms;
- H is a hydrogen atom;
- L is a neutral or cationic Lewis acid;
- W is a Group 13 element;
- and
- a is an integer of 2 or more.
Dependencies are inferred from the claim text.