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US 10,941,352 B2Granted
Processes for increasing an octane value of a gasoline component
AssigneeUop LLC
InventorsMark P. Lapinski, Michael W. Penninger, Rajeswar Gattupalli, Christopher D. DiGiulio, Bryan J. Egolf, Louis A. Lattanzio
Life of this patent
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Abstract
Processes for producing a gasoline blend in which C7 hydrocarbons are separated from a naphtha feed. The C7 hydrocarbons are isomerized and dehydrogenated to increase the octane value of the components therein. In order to avoid conversion of methylcyclohexane to toluene in the dehydrogenation reactor, the various processes provide flow schemes in which the methylcyclohexane bypasses the C7 dehydrogenation reaction zone.
Claims20
A process for producing a gasoline blend, the process comprising:
- separating a naphtha feed in a fractionation column into a stream comprising C6 and lighter boiling hydrocarbons, one or more C7 hydrocarbon streams comprising methylcyclohexane, iC7, and nC7, and a heavy stream comprising C8 hydrocarbons;
- isomerizing, in a C6 isomerization zone at isomerization conditions, at least a portion of the stream comprising C6 and lighter boiling hydrocarbons to form a C6 isomerization effluent;
- isomerizing, in a C7 isomerization zone at isomerization conditions, at least the nC7 from the one or more C7 hydrocarbon streams comprising methylcyclohexane, iC7, and nC7 to form a C7 isomerization effluent;
- dehydrogenating, in a C7 dehydrogenation zone at dehydrogenation conditions, the iC7 from the one or more C7 hydrocarbon streams comprising methylcyclohexane, iC7, and nC7 to form a C7 dehydrogenation effluent, wherein the methylcyclohexane of the one or more C7 hydrocarbon stream comprising methylcyclohexane, iC7, and nC7 bypasses the C7 dehydrogenation zone;
- reforming, in a reforming zone under reforming conditions, the heavy stream to form a reformate stream;
- and,
- blending the C6 isomerization effluent, the reformate stream, the C7 dehydrogenation effluent, and the C7 isomerization effluent to form the gasoline blend.
4 more elements
Dependencies are inferred from the claim text.