Liquid crystal composition and liquid crystal display device
AssigneeDIC Corporation
InventorsHaruki Ohishi, Kenzo Takeishi
Life of this patent
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Abstract
A composition having a high Δn, a wide temperature range of a liquid crystal phase, low viscosity, good solubility at a low temperature, high resistivity, a high voltage holding ratio, and stability against heat and light; a liquid crystal composition containing the composition, the liquid crystal composition having a good lens effect and good chemical stability; a liquid crystal display device including the liquid crystal composition; and a liquid crystal lens including the liquid crystal composition. The liquid crystal composition contains one or two or more compounds represented by general formula (i) and one or two or more compounds represented by general formula (ii).
Claims10
A liquid crystal composition comprising:
- at least two compounds represented by general formula (i):
- where in the formula, and Ri1 and Ri2 each independently represent a fluorine atom, a chlorine atom, a cyano group or an alkyl group having 1 to 12 carbon atoms, one —CH2— group or two or more non-adjacent —CH2— groups in the alkyl group are each independently optionally replaced with —CH═CH—, —C≡C—, —O—, —CO—, —COO—, or OCO—, one or two or more hydrogen atoms present in each of and Ri1 and Ri2 are each independently optionally replaced with a fluorine atom, provided that either or Ri1 and Ri2, but not both, optionally represents a substituent selected from a fluorine atom, a chlorine atom, and a cyano group,
- Zi1, Zi2, and Zi3 each independently represent a single bond, —OCH2—, —CH2O—, —C2H4—, —C4H8—, —COO—, —OCO—, —CH═CH—, —CF═CF—, —CF2O—, —OCF2—, —CF2CF2—, or —C≡C—,
- Ai1, Ai2, Ai3, Ai4, and Ai5 each independently represent a1,4-cyclohexylene group, a 1,4-phenylene group, a naphthalene-1,4-diyl group, or a naphthalene-2,6-diyl group, one or two or more hydrogen atoms in Ai1, Ai2, Ai3, Ai4 and Ai5 are each independently optionally replaced with a halogen atom or a cyano group, one or more non-adjacent —CH═ groups in Ai1, Ai2, Ai3, Ai4 and Ai5 are optionally replaced with —N═, Xi1 and Xi2 each independently represent a hydrogen atom or a fluorine atom, and
- mi1, mi2, and mi3 each independently represent 0 or 1, provided that mi1+mi2+mi3 is 0 or 1;
- and
- at least one compound represented by general formulae (C1c), and at least one compound represented by general formulae (C2d):
- where in the formulae, Rf and Rg each independently represent a linear alkyl group having 1 to 7 carbon atoms, a linear 1-alkenyl group having 2 to 7 carbon atoms, a linear 3-alkenyl group having 4 to 7 carbon atoms, a linear alkoxy group having 1 to 3 carbon atoms, or a linear alkyl group that has 1 to 5 carbon atoms and that has an end substituted with an alkoxy group having 1 to 3 carbon atoms, wherein at least one of Rf and Rg represents a linear alkyl group having 1 to 7 carbon atoms, a linear 1-alkenyl group having 2 to 7 carbon atoms, or a linear 3-alkenyl group having 4 to 7 carbon atoms,
- rings G2, H2 and 12 each independently represent a trans-1,4-cyclohexylene group, a trans-decahydronaphthalene-trans-2,6-diyl group, a 1,4-phenylene group optionally substituted with one or two fluorine atoms or a methyl group, a naphthalene-2,6-diyl group optionally substituted with one or more fluorine atoms, or a tetrahydronaphthalene-2,6-diyl group optionally substituted with one or two fluorine atoms,
- wherein when ring G2 represent aromatic rings, a 1-alkenyl group and an alkoxy group are excluded from Rf, and when ring H2 represent aromatic rings, a 1-alkenyl group and an alkoxy group are excluded from Rg,
- the total content of the compound according to general formulae (C1c) and the general formulae (C2d) is 2% or more and 60% or less with respect to all compounds in the liquid crystal composition, and
- the liquid crystal composition has a refractive index anisotropy of 0.179 or more.
Dependencies are inferred from the claim text.