Cross-linked polymeric material
AssigneeCornell University
InventorsLin Ma, Lynden Archer
Life of this patent
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Abstract
A cross-linked polymeric material is formed by polymerizing a polyethylene glycol di(meth)acrylate and a sulfonate salt containing a double bond that facilitates covalent bonding of the sulfonate salt to the polyethylene glycol di(meth)acrylate. In the polymeric material, cations from the salt are optionally replaced with metal ions selected from sodium, lithium, aluminum, magnesium, and zinc. Related methods and membranes and batteries including the cross-linked polymeric material are also provided.
Claims20
A cross-linked polymeric material formed by polymerizing a polyethylene glycol di(meth)acrylate and a sulfonate salt containing a double bond that facilitates covalent bonding of the sulfonate salt to the polyethylene glycol di(meth)acrylate, wherein, in said polymeric material, cations from the salt are replaced with metal ions selected from sodium, lithium, aluminum, magnesium, and zinc, and combinations thereof, wherein:
- (a) the sulfonate salt is vinylsulfonic acid sodium salt;
- and/or
- (b) the metal ions are lithium ions;
- and/or
- (c) the cross-linked polymeric material comprises a repeating unit of formula (I):
- wherein:
- R1 and R1′ are individually selected from hydrogen and methyl;
- R2 and R2′ are individually selected from H, Me, H,H and H,Me;
- A and A′ are individually selected from a bond, Ph, C1-6alkyl, —C(O)OC1-6alkyl, and —C(O)NHC1-6alkyl;
- M and M′ are individually selected from sodium, lithium, aluminum, magnesium, and zinc;
- m and m′ are each an integer selected from 1 to 50;
- n is an integer selected from 1 to 30;
- n′ is an integer selected from 0 to 30;
- p is an integer selected from 2 to 20;
- each * indicates a point of attachment to an adjacent polymer repeating unit;
- and
- *′ and *″ indicate a point of attachment to an adjacent polymer repeating unit, or, when R2 or R2′ is H,H or H,Me, *′ or *″, respectively, is absent.
A battery comprising a membrane, wherein the membrane comprises a cross-linked polymeric material formed by polymerizing a polyethylene glycol di(meth)acrylate and a sulfonate salt containing a double bond that facilitates covalent bonding of the sulfonate salt to the polyethylene glycol di(meth)acrylate, wherein, in said polymeric material, cations from the salt are replaced with metal ions selected from sodium, lithium, aluminum, magnesium, and zinc.
Dependencies are inferred from the claim text.