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US 10,906,023 B2Granted
Production of metal-organic frameworks
AssigneeCommonwealth Scientific and Industrial Research Organisation
InventorsMarta Rubio Martinez, Matthew Roland Hill, Michael Batten, Kok Seng Lim, Anastasios Polyzos, Timothy Raymond Barton, Trevor Deon Hadley, Andreas Alexander Monch
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Abstract
An apparatus for producing metal organic frameworks, comprising: a tubular flow reactor comprising a tubular body into which, in use, precursor compounds which form the metal organic framework are fed and flow, said tubular body including at least one annular loop.
Claims20
A process for producing metal organic frameworks, the process comprising:
- mixing at least two different precursor solutions for forming the metal organic framework (MOF) through inline mixing to form a solution mixture, the precursor solutions comprising a first precursor solution comprising at least one multidentate linking ligand in water;
- and a second precursor solution comprising a metal cluster or metallic salt thereof in water,
- introducing the solution mixture into an apparatus which comprises:
- a tubular flow reactor which comprises a tubular body having an inlet into which, in use, the solution mixture is fed and flows, said tubular body including at least one annular loop comprising a coil;
- and
- promoting a reaction within the tubular flow reactor to form the metal organic framework,
- wherein the precursor solutions are mixed through inline mixing in a feed conduit fluidly connected to the inlet of the tubular body and the resulting solution mixture being fed into said inlet,
- and wherein the solution mixture flows through said tubular body mixing the precursor compounds therein to produce the metal organic frameworks.
5 more elements
Dependencies are inferred from the claim text.