Group-IV solar cell structure using group-IV or III-V heterostructures
AssigneeThe Boeing Company
InventorsRichard R. King, Christopher M. Fetzer, Nasser H. Karam
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Abstract
Device structures, apparatuses, and methods are disclosed for photovoltaic cells that may be a single-junction or multijunction solar cells, with at least a first layer comprising a group-IV semiconductor in which part of the cell comprises a second layer comprising a III-V semiconductor or group-IV semiconductor having a different composition than the group-IV semiconductor of the first layer, such that a heterostructure is formed between the first and second layers.
Claims23
A photovoltaic cell comprising:
- at least two group-IV subcells arranged as an upper group-IV subcell and a lower group-IV subcell within a multijunction cell, wherein the upper group-IV subcell is designed to be positioned closer to a primary light source than the lower group-IV subcell, and wherein the upper group-IV subcell has a higher direct or indirect energy bandgap than the lower group-IV subcell, the upper group-IV subcell further comprising a first layer comprising a solar cell emitter layer formed from at least one group-IV semiconductor material, the solar cell emitter layer being the primary photoabsorber, the photovoltaic cell further comprising a tunnel junction formed from at least one group-IV semiconductor layer, the upper group-IV subcell and the lower group-IV subcell being interconnected in series with the tunnel junction, wherein the tunnel junction is selected from the group consisting of:
- strained or unstrained p+Ge/n+Ge tunnel junctions;
- strained or unstrained p+SiGe/n+SiGe tunnel junctions;
- strained or unstrained p+CGe/n+CGe tunnel junctions;
- strained p+SiGe/n+Ge tunnel junctions;
- p+Ge/strained n+SiGe tunnel junctions;
- strained p+CGe/n+Ge tunnel junctions;
- p+Ge/strained n+CGe tunnel junctions;
- p+SiGeSn/n+Ge tunnel junctions;
- p+Ge/n+SiGeSn tunnel junctions;
- p+CSiGeSn/n+Ge tunnel junctions;
- and
- p+Ge/n+CSiGeSn tunnel junctions,
- the upper group-IV subcell further comprising a back-surface field (BSF) layer between the solar cell emitter layer and the tunnel junction, the BSF layer being immediately adjacent the solar cell emitter layer.
A photovoltaic cell comprising:
- at least two group-IV subcells arranged as an upper group-IV subcell and a lower group-IV subcell within a multijunction cell, wherein the upper group-IV subcell is designed to be positioned closer to a primary light source than the lower group-IV subcell, and wherein the upper group-IV subcell has a higher direct or indirect energy bandgap than the lower group-IV subcell, the upper group-IV subcell further comprising a first layer comprising a solar cell emitter layer formed from at least one group-IV semiconductor material, the solar cell emitter layer being the primary photoabsorber, the photovoltaic cell further comprising a tunnel junction formed from at least one group-IV semiconductor layer, the upper group-IV subcell and the lower group-IV subcell being interconnected in series with the tunnel junction, wherein the tunnel junction comprises one or more tunnel junction semiconductors selected from the group consisting of:
- CGe and GeSn,
- the upper group-IV subcell further comprising a back-surface field (BSF) layer between the solar cell emitter layer and the tunnel junction, the BSF layer being immediately adjacent the emitter layer.
A method for energy generation comprising the step of:
- providing a photovoltaic cell comprising at least two group-IV subcells arranged as an upper group-IV subcell and a lower group-IV subcell within a multijunction cell, wherein the upper group-IV subcell is designed to be positioned closer to a primary light source than at the lower group-IV subcell, and wherein the upper group-IV subcell has a higher direct or indirect energy bandgap than the lower group-IV subcell, the upper group-IV subcell further comprising a first layer comprising a solar cell emitter layer formed from at least one group-IV semiconductor material, the solar cell emitter layer being the primary photoabsorber, the photovoltaic cell further comprising a tunnel junction formed from at least one group-IV semiconductor layer, the upper group-IV subcell and the lower group-IV subcell being interconnected in series with the tunnel junction, wherein the tunnel junction is selected from the group consisting of:
- strained or unstrained p+Ge/n+Ge tunnel junctions;
- strained or unstrained p+SiGe/n+SiGe tunnel junctions;
- strained or unstrained p+CGe/n+CGe tunnel junctions;
- strained p+SiGe/n+Ge tunnel junctions;
- p+Ge/strained n+SiGe tunnel junctions;
- strained p+CGe/n+Ge tunnel junctions;
- p+Ge/strained n+CGe tunnel junctions;
- p+SiGeSn/n+Ge tunnel junctions;
- p+Ge/n+SiGeSn tunnel junctions;
- p+CSiGeSn/n+Ge tunnel junctions;
- and
- p+Ge/n+CSiGeSn tunnel junctions,
- the upper group-IV subcell further comprises a back-surface field (BSF) layer between the solar cell emitter layer and the tunnel junction, the BSF layer being immediately adjacent the emitter layer.
Dependencies are inferred from the claim text.