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US 10,894,924 B2Granted
Multi-stage upgrading of hydrocarbon pyrolysis tar using recycled interstage product
AssigneeExxonMobil Chemical Patents Inc.
InventorsJohn S. Coleman, Kapil Kandel, Subramanya V. Nayak, Teng Xu
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Abstract
A multi-stage process is described for upgrading pyrolysis tar, such as steam cracker tar, by hydroprocessing in at least two stages. Hydroprocessing in a first stage is performed in the presence of a utility fluid. The utility fluid has a boiling point distribution from about 120° C. to about 480° C. and is separated from the first stage product.
Claims20
A hydrocarbon conversion process comprising:
- (a) hydroprocessing a feedstock comprising pyrolysis tar in a first hydroprocessing zone by contacting the feedstock with at least one hydroprocessing catalyst in the presence of a utility fluid and molecular hydrogen under catalytic hydroprocessing conditions to convert at least a portion of the feedstock to a first hydroprocessed product;
- (b) separating the first hydroprocessed product in one or more separation stages to form:
- (i) an overhead stream comprising ≥about 1.0 wt % of the first hydroprocessed product;
- (ii) a mid-cut stream comprising ≥about 20 wt % of the first hydroprocessed product and having a having a boiling point distribution from about 120° C. to about 480° C. as measured according to ASTM D7500;
- and
- (iii) a bottoms stream comprising ≥about 10 wt % of the first hydroprocessed product;
- (c) recycling at least a portion of the mid-cut stream for use as the utility fluid in the first hydroprocessing zone;
- and
- (d) hydroprocessing at least a portion of the bottoms stream in a second hydroprocessing zone by contacting the bottoms stream with at least one hydroprocessing catalyst in the presence of molecular hydrogen under catalytic hydroprocessing conditions to convert at least a portion of the bottoms stream to a second hydroprocessed product, wherein the at least a portion of the bottoms stream is hydroprocessed in the second hydroprocessing zone in the absence of any utility fluid.
6 more elements
Dependencies are inferred from the claim text.