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US 10,894,851 B2Granted
Ionic polymers and use thereof in processing of biomass
AssigneeEcole Polytechnique Federale De Lausanne (Epfl)
InventorsPaul Dyson, Zhaofu Fei, Sviatlana Siankevich, Georgios Savoglidis
Life of this patent
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Abstract
Ionic polymers (IP) are made of anions and a polymeric backbone containing cations. The ionic polymers are incorporated in membranes or attached to solid supports and use of the ionic polymers in processing of biomass.
Claims15
An ionic polymer (IP) of formula (I) consisting of anions and a polymeric backbone containing cations
- wherein
- R is selected from substituted C1-C20 alkyl and substituted C5-C10 aryl, wherein substituents are selected from the group consisting of H, —SO3H, —COOH, —[P(=O)(OH)2], —[P(=O)(OH)],—O—SO3H, —O—COOH, —O—[P(=O)(OH)2] and —O—[P(=O)(OH)];
- A is a cation selected from the group consisting of
- R1, R2, R3, R4, R5, R6 and R7 are each independently selected from the group consisting of a bond, H, C1-C6 alkyl, allyl, CH3—(CH2)n—O—(CH2)m—CH3, C1-C6 alkoxy, C1-C6 alkoxyalkyl, benzyl and —SO3H, provided that two of R1, R2, R3, R4, R5, R6 and R7 are each a bond to the polymeric backbone;
- n and m are independently selected from the group consisting of 0, 1, 2, 3, 4, 5 and 6;
- x and y are integers each independently selected within the range 1 to 1000;
- X is selected from the group consisting of F−, Cl−, Br−, I−, ClO4−, BF4 −, PF6−, AsF6−, SbF6−, NO2, NO3−, HSO4−, SO42−, PO43−, HPO42−, CF3CO2−, CF3CO3−, CO32−, CF3SO3−, C1-C6 carboxylate, CN−, SCN−, OCN−, CNO−, N3−, tosylate, mesylate, trifluoromethanesulfonate, trifluoroethane sulfonate, di-trifluoromethanesulfonyl amino, docusate and xylenesulfonate.
4 more elements
Dependencies are inferred from the claim text.