Compositions for containers and other articles and methods of using same
OwnerJeffrey Niederst, Richard H. Evans +3inventors
InventorsJeffrey Niederst, Richard H. Evans, Robert M. O'Brien, Kevin Romagnoli, Mark S. Von Maier
Life of this patent
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Abstract
This invention provides a polymer, which is preferably a polyether polymer. The polymer may be used in coating compositions. Containers and other articles comprising the polymer and methods of making such containers and other articles are also provided. The invention further provides compositions including the polymer (e.g., powder coatings), which have utility in a variety of coating end uses, including, for example, valve and pipe coatings.
Claims32
A coating composition comprising:
- at least 10 weight percent, based on total resin solids in the coating composition, of a polyether polymer that has a glass transition temperature of at least 60° C. prior to cure of the coating composition and a number average molecular weight of at least 2,000, wherein the polyether polymer does not include any structural units derived from a dihydric phenol that exhibits an estrogenic agonist activity greater than 4,4′-(propane-2,2-diyl)bis(2,6-dibromophenol) in the MCF-7 assay;
- wherein the polyether polymer is formed by reacting ingredients including:
- (i) an extender and (ii) a diepoxide compound, wherein the extender or diepoxide compound, or both, includes one or more segments of the below Formula (I):
- wherein:
- each of the oxygen atoms depicted in Formula (I) is present in an ether linkage;
- v is independently 0 to 4 when t is 0 and v is independently 0 to 3 when t is 1;
- w is 4;
- when t is 1 each of the phenylene groups depicted in Formula (I) includes at least one Hydrogen atom attached to the ring at an ortho position relative to the depicted oxygen atoms;
- each R1, if present, is an organic group, a sulfur-containing group, or any other suitable group that is substantially non-reactive with an epoxy group;
- R2, if present, is a divalent group;
- n is 0 or 1;
- with the proviso that if n is 0, the phenylene groups depicted in Formula (I) can optionally join to form a fused ring system in which case w is 3 and v is 0 to 2;
- t is 0 or 1;
- and
- two or more R1 and/or R2 groups can join to form one or more cyclic groups;
- and
- wherein the coating composition is a thermoset food or beverage can coating composition suitable for use in forming an interior food-contact coating.
A water-based coating composition comprising:
- an aqueous carrier;
- at least 10 weight percent, based on total resin solids in the coating composition, of a polyether polymer that has a glass transition temperature of at least 70° C. prior to cure of the coating composition and a number average molecular weight of at least 2,000, wherein the polyether polymer does not include any structural units derived from a dihydric phenol that exhibits an estrogenic agonist activity greater than 4,4′-(propane-2,2-diyl)bis(2,6-dibromophenol) in the MCF-7 assay;
- wherein the polyether polymer is formed by reacting ingredients including:
- (i) an extender and (ii) a diepoxide compound, wherein the extender or diepoxide compound, or both, includes one or more segments of the below Formula (I):
- wherein:
- each of the oxygen atoms depicted in Formula (I) is present in an ether linkage;
- v is independently 0 to 4 when t is 0 and v is independently 0 to 3 when t is 1;
- w is 4;
- when t is 1 each of the phenylene groups depicted in Formula (I) includes at least one Hydrogen atom attached to the ring at an ortho position relative to the depicted oxygen atoms;
- each R1, if present, is a group that is free of halogen atoms and includes at least one carbon atom;
- R2, if present, is a divalent group having an atomic weight of less than 600 Daltons that does not include any ester linkages in a backbone of R2 connecting the pair of depicted phenylene groups;
- n is 0 or 1;
- with the proviso that if n is 0, the phenylene groups depicted in Formula (I) can optionally join to form a fused ring system in which case w is 3 and v is 0 to 2;
- t is 0 or 1;
- and
- two or more R1 and/or R2 groups can join to form one or more cyclic groups;
- and
- wherein the coating composition is a thermoset food or beverage can coating composition that includes no greater than 50 weight percent of non-volatile materials and is suitable for use in forming an interior food-contact can coating.
A coating composition comprising:
- at least 10 weight percent, based on total resin solids in the coating composition, of a polyether polymer that includes one or more —CH2—CH(OH)—CH2— or —CH2—CH2—CH(OH)— segments, has a glass transition temperature of at least 70° C. prior to cure of the coating composition and has a number average molecular weight of at least 2,000, wherein the polyether polymer does not include any structural units derived from a dihydric phenol that exhibits an estrogenic agonist activity greater than 4,4′-(propane-2,2-diyl)bis(2,6-dibromophenol) in the MCF-7 assay;
- wherein the polyether polymer is formed by reacting ingredients including:
- (i) an extender and (ii) a diepoxide compound, wherein the extender or diepoxide compound, or both, includes one or more segments of the below Formula (I):
- wherein:
- each of the oxygen atoms depicted in Formula (I) is present in an ether linkage;
- v is independently 0 to 2;
- w is 4;
- each of the phenylene groups depicted in Formula (I) includes two Hydrogen atom attached to the ring at an ortho position relative to the depicted oxygen atoms;
- each R1, if present, is a group that is free of halogen atoms and includes at least one carbon atom;
- R2 is a divalent group having an atomic weight of less than 600 Daltons that does not include any ester linkages in a backbone of R2 connecting the pair of depicted phenylene groups;
- n is 1;
- t is 1;
- and
- two or more R′ and/or R2 groups can join to form one or more cyclic groups;
- and
- wherein the coating composition is a thermoset food or beverage can coating composition suitable for use in forming an interior food-contact can coating.
Dependencies are inferred from the claim text.