Cosmetic compositions which are homogenous in the bulk and capable of forming a multilayer structure after application to a keratinous material

A cosmetic composition capable of forming a multilayer structure after application to skin, the composition comprising:

• Component A which comprises about 0.01% to 50% by weight with respect to the total weight of the composition of at least one silicone- and/or hydrocarbon-containing film forming agent having at least one glass transition temperature which is lower than 60° C. and at least one first volatile oil;
• Component B which comprises about 0.01% to 90% by weight with respect to the total weight of the composition of one or more silicone compounds having a viscosity of greater than about 10 million cSt and at least one second volatile oil;
• and
• an inorganic pigment, skin active agent, skin adjuvant, or UV filter;
• wherein the weight ratio of the silicone- and/or hydrocarbon-containing film forming agent(s) in the Component A to the one or more silicone compound(s) in the Component B of about 1:1.5 to about 1:100,
• wherein, after application to the skin, the at least one first volatile oil and the at least one second volatile oil evaporate and the Component A separates from the Component B to form a multilayer structure comprising Layer A corresponding to the Component A and Layer B corresponding to the Component B on the skin, and
• wherein the cosmetic composition does not contain fluorinated compound, and wherein the Component A and the Component B are homogeneous in the bulk.