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US 10,883,057 B2Granted
Method for separating normal paraffin and isoparaffin from hydrocarbon oil
AssigneesSK Innovation Co., Ltd., SK Energy Co., Ltd.
InventorsHyeon Hui Lee, Min Su Koo, Young Bin Seo, Hye Ryun Seo, Ju Hoe Kim
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Abstract
Provided is a method for separating normal paraffin and isoparaffin from raffinates of a benzene, toluene, and xylene (BTX) reforming process including C5 to C8 light naphtha, the method including: a liquid hydrogenation process for removing olefin by feeding raffinates in which hydrogen is dissolved into a reactor filled with a hydrogenation catalyst.
Claims13
A method for separating normal paraffin and isoparaffin from raffinates of a benzene, toluene, and xylene (BTX) reforming process including C5 to C8 light naphtha, the method comprising:
- a liquid hydrogenation process for removing olefin by feeding raffinates in which hydrogen is dissolved into a reactor filled with a hydrogenation catalyst, and
- after the liquid hydrogenation process, an adsorption step for separating normal paraffin and isoparaffin is performed,
- wherein the liquid hydrogenation process is performed under conditions satisfying Equations 1 and 2 below:
- 16≤A1/A2≤35 [Equation 1]
- 1.5≤A3/A24≤2.5 [Equation 2]
- wherein in Equations 1 and 2,
- A1 is a space velocity (Hr−1) of reactants in the reactor,
- A2 is a ratio of a molar amount of dissolved hydrogen gas with respect to a molar amount of olefin in the raffinates in which hydrogen is dissolved,
- A3 is a space velocity (Hr−1) of the raffinates in which hydrogen is dissolved in the reactor, and
- the reactants in the reactor are a mixture of the raffinates in which hydrogen is dissolved and a mixture that is recycled from a downstream part of the process to said reactor of the liquid hydrogenation process.
7 more elements
Dependencies are inferred from the claim text.