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US 10,882,801 B2Granted
Methods for gas phase oxidative desulphurization of hydrocarbons using CuZnAl catalysts promoted with group VIB metal oxides
AssigneeSaudi Arabian Oil Company
InventorsOmer Refa Koseoglu, Yaming Jin, Zinfer Ismagilov, Svetlana Yashnik, Anton Salnikov, Mikhail Kerzhentsev, Valentin Parmon
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Abstract
A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide with a spinel formula, and crystals of ZnO, CuO, and at least one Group VIB metal oxide, and preferably, at least one acidic oxide of B, P, or Si, as well. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.
Claims14
A catalyst composition useful in oxidative desulfurization of a sulfur containing hydrocarbon, comprising:
- copper oxide in an amount ranging from 10 weight percent to 50 wt. %, zinc oxide in an amount ranging from 5 wt. % to less than 20 wt %, aluminum oxide in an amount ranging from 20 wt. % to 70 wt. %, and at least one Group VIB metal oxide promoter, in an amount up to 20 wt. % of said catalytic composition.
Dependencies are inferred from the claim text.