# US 10,873,200 B2 · Devices and methods comprising supercapacitor-emulating fast-charging batteries

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- Number: US 10,873,200 B2
- Document ID: US10873200B2
- Status: Granted
- Kind: B2
- Application number: 15/935,006
- Filed: 2018-03-25
- Published: 2018-07-26
- Granted: 2020-12-22
- Earliest claimed: 2016-12-15
- Assignees: StoreDot Ltd.
- Applicants: StoreDot Ltd.
- Inventors: Daniel Aronov
- Web page: https://patentgrep.com/patent/US10873200B2

## CPC

- H01M 4/134: Electrodes based on metals, Si or alloys
- H01M 4/366: {as layered products}
- H01M 4/38: of elements or alloys
- H01M 4/386: {Silicon or alloys based on silicon}
- H01M 4/387: {Tin or alloys based on tin}
- H01M 10/052: Li-accumulators
- H01M 10/0525: Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
- H01M 10/44: Methods for charging or discharging (circuits for charging H02J7/00)
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

Methods and supercapacitor-emulating fast-charging batteries are provided. Methods comprise configuring a fast-charging battery to emulate a supercapacitor with given specifications by operating the fast-charging battery only within a partial operation range which is defined according to the given specifications of the supercapacitor and is smaller than 20%, possibly 5% or 1%, of a full operation range of the fast-charging battery. Devices are provided, which comprise control circuitry and a modified fast-charging lithium ion battery having Si, Ge and/or Sn-based anode active material and designed to operate at 5 C at least and within a range of 5% at most around a working point of between 60-80% lithiation of the Si, Ge and/or Sn-based anode active material, wherein the control circuitry is configured to maintain a state of charge (SOC) of the battery within the operation range around the working point.

## Claims

### Claim 1

A device comprising control circuitry and a modified fast-charging lithium ion battery having Si, Ge and/or Sn based anode active material and designed to operate at 5 C at least and within an operation range of 5% at most around a working point of between 60-80% lithiation of the Si, Ge and/or Sn-based anode active material, wherein the control circuitry is configured to maintain a state of charge (SoC) of the battery within the operation range around the working point:
wherein the anode active material is configured to enable operation of the modified fast-charging lithium ion battery only around the working point and within the operation range;
wherein an anode of the modified fast-charging lithium ion battery comprises mechanical barriers configured to prevent full expansion of the anode material upon lithiation; and
wherein the anode material comprises composite anode material particles having shell structures which are smaller than a full expansion volume of cores of the composite anode material particles.

### Claim 2 (depends on 1)

The device of claim 1, wherein the mechanical barriers are configured to enable 80% or less of the full expansion of the anode material upon lithiation.

### Claim 3 (depends on 1)

The device of claim 1, wherein a cathode of the modified fast-charging lithium ion battery has a capacity of 80% or less than the anode.

### Claim 4 (depends on 1)

The device of claim 1, configured to operate at a voltage level of at least 3V, and have a leakage current smaller than 0.1% of a respective maximal continuous current.

### Claim 5

A fast-charging lithium ion battery having Si, Ge and/or Sn-based anode active material and operating at least at 5 C charging rate, only within an operation range of 5% at most around a working point of between 60-80% lithiation of the Si, Ge and/or Sn-based anode active material, maintaining a state of charge (SoC) of the battery within the operation range around the working point:
wherein the fast-charging lithium ion battery is modified to enable operation thereof only around the working point and within the operation range, wherein an anode of the battery comprises mechanical harriers configured to prevent full expansion of the anode material upon lithiation;
wherein the mechanic barriers are configured to enable 80% or less of the full expansion of the anode material upon lithiation; and
wherein the anode material comprises composite anode material particles having shell structures which are smaller than a full expansion volume of cores of the composite anode material particles.

### Claim 6 (depends on 5)

The fast-charging lithium ion battery of claim 5, wherein a cathode thereof has a capacity of 80% or less than an anode thereof.