# US 10,873,092 B2 · Fuel cell interconnect with reduced voltage degradation and manufacturing method

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- Number: US 10,873,092 B2
- Document ID: US10873092B2
- Status: Granted
- Kind: B2
- Application number: 15/903,363
- Filed: 2018-02-23
- Published: 2018-08-30
- Granted: 2020-12-22
- Earliest claimed: 2017-02-27
- Assignees: Bloom Energy Corporation
- Applicants: Bloom Energy Corporation
- Inventors: Sanchit Khurana; Tad Armstrong; Harald Herchen; Emily Wong; Cheng-Yu Lin
- Web page: https://patentgrep.com/patent/US10873092B2

## CPC

- H01M 8/0202: Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M 4/0471: {involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis}
- H01M 8/021: Alloys based on iron
- H01M 8/0223: Composites
- H01M 8/0228: in the form of layered or coated products
- H01M 8/12: operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M 2004/8684: {Negative electrodes}
- H01M 2004/8689: {Positive electrodes}
- H01M 2008/1293: {Fuel cells with solid oxide electrolytes}
- Y02E 60/10: Energy storage using batteries
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

A method of making an interconnect for a solid oxide fuel cell stack includes contacting an interconnect powder located in a die cavity with iron, the interconnect powder including a chromium and iron, compressing the interconnect powder to form an interconnect having ribs and fuel channels on a first side of the interconnect, such that the iron is disposed on tips of the ribs; and sintering the interconnect, such that the iron forms an contact layer on the tips of the ribs having a higher iron concentration than a remainder of the interconnect. A glass containing cathode contact layer having a glass transition temperature of 900° C. or less may be located over the rib tips on the oxidant side of the interconnect.

## Claims

### Claim 1

A fuel cell interconnect, comprising:
fuel channels at least partially defined by first ribs disposed on a first side of the interconnect;
oxidant channels at least partially defined by second ribs disposed on an opposing second side of the interconnect; and
a cathode contact layer located only over tips of the second ribs but not over the oxidant channels, the cathode contact layer comprising a conductive metal oxide and a glass material having a glass transition temperature ranging from about 450° C. to about 550° C., wherein the glass material remains viscous at all temperatures from about 400° C. to about 900° C.

### Claim 2 (depends on 1)

The interconnect of claim 1, further comprising a protective layer disposed on tips of the second ribs, wherein the cathode contact layer is disposed on the protective layer over tips of the second ribs but not over sidewalls of the second ribs or over the oxidant channels.

### Claim 3 (depends on 1)

The interconnect of claim 1, wherein:
the cathode contact layer comprises from about 4 wt % to about 10 wt % of the glass material, based on the total weight of the cathode contact layer.

### Claim 4 (depends on 1)

The interconnect of claim 1, wherein the conductive metal oxide comprises La1-xSrxMnO3, where 0.1≤x≤0.3.

### Claim 5 (depends on 1)

The interconnect of claim 1, further comprising a contact layer disposed on tips of the first ribs, the contact layer comprising from about 20 wt % to about 80 wt % iron, based on the total weight of the contact layer.

### Claim 6 (depends on 2)

A solid fuel cell stack comprising:
solid oxide fuel cells; and
interconnects of claim 2 disposed between the solid oxide fuel cells,
wherein the cathode contact layers contact cathodes of the solid oxide fuel cells.

### Claim 7 (depends on 6)

The solid fuel cell stack of claim 6, wherein the cathode contact layer of each interconnect is coated only over tips of the second ribs and the cathode contact layer contacts only portions of the cathodes that face the tips of the second ribs.

### Claim 8 (depends on 7)

The solid fuel cell stack of claim 7, wherein the cathode contact layer of each interconnect comprises discrete segments that contact only portions of the cathode that faces the tips of the second ribs.

### Claim 9 (depends on 8)

The solid fuel cell stack of claim 8, wherein the cathode contact layer of each interconnect is absent over a portion of the cathode that faces the oxidant channels.

### Claim 10 (depends on 5)

The interconnect of claim 5, wherein:
the contact layer comprises from about 20 wt % to about 80 wt % iron and from about 80 wt % to about 20 wt % chromium, based on the total weight of the contact layer; and
an iron to chromium ratio of the contact layer varies in a thickness direction of the contact layer such that the iron to chromium ratio decreases as a distance from the tips of the first ribs increases.

### Claim 11 (depends on 1)

The interconnect of claim 1, wherein the cathode contact layer of each interconnect comprises continuous discrete segments that continuously extend along the entire length of the tips of the second ribs.