# US 10,873,044 B2 · Method and apparatus for light absorption and charged carrier transport

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- Number: US 10,873,044 B2
- Document ID: US10873044B2
- Status: Granted
- Kind: B2
- Application number: 16/122,511
- Filed: 2018-09-05
- Published: 2019-01-17
- Granted: 2020-12-22
- Earliest claimed: 2007-05-23
- Assignees: University of Florida Research Foundation, Inc.
- Applicants: University of Florida Research Foundation, Inc.
- Inventors: Jiangeng Xue
- Web page: https://patentgrep.com/patent/US10873044B2

## CPC

- H10K 71/13: using printing techniques, e.g. ink-jet printing or screen printing
- H10K 30/10: comprising heterojunctions between organic semiconductors and inorganic semiconductors
- H10K 30/20: comprising organic-organic junctions, e.g. donor-acceptor junctions
- H10K 30/35: comprising inorganic nanostructures, e.g. CdSe nanoparticles
- G03F 7/0002: {Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping}
- H10K 30/50: Photovoltaic [PV] devices
- Y02E 10/549: Organic PV cells
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES
- G03F: PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR; (phototypographic composing devices B41B; photosensitive materials or processes for photographic purposes G03C; electrophotography, sensitive layers or processes therefor G03G)
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

Embodiments of the invention pertain to the use of alloyed semiconductor nanocrystals for use in solar cells. The use of alloyed semiconductor nanocrystals offers materials that have a flexible stoichiometry. The alloyed semiconductor may be a ternary semiconductor alloy, such as AxB1-xC or AB1-yCy, or a quaternary semiconductor alloy, such as AxByC1-x-yD, AxB1-xCyD1-y or ABxCyD1-x-y (where A, B, C, and D are different elements). In general, alloys with more than four elements can be used as well, although it can be much harder to control the synthesis and quality of such materials. Embodiments of the invention pertain to solar cells having a layer incorporating two or more organic materials such that percolated paths for one or both molecular species are created. Specific embodiments of the invention pertain to a method for fabricating nanostructured bulk heterojunction that facilitates both efficient exciton diffusion and charge transport. Embodiments of the subject invention pertain to a solar cell having an architecture that allows for efficient harvesting of solar energy. The organic solar cell architecture can incorporate a host/guest (or matrix/dopant) material system that utilizes the long diffusion lengths for triplet excitons without compromising light absorption efficiency.

## Claims

### Claim 1

A solar cell device, comprising:
a donor region having a donor layer made of a crystalline donor material, wherein the donor layer has a plurality of vertically aligned protrusions extending therefrom in a controlled pattern, where each protrusion has a height of about 50 nm to 200 nm and a width of about 10 nm to 100 nm, where the distance between a pair of protrusions is about 10 nm to 100 nm, wherein the crystalline donor material is a first organic material, wherein the donor region is disposed on a indium-tin-oxide anode, wherein the donor region comprises the crystalline donor material and a dopant material, wherein the donor region has the following characteristics: the dopant material has the characteristic of being able to absorb an incident photon to create a singlet exciton, a virtual photon is emitted by the dopant material that absorbed the incident photon and a host material has the characteristic of being able to absorb the virtual photon to create a triplet exciton, and the donor region has the characteristic that the triplet exciton is transported within the donor region; and
an acceptor region having an acceptor layer made of a crystalline acceptor material, wherein the acceptor layer is disposed among the plurality of protrusions of the donor layer and on top of the plurality of protrusions of the donor layer to cover the donor region, wherein the crystalline acceptor material is a second organic material, wherein the first organic material and the second organic material are different, wherein the acceptor region contacts the donor region to form a nano-structured donor-acceptor heterojunction, wherein the nano-structured donor-acceptor heterojunction, donor region, and the acceptor region have the following characteristics: the triplet exciton is transported within the donor region to the nano-structured donor-acceptor heterojunction, the triplet exciton creates a first charge and a second charge at the nano-structured donor-acceptor heterojunction, the first charge is transported away from the nano-structured donor-acceptor heterojunction in the acceptor region, and the second charge is transported away from the nano-structured donor-acceptor heterojunction in the donor region.

### Claim 2 (depends on 1)

The solar cell device according to claim 1, wherein the crystalline donor material is a phthalocyanine, a porphyrin, a derivative of a transition metal complex of a phthalocyanine, or a transition metal complex of a porphyrin.

### Claim 3 (depends on 1)

The solar cell device according to claim 1, wherein the crystalline acceptor material is a soluble derivative of a fullerene, a perylene, a naphthalene, or a nanotubule.

### Claim 4 (depends on 1)

The solar cell device according to claim 1, wherein the first organic material is a first organic semiconductor and the second organic material is a second organic semiconductor.

### Claim 5 (depends on 1)

The solar cell device according to claim 1, wherein the acceptor layer comprises up to 40% dopant material, and wherein the optical density of the acceptor region is up to 5 times higher than the optical density of a pure layer of crystalline dopant material.

### Claim 6

A solar cell device, comprising:
an acceptor region having an acceptor layer made of a crystalline acceptor material, wherein the acceptor layer has a plurality of vertically aligned protrusions extending therefrom in a controlled pattern, where each protrusion has a height of about 50 nm to 200 nm and a width of about 10 nm to 100 nm, where the distance between a pair of protrusions is about 10 nm to 100 nm, wherein the crystalline acceptor material is a first organic material, wherein the acceptor region is disposed on a indium-tin-oxide anode, wherein the acceptor region comprises crystalline acceptor material and a dopant material, wherein the acceptor region has the following characteristics: the dopant material has the characteristic of being able to absorb an incident photon to create a singlet exciton, a virtual photon is emitted by the crystalline acceptor material that absorbed the incident photon and a host material has the characteristic of being able to absorb the virtual photon to create a triplet exciton, and the acceptor region has the characteristic that the triplet exciton is transported within the acceptor region; and
a donor region having a donor layer made of a crystalline donor material, wherein the donor layer is disposed among the plurality of protrusions of the acceptor layer and on top of the plurality of protrusions of the acceptor layer to cover the acceptor region, wherein the crystalline donor material is a second organic material, wherein the first organic material and the second organic material are different, wherein the donor region contacts the acceptor region to form a nano-structured donor-acceptor heterojunction, wherein the nano-structured donor-acceptor heterojunction, donor region, and the acceptor region have the following characteristics: the triplet exciton is transported within the acceptor region to the nano-structured donor-acceptor heterojunction, the triplet exciton creates a first charge and a second charge at the nano-structured donor-acceptor heterojunction, the first charge is transported away from the nano-structured donor-acceptor heterojunction in the donor region, and the second charge is transported away from the nano-structured donor-acceptor heterojunction in the acceptor region.