# US 10,870,793 B2 · Electrically conductive proppant and methods for energizing and detecting same in a single wellbore > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,870,793 B2 - Document ID: US10870793B2 - Status: Granted - Kind: B2 - Application number: 15/498,266 - Filed: 2017-04-26 - Published: 2017-08-10 - Granted: 2020-12-22 - Earliest claimed: 2013-01-04 - Assignees: Carbo Ceramics Inc. - Applicants: Carbo Ceramics Inc. - Inventors: Chad Cannan; Lewis Bartel; Todd Roper - Web page: https://patentgrep.com/patent/US10870793B2 ## CPC - C09K 8/805: {Coated proppants} - C23C 18/1639: {Substrates other than metallic, e.g. inorganic or organic or non-conductive} - C23C 18/1889: {with use of metal first} - C23C 18/34: using reducing agents - C23C 18/40: using reducing agents - E21B 43/267: reinforcing fractures by propping - G01V 3/26: operating with magnetic or electric fields produced or modified either by the surrounding earth formation or by the detecting device (with electromagnetic waves G01V3/30) - C23C 18/1619: {Apparatus for electroless plating} - C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE - C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04) - E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS - G01V: GEOPHYSICS; GRAVITATIONAL MEASUREMENTS; DETECTING MASSES OR OBJECTS; TAGS (means for indicating the location of accidentally buried, e.g. snow-buried, persons A63B29/02) ## Abstract Electrically conductive proppant and methods for energizing and detecting the electrically conductive proppant in a single wellbore are disclosed. The methods can include performing numerical simulations solving Maxwell's equations of electromagnetism for electric and/or magnetic fields to determine temporal characteristics of an optimum input wave form and a recording sensor location to be used in a wellbore that extends into a subterranean formation having a fracture that is at least partially filled with proppant and an electrically conductive material, wherein the numerical simulations are based upon an earth model determined from geophysical logs and/or geological information. The method can also include electrically energizing a casing of the wellbore, measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses in the wellbore, and determining a location of the electrically conductive proppant through comparison of the electric and/or magnetic field responses to the numerical simulations. ## Claims ### Claim 1 A method, comprising: performing one or more numerical simulations solving Maxwell's equations of electromagnetism for electric and/or magnetic fields to determine temporal characteristics of an optimum input wave form and a recording sensor location to be used in a wellbore that extends from a surface of the earth into a subterranean formation having a fracture that is at least partially filled with proppant and an electrically conductive material, wherein the numerical simulations are based upon an earth model determined from geophysical logs and/or geological information; electrically energizing a casing of the wellbore; measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses in the wellbore; determining a location of the electrically conductive proppant through comparison of the electric and/or magnetic field responses to the numerical simulations; and analyzing the three dimensional (x, y, and z) components with imaging methods including an inversion algorithm based on Maxwell's equations for electromagnetism and/or electromagnetic holography to determine the location of the proppant. ### Claim 2 (depends on 1) The method of claim 1, wherein the inversion algorithm based on Maxwell's equations for electromagnetism comprises adjusting parameters of the earth model including proppant location within a fracture and a net electrical conductivity of the fracture. ### Claim 3 (depends on 1) The method of claim 1, wherein, in the electromagnetic holography, the electric and/or magnetic field responses and a source wave form are projected into an earth volume to form an image of a pack of the electrically conductive proppant using constructive and destructive interferences. ### Claim 4 (depends on 1) The method of claim 1, wherein electromagnetic wave forms selected from the group consisting of a Gaussian pulse, a square wave in a frequency domain, and a square wave in a time domain are used as an input signal to generate the three dimensional electric and/or magnetic field responses. ### Claim 5 A method, comprising: performing one or more numerical simulations solving Maxwell's equations of electromagnetism for electric and/or magnetic fields to determine temporal characteristics of an optimum input wave form and a recording sensor array geometry to be used in a wellbore that extends from a surface of the earth into a subterranean formation having a fracture that is at least partially filled with an electrically conductive proppant, wherein the numerical simulations are based upon an earth model determined from geophysical logs and/or geological information; electrically energizing a casing of the wellbore; measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses in the wellbore; determining a location of the electrically conductive proppant through comparison of the electric and/or magnetic field responses to the numerical simulations; and analyzing the three dimensional (x, y, and z) components with imaging methods including an inversion algorithm based on Maxwell's equations for electromagnetism and/or electromagnetic holography to determine the location of the proppant. ### Claim 6 A method, comprising: performing one or more numerical simulations solving Maxwell's equations of electromagnetism for electric and/or magnetic fields to determine temporal characteristics of an optimum input wave form and a recording sensor array geometry to be used in a wellbore that extends from a surface of the earth into a subterranean formation having a fracture that is at least partially filled with an electrically conductive proppant, wherein the numerical simulations are based upon an earth model determined from geophysical logs and/or geological information; electrically energizing a casing of the wellbore; measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses in the wellbore; and determining a location of the electrically conductive proppant through comparison of the electric and/or magnetic field responses to the numerical simulations, wherein the electrically conductive proppant comprises a coating of electrically conductive material. ### Claim 7 (depends on 6) The method of claim 6, wherein the electrically conductive material comprises aluminum, copper, nickel, and phosphorous and any alloy or mixture thereof, pyrolytic carbon, carbon black, graphite, coke breeze, carbon fiber, and carbon nanotubes and combination thereof. ### Claim 8 (depends on 6) The method of claim 6, wherein the coating of electrically conductive material is non-uniform. ### Claim 9 (depends on 8) The method of claim 8, wherein less than 95% of an outer surface of each electrically conductive proppant particle is coated with the electrically conductive material. ### Claim 10 A method, comprising: performing one or more numerical simulations solving Maxwell's equations of electromagnetism for electric and/or magnetic fields to determine temporal characteristics of an optimum input wave form and a recording sensor array geometry to be used in a wellbore that extends from a surface of the earth into a subterranean formation having a fracture that is at least partially filled with an electrically conductive proppant, wherein the numerical simulations are based upon an earth model determined from geophysical logs and/or geological information; electrically energizing a casing of the wellbore; measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses in the wellbore; and determining a location of the electrically conductive proppant through comparison of the electric and/or magnetic field responses to the numerical simulations, wherein the electrically conductive proppant is mixed with non-electrically conductive proppant to provide a proppant pack, and wherein the proppant pack comprises at least 40 wt % non-electrically conductive proppant. ### Claim 11 A method, comprising: performing one or more numerical simulations solving Maxwell's equations of electromagnetism for electric and/or magnetic fields to determine temporal characteristics of an optimum input wave form and a recording sensor array geometry to be used in a wellbore that extends from a surface of the earth into a subterranean formation having a fracture that is at least partially filled with an electrically conductive proppant, wherein the numerical simulations are based upon an earth model determined from geophysical IOU and/or geological information; electrically energizing a casing of the wellbore; measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses in the wellbore; and determining a location of the electrically conductive proppant through comparison of the electric and/or magnetic field responses to the numerical simulations, wherein the electrically conductive proppant is mixed with non-electrically conductive proppant to provide a proppant pack, and wherein the electrically conductive proppant comprises a uniform coating of electrically conductive material. ### Claim 12 A method of fracturing a subterranean formation, comprising: introducing a downhole tool comprising an energizing point and a sensor into a casing of a wellbore extending into the subterranean formation; electrically energizing the casing of the wellbore from the energizing point of the downhole tool; measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses with the sensor in the wellbore to provide a first measurement; injecting a hydraulic fluid into the wellbore at a rate and pressure sufficient to open a fracture in the subterranean formation; injecting into the fracture a fluid containing a plurality of sintered, substantially round and spherical particles, each having a coating of an electrically conductive material having a thickness of at least 10 nm formed on an outer surface of the sintered, substantially round and spherical particles, wherein less than 90% of the outer surfaces of each of the sintered, substantially round and spherical particles are coated with the electrically conductive material and wherein the electrically conductive material is nickel; forming a proppant pack of the plurality of sintered, substantially round and spherical particles inside the fracture; reintroducing the downhole tool into the wellbore extending into the subterranean formation; electrically energizing the casing of the wellbore from the energizing point of the downhole tool; measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses with the sensor in the wellbore to provide a first measurement to provide a second measurement; and determining a location of the electrically conductive proppant through comparison of the first and second measurements. ### Claim 13 A method of fracturing a subterranean formation, comprising: introducing a downhole tool comprising an energizing point and a sensor into a casing of a wellbore extending into the subterranean formation; electrically energizing the casing of the wellbore from the energizing point of the downhole tool; measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses with the sensor in the wellbore to provide a first measurement; injecting a hydraulic fluid into the wellbore at a rate and pressure sufficient to open a fracture in the subterranean formation; injecting into the fracture a fluid containing a plurality of sintered, substantially round and spherical particles, each having a coating of an electrically conductive material having a thickness of at least 10 nm formed on an outer surface of the sintered, substantially round and spherical particles; forming a proppant pack of the plurality of sintered, substantially round and spherical particles inside the fracture; reintroducing the downhole tool into the wellbore extending into the subterranean formation; electrically energizing the casing of the wellbore from the energizing point of the downhole tool; measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses with the sensor in the wellbore to provide a first measurement to provide a second measurement; determining a location of the electrically conductive proppant through comparison of the first and second measurements; prior to injecting the hydraulic fluid into wellbore, performing one or more numerical simulations solving Maxwell's equations of electromagnetism for electric and/or magnetic fields to determine temporal characteristics of an optimum input wave form and a recording sensor location to be used in the wellbore, wherein the numerical simulations are based upon an earth model determined from geophysical logs and/or geological information; and analyzing the three dimensional (x, y, and z) components with imaging methods including an inversion algorithm based on Maxwell's equations for electromagnetism and/or electromagnetic holography to determine the location of the proppant pack, wherein, in the electromagnetic holography, the electric and/or magnetic field responses and a source wave form are projected into an earth volume to form an image of proppant pack using constructive and destructive interferences. ### Claim 14 (depends on 13) The method of claim 13, wherein measuring three dimensional (x, y, and z) components of electric and/or magnetic field responses further comprises measuring an induced polarization response at or near the outer surfaces of the electrically conductive proppant.