# US 10,870,335 B2 · Humidifier having an integrated water separator for a fuel cell system, fuel cell system and vehicle comprising same

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- Number: US 10,870,335 B2
- Document ID: US10870335B2
- Status: Granted
- Kind: B2
- Application number: 16/062,032
- Filed: 2016-12-08
- Published: 2018-12-27
- Granted: 2020-12-22
- Earliest claimed: 2015-12-17
- Assignees: Audi AG; Volkswagen Aktiengesellschaft
- Applicants: Audi AG; Volkswagen AG
- Inventors: Christian Lucas; Rune Staeck
- Web page: https://patentgrep.com/patent/US10870335B2

## CPC

- B60H 3/022: {for only humidifying the air}
- H01M 8/0289: Means for holding the electrolyte (solid polymer electrolytes H01M8/1018)
- H01M 8/04149: {by diffusion, e.g. making use of membranes}
- H01M 2250/20: Fuel cells in motive systems, e.g. vehicle, ship, plane
- Y02E 60/50: Fuel cells
- Y02T 10/70: Energy storage systems for electromobility, e.g. batteries
- Y02T 10/7072: Electromobility specific charging systems or methods for batteries, ultracapacitors, supercapacitors or double-layer capacitors
- Y02T 90/14: Plug-in electric vehicles
- Y02T 90/40: Application of hydrogen technology to transportation, e.g. using fuel cells
- B60H: ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02T: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION

## Abstract

It is proposed to arrange a plurality of individual separator elements (48, 49) on the first side (40) of the membrane (38) in order to provide a humidifier (37) with integrated water separator, in particular for fuel cells (11) having a water vapor permeable membrane (38) and separator elements (48, 49) for separating water, wherein the membrane (38) on a first side (40) is in contact with a first channel (41) for a first humid gas stream, and on the second side (42) is in contact with a second channel (43) for a second, dry gas stream to be humidified, which allows an optimized exchange of moisture between the exhaust gas and operating medium streams of a fuel cell. Also provided is a fuel cell system and vehicle having the aforementioned humidifier.

## Claims

### Claim 1

A humidifier for humidifying process gases of fuel cells, the humidifier comprising:
a water vapor-permeable membrane; and
separator elements for separating water, wherein:
the water vapor-permeable membrane on a first side is in contact with a first channel for a first humid gas stream, and on a second side is in contact with a second channel for a second, dry gas stream to be humidified; and
a plurality of separate separator elements are arranged on the first side of the water vapor-permeable membrane.

### Claim 2 (depends on 1)

The humidifier according to claim 1, wherein at least a part of the separator elements is formed to receive a volume of liquid in contact with the water vapor-permeable membrane.

### Claim 3 (depends on 1)

The humidifier according to claim 1, wherein, from the first side of the water vapor-permeable membrane, a first plurality of flow webs are arranged which carry at least one or more of the separator elements, and wherein a second plurality of flow webs are arranged on the water vapor-permeable membrane on the second side, which flow webs on the second side are arranged to correspond to the flow webs on the first side.

### Claim 4 (depends on 1)

The humidifier according to claim 1, wherein at least a part of the flow webs is formed as separator elements.

### Claim 5 (depends on 1)

The humidifier according to claim 1, wherein the humidifier is a plate humidifier and the separator elements are formed to support the water vapor-permeable membrane.

### Claim 6 (depends on 1)

The humidifier according to claim 1, wherein the humidifier has a plurality of layers comprising the first channel, the second channel, and the water vapor-permeable membrane.

### Claim 7 (depends on 1)

The humidifier according to claim 1, wherein the humidifier includes a collecting container for collecting separated water, which is connected to the first channel having a discharge opening for separated liquid water, the collecting container comprising at least one of an overflow valve and a controllable drain valve.

### Claim 8 (depends on 1)

The humidifier according to claim 1, wherein the water vapor-permeable membrane is partially provided with a porous coating on the first side.

### Claim 9 (depends on 1)

The humidifier according to claim 1 wherein a height of the separator elements with respect to the water vapor-permeable membrane corresponds to a height of the first channel with respect to the water vapor-permeable membrane.

### Claim 10 (depends on 1)

The humidifier according to claim 1 wherein each of the separator elements includes a recess configured to receive separated liquid water.

### Claim 11 (depends on 1)

The humidifier according to claim 1 wherein the humidifier is external to the fuel cells, the first humid gas stream is an effluent from the fuel cells, and the second dry gas stream is an influent to the fuel cells.

### Claim 12

A fuel cell system comprising:
a fuel cell stack;
an anode supply having an anode supply path for supplying an anode operating medium to the fuel cell stack, and an anode exhaust path for discharging an anode exhaust gas from the fuel cell stack;
a cathode supply having a cathode supply path for supplying a cathode operating medium to the fuel cell stack, and a cathode exhaust path for discharging a cathode exhaust gas from the fuel cell stack; and
a humidifier arranged in either the anode supply or in the cathode supply, the humidifier comprising:
a water vapor-permeable membrane;
separator elements for separating water, wherein:
the water vapor-permeable membrane on a first side is in contact with a first channel for a first humid gas stream, and on a second side is in contact with a second channel for a second, dry gas stream to be humidified, and
a plurality of separate separator elements are arranged on the first side of the water vapor-permeable membrane; and
optionally a turbine arranged after the humidifier in a flow direction of humid exhaust air from the fuel cell stack.

### Claim 13 (depends on 12)

The fuel cell system of claim 12, wherein in the humidifier, from the first side of the water vapor-permeable membrane, a first plurality of flow webs are arranged which carry at least one or more of the separator elements, and wherein a second plurality of flow webs are arranged on the water vapor-permeable membrane on the second side, which flow webs on the second side are arranged to correspond to flow webs on the first side.

### Claim 14

A vehicle comprising:
a fuel cell stack;
a humidifier for humidifying process gases of fuel cells, the humidifier comprising:
a water vapor-permeable membrane; and
separator elements for separating water, wherein:
the water vapor-permeable membrane on a first side is in contact with a first channel for a first humid gas stream, and on a second side is in contact with a second channel for a second, dry gas stream to be humidified, and
a plurality of separate separator elements are arranged on the first side of the water vapor-permeable membrane.

### Claim 15 (depends on 14)

The vehicle of claim 14, wherein the humidifier includes a collecting container for collecting separated water, which is connected to the first channel having a discharge opening for separated liquid water.

### Claim 16

A vehicle comprising:
a fuel cell stack;
an anode supply having an anode supply path for supplying an anode operating medium to the fuel cell stack, and an anode exhaust path for discharging an anode exhaust gas from the fuel cell stack;
a cathode supply having a cathode supply path for supplying a cathode operating medium to the fuel cell stack, and a cathode exhaust path for discharging a cathode exhaust gas from the fuel cell stack; and
a humidifier arranged either in the anode supply or in the cathode supply, the humidifier comprising:
a water vapor-permeable membrane;
separator elements for separating water;
the water vapor-permeable membrane on a first side is in contact with a first channel for a first humid gas stream, and on a second side is in contact with a second channel for a second, dry gas stream to be humidified; and
a plurality of separate separator elements are arranged on the first side of the water vapor-permeable membrane.

### Claim 17 (depends on 16)

The vehicle of claim 16, wherein the humidifier includes a collecting container for collecting separated water, which is connected to the first channel having a discharge opening for separated liquid water.

### Claim 18 (depends on 16)

The vehicle of claim 16 wherein in the humidifier, from the first side of the water vapor-permeable membrane, a first plurality of flow webs are arranged which carry at least one or more of the separator elements, and wherein a second plurality of flow webs are arranged on the water vapor-permeable membrane on the second side, which flow webs on the second side are arranged to correspond to flow webs on the first side.
