# US 10,870,080 B2 · Wet desulfurization apparatus capable of improving desulfurization efficiency and wet desulfurization method using the same

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- Number: US 10,870,080 B2
- Document ID: US10870080B2
- Status: Granted
- Kind: B2
- Application number: 16/724,141
- Filed: 2019-12-20
- Published: 2020-05-07
- Granted: 2020-12-22
- Earliest claimed: 2017-12-19
- Assignees: Doosan Heavy Industries Construction Co., Ltd
- Applicants: Doosan Heavy Industries & Construction Co., Ltd.
- Inventors: In Gab Chang; Min Su Paek; Jeong Seok Yoo; Joon Ho Kim
- Web page: https://patentgrep.com/patent/US10870080B2

## CPC

- B01D 53/504: {characterised by a specific device}
- B01D 53/26: Drying gases or vapours
- B01D 53/346: {Controlling the process}
- B01D 53/505: {in a spray drying process}
- B01D 53/80: Semi-solid phase processes, i.e. by using slurries
- B01D 2251/404: of calcium
- B01D 2251/606: Carbonates
- B01D 2257/302: Sulfur oxides
- B01D 2257/80: Water
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)

## Abstract

A wet desulfurization apparatus includes a chamber enclosing a space for passing flue gas and including a tubular barrier partitioning the space into an inner chamber region having a first volume and an outer chamber region surrounding the inner chamber region and having a second volume, a flue gas inlet to introduce raw flue gas into the outer chamber region, and a flue gas outlet to discharge desulfurized flue gas from the inner chamber region; a slurry reservoir disposed under the chamber to receive and store an alkaline slurry; first and second sprayers to spray the alkaline slurry into the outer and inner chamber regions, respectively, in order to remove sulfur from the flue gas in the corresponding chamber region; and a demister disposed in the inner chamber region between the second sprayer and the flue gas outlet to remove mist from the flue gas in the inner chamber region.

## Claims

### Claim 1

A wet desulfurization apparatus comprising:
a chamber enclosing a space for passing flue gas and including a tubular barrier partitioning the space into an inner chamber region having a first volume and an outer chamber region surrounding the inner chamber region and having a second volume, a flue gas inlet configured to introduce raw flue gas into the inner chamber region, and a flue gas outlet configured to discharge desulfurized flue gas from the outer chamber region;
a slurry reservoir disposed under the chamber and configured to receive and store an alkaline slurry;
a first sprayer disposed in the inner chamber region and configured to receive the stored alkaline slurry and to spray the received alkaline slurry into the inner chamber region in order to remove sulfur (S) from the flue gas in the inner chamber region;
a second sprayer disposed in the outer chamber region and configured to receive the stored alkaline slurry and to spray the received alkaline slurry into the outer chamber region in order to remove sulfur (S) from the flue gas in the outer chamber region; and
a demister disposed in the outer chamber region between the second sprayer and the flue gas outlet and configured to remove mist from the flue gas in the outer chamber region.

### Claim 2 (depends on 1)

The wet desulfurization apparatus of claim 1, wherein the first volume is greater than the second volume.

### Claim 3 (depends on 1)

The wet desulfurization apparatus of claim 1, wherein the second volume is greater than the first volume.

### Claim 4 (depends on 1)

The wet desulfurization apparatus of claim 1, wherein the outer chamber region is configured such that the flue gas in the outer chamber region forms a descending air current that passes over the tubular barrier to form an ascending air current in the inner chamber region.

### Claim 5 (depends on 1)

The wet desulfurization apparatus of claim 1, wherein the inner chamber region is configured such that the flue gas in the inner chamber region forms a descending air current that passes over the tubular barrier to form an ascending air current in the outer chamber region.

### Claim 6 (depends on 1)

The wet desulfurization apparatus of claim 1, wherein each of the first and second sprayers includes a spray pipe communicating with the slurry reservoir and having multiple spray nozzles so as to spray the alkaline slurry supplied from the slurry reservoir.

### Claim 7 (depends on 1)

The wet desulfurization apparatus of claim 1, wherein the demister comprises:
an upper support frame fixed to an inner wall of the outer chamber region of the chamber;
a lower support frame fixed to the inner wall of the outer chamber region of the chamber; and
a plurality of corrugated plates spaced apart from each other, each corrugated plate having an upper end joined to the upper support frame and a lower end joined to the lower support frame.

### Claim 8 (depends on 7)

The wet desulfurization apparatus of claim 7, wherein the demister further comprises:
a demisting pipe communicating with the slurry reservoir; and
multiple spray nozzles disposed along the demisting pipe to spray the alkaline slurry downward in order to remove mist attached to the upper support frame, the lower support frame, and the corrugated plates.

### Claim 9 (depends on 7)

The wet desulfurization apparatus of claim 7, wherein each of the corrugated plates comprises:
a crest plate extending vertically and protruding in a first direction;
a valley plate extending vertically and protruding in a second direction opposite to the first direction;
a plate fastener extending vertically to fasten the upper end of the corrugated plate to the upper support frame and to fasten the lower end of the corrugated plate to the lower support frame; and
a plurality of coupling plates extending obliquely to couple the plate fastener to each of the crest plate and the valley plate and to couple the crest plate and the valley plate to each other.

### Claim 10 (depends on 1)

The wet desulfurization apparatus of claim 1, further comprising a slurry transfer controller for controlling an amount of the alkaline slurry being transferred from the slurry reservoir to at least one of the first sprayer, the second sprayer, and the demister.

### Claim 11 (depends on 1)

A method for removing sulfur (S) from flue gas using the wet desulfurization apparatus of claim 1, the method comprising:
introducing raw flue gas into the inner chamber region to form a descending air current of the flue gas in the inner chamber region and to form an ascending air current of the flue gas in the outer chamber region that is introduced via the inner chamber region;
first spraying the stored alkaline slurry into the inner chamber region, to remove sulfur from the flue gas forming the descending air current and having a first flow rate;
second spraying the stored alkaline slurry into the outer chamber region, to remove sulfur from the flue gas forming the ascending air current and having a second flow rate; and
removing mist from the flue gas that has undergone the second spraying.

### Claim 12 (depends on 11)

The method of claim 11, wherein the first flow rate is higher than the second flow rate.

### Claim 13 (depends on 11)

The method of claim 11, wherein the wet desulfurization apparatus further comprises a plurality of sprayers respectively communicating with the slurry reservoir and forming a multi-tiered structure arranged vertically in the outer chamber region along a flow direction of the flue gas in the outer chamber region, each sprayer configured to spray the received alkaline slurry into the outer chamber region in order to remove sulfur (S) from the flue gas in the outer chamber region, the method further comprising:
controlling an amount of the alkaline slurry being transferred from the slurry reservoir to each sprayer such that a higher-positioned sprayer of the multi-tiered structure receives more alkaline slurry than a lower-positioned sprayer of the multi-tiered structure.