# US 10,869,817 B2 · Antiperspirant stick compositions

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- Number: US 10,869,817 B2
- Document ID: US10869817B2
- Status: Granted
- Kind: B2
- Application number: 15/729,299
- Filed: 2017-10-10
- Published: 2019-04-11
- Granted: 2020-12-22
- Earliest claimed: 2017-10-10
- Assignees: Henkel IP & Holding GmbH
- Applicants: Henkel IP & Holding GmbH
- Inventors: Tyler Mikkelsen; Sofia Carolina Herrera; Nancy D. Rodgers
- Web page: https://patentgrep.com/patent/US10869817B2

## CPC

- A61K 8/0229: {Sticks}
- A61K 8/28: Zirconium; Compounds thereof
- A61K 8/342: {Alcohols having more than seven atoms in an unbroken chain}
- A61K 8/4973: {with oxygen as the only hetero atom}
- A61K 8/585: {Organosilicon compounds}
- A61K 8/86: Polyethers
- A61K 8/92: Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61Q 15/00: Anti-perspirants or body deodorants (deodorisation of air A61L9/00)
- A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D)
- A61Q: SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS

## Abstract

An antiperspirant stick composition can include a synthetic wax, a fatty alcohol, a hydrophilic surfactant having a hydrophilic-lipophilic balance (HLB) value greater than 10, a plasticizer present in an amount to minimize hardening of the composition due to contact with an aqueous composition, and an effective amount of an antiperspirant active agent. The hydrophilic surfactant can be present in an amount sufficient to minimize perspiration-induced discoloration of fabric in contact with the composition. The fatty alcohol and the antiperspirant active agent can be present at a weight ratio of from about 2:1 to about 1:2.

## Claims

### Claim 1

An antiperspirant stick composition, comprising:
1.5 wt % to 2.0 wt % of a synthetic wax;
16 wt % to 22 wt % of a fatty alcohol;
2 wt % to 10 wt % a hydrophilic surfactant having a hydrophilic-lipophilic balance (HLB) value greater than 10, said hydrophilic surfactant being present in an amount sufficient to minimize perspiration-induced discoloration of fabric in contact with the composition;
0.5 wt % to 5 wt % of the plasticizer propylene carbonate; and
14 wt % to about 20 wt % of an antiperspirant active agent, wherein the fatty alcohol and the antiperspirant active agent are present at a weight ratio of from 2:1 to 1:2,
wherein the composition includes less than 2 wt % polyethylenes having a melting point greater than or equal to 60° C.

### Claim 2 (depends on 1)

The composition of claim 1, wherein the synthetic wax has a weight average molecular weight (Mw) of from 100 g/mol to 2000 g/mol.

### Claim 3 (depends on 1)

The composition of claim 1, wherein the synthetic wax has a melting point less than or equal to about 90° C.

### Claim 4 (depends on 1)

The composition of claim 1, wherein the synthetic wax has a viscosity of from about 0.1 centipoise (cps) to about 20 cps at a temperature of 99° C.

### Claim 5 (depends on 1)

The composition of claim 1, wherein the synthetic wax has a penetration value of from about 8 decimillimeters (dmm) to about 30 dmm at 25° C.

### Claim 6 (depends on 1)

The composition of claim 1, wherein the fatty alcohol comprises a saturated or unsaturated C8-C26 fatty alcohol.

### Claim 7 (depends on 1)

The composition of claim 1, wherein the fatty alcohol comprises lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol, or a combination thereof.

### Claim 8 (depends on 1)

The composition of claim 1, wherein the hydrophilic surfactant is a non-ionic surfactant.

### Claim 9 (depends on 1)

The composition of claim 1, wherein the hydrophilic surfactant has a melting point greater than or equal to 35° C.

### Claim 10 (depends on 1)

The composition of claim 1, wherein the hydrophilic surfactant is an ethoxylated surfactant.

### Claim 11 (depends on 1)

The composition of claim 1, wherein the hydrophilic surfactant has a molecular formula of R—(OA)n—OH, where R represents a C12-C24 alkyl group, OA represents an ethylene oxide or propylene oxide group, and n represents an integer from 20 to 40.

### Claim 12 (depends on 1)

The composition of claim 1, wherein the hydrophilic surfactant and the plasticizer are present at a weight ratio of from 1:1 to 6:1 hydrophilic surfactant to plasticizer.

### Claim 13 (depends on 1)

The composition of claim 1, wherein the antiperspirant active agent is a member selected from the group consisting of aluminum chlorohydrate, aluminum chloride, aluminum hydroxide, aluminum chlorohydrex polyethylene glycol, aluminum chlorohydrex propylene glycol, aluminum dichlorohydrate, aluminum dichlorohydrex polyethylene glycol, aluminum dichlorohydrex propylene glycol, aluminum sesquichlorohydrate, aluminum sesquichlorohydrate polyethylene glycol, aluminum sesquichlorohydrate propylene glycol, aluminum-zirconium octachlorohydrate, aluminum-zirconium octachlorohydrex glycine, aluminum-zirconium pentachlorohydrate, aluminum-zirconium pentachlorohydrex glycine; aluminum-zirconium tetrachlorohydrate, aluminum-zirconium tetrachlorohydrex glycine, aluminum-zirconium trichlorohydrate, aluminum-zirconium trichlorohydrex glycine, potassium aluminum sulfate, aluminum undecylenoyl collagen amino acid, sodium aluminum lactate, aluminum sulfate, sodium aluminum chlorohydroxylactate, aluminum bromohydrate, aluminum chlorohydroxyallantoinate, zinc chloride, zinc sulfocarbolate, zinc sulfate, zirconium chlorohydrate, and combinations thereof.

### Claim 14 (depends on 1)

The composition of claim 1, further comprising a lubricant.

### Claim 15 (depends on 14)

The composition of claim 14, wherein the lubricant is a member selected from the group consisting of cyclopentasiloxane, cyclohexasiloxane, dimethylpolysiloxane, methylphenylpolysiloxane, hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, and combinations thereof.
