# US 10,865,604 B2 · Laser induced graphene coated optical fibers

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- Number: US 10,865,604 B2
- Document ID: US10865604B2
- Status: Granted
- Kind: B2
- Application number: 16/315,990
- Filed: 2016-09-30
- Published: 2019-05-09
- Granted: 2020-12-15
- Earliest claimed: 2016-09-30
- Assignees: Halliburton Energy Services, Inc.
- Applicants: Halliburton Energy Services, Inc.
- Inventors: Satyan Gopal Bhongale; Daniel Joshua Stark; Etienne Samson; Li Gao
- Web page: https://patentgrep.com/patent/US10865604B2

## CPC

- G02B 6/02395: {Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture (G02B6/02052, G02B6/02057, G02B6/024, G02B6/032, G02B6/105, G02B6/14 take precedence; coating on fibre gratings G02B6/02104; multilayer core or cladding G02B6/036; reinforcing splice joints G02B6/2558; optical cables, i.e. comprising protective structures external to the protective coating such as a jacket or plural coated optical fibres G02B6/44; coating of glass to obtain optical fibres C03C25/104)}
- E21B 17/003: {with electrically conducting or insulating means (E21B17/028 and E21B17/023 take precedence)}
- E21B 47/00: Survey of boreholes or wells (monitoring pressure or flow of drilling fluid E21B21/08)
- G01D 5/268: {using optical fibres (G01D5/28 - G01D5/38 take precedence)}
- G01N 21/00: Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light (G01N3/00 - G01N19/00 take precedence)
- G02B 6/4415: {Cables for special applications (G02B6/4429, G02B6/4439, G02B6/4479 take precedence)}
- G02B 6/443: {Protective covering}
- G02B 6/4479: {Manufacturing methods of optical cables}
- H01G 11/08: Structural combinations, e.g. assembly or connection, of hybrid or EDL capacitors with other electric components, at least one hybrid or EDL capacitor being the main component
- H01G 11/10: Multiple hybrid or EDL capacitors, e.g. arrays or modules (housings, cases, encapsulations or mountings thereof H01G11/78)
- H01G 11/36: Nanostructures, e.g. nanofibres, nanotubes or fullerenes
- H01G 11/86: specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34)
- G02B 6/02: Optical fibres with cladding {with or without a coating}
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- G01D: MEASURING NOT SPECIALLY ADAPTED FOR A SPECIFIC VARIABLE; ARRANGEMENTS FOR MEASURING TWO OR MORE VARIABLES NOT COVERED IN A SINGLE OTHER SUBCLASS; TARIFF METERING APPARATUS; MEASURING OR TESTING NOT OTHERWISE PROVIDED FOR
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)
- H01G: CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE (selection of specified materials as dielectric H01B3/00; capacitors having potential barriers H10D1/62, H10K10/10)

## Abstract

The disclosed embodiments include an optical fiber having a graphene coating, a method to apply a graphene coating onto an optical fiber, and a fiber optic cable having a graphene coating. In one embodiment, the optical fiber includes an optical core that extends along a longitudinal axis. The optical fiber also includes a carbon based coating that covers the optical core along the longitudinal axis. The optical fiber also includes a layer of graphene formed on a first surface of the carbon based coating. The layer of graphene is formed from a laser induction process that includes focusing a laser beam at the carbon based coating to photothermally convert the first surface of the carbon based coating into graphene.

## Claims

### Claim 1

An optical fiber having a graphene coating, comprising:
an optical core extending along a longitudinal axis;
a carbon based coating covering the optical core along the longitudinal axis;
a layer of graphene formed on a first surface of the carbon based coating; and
a plurality of electrical components formed on the layer of graphene.

### Claim 2 (depends on 1)

The optical fiber of claim 1, wherein the layer of graphene is formed from a laser induction process comprising focusing a laser beam at the carbon based coating to photothermally convert the first surface of the carbon based coating into the layer of graphene.

### Claim 3 (depends on 1)

The optical fiber of claim 1, wherein the plurality of electrical components form a power source to provide power to a downhole tool.

### Claim 4 (depends on 1)

The optical fiber of claim 1, wherein the plurality of electrical components form sensor components to provide measurements of a downhole environment.

### Claim 5 (depends on 4)

The optical fiber of claim 4, wherein the sensor components are operable to measure at least one of a pressure, a temperature, a resistivity, an electromagnetic field strength and direction, an acoustic field strength, a radioactive flux, water content, and a pH of the downhole environment.

### Claim 6 (depends on 1)

The optical fiber of claim 1, further comprising an intermediary layer having material properties that strengthen the optical fiber.

### Claim 7 (depends on 6)

The optical fiber of claim 6, wherein the intermediary layer has insulating or semiconducting properties that isolate the optical core from one or more electrically conductive layers.

### Claim 8 (depends on 1)

The optical fiber of claim 1, wherein the carbon based coating is formed from polyimides.

### Claim 9 (depends on 1)

The optical fiber of claim 1, wherein the layer of graphene inhibits hydrogen ions from penetrating the carbon based coating.

### Claim 10 (depends on 1)

The optical fiber of claim 1, wherein the graphene layer is electrically conductive.

### Claim 11

A fiber optic cable having a graphene coating, the fiber optic cable comprising:
a plurality of optical fibers extending along a longitudinal axis;
a carbon based coating encapsulating the plurality of optical fibers along the longitudinal axis;
a layer of graphene having conductive properties and disposed on a first surface of the carbon based coating; and
at least one layer of material disposed on a first surface of the layer of graphene.

### Claim 12 (depends on 11)

The fiber optic cable of claim 11, further comprising a plurality of electrical components formed from the layer of graphene and a first layer of the at least one layer of the material.

### Claim 13 (depends on 11)

The fiber optic cable of claim 11, wherein the layer of graphene is disposed on the first surface of the carbon based coating via a laser induction process comprising focusing a laser beam at the carbon based coating to photothermally convert carbon atoms of the carbon based coating from having an sp3 hybridization to an sp2 hybridization.

### Claim 14 (depends on 11)

The fiber optic cable of claim 11, further comprising a plurality of electrical components formed on the layer of graphene.

### Claim 15 (depends on 14)

The fiber optic cable of claim 14, wherein the plurality of electrical components form a power source to provide power to a downhole tool.

### Claim 16 (depends on 14)

The fiber optic cable of claim 14, wherein the plurality of electrical components form sensor components to provide measurements of a downhole environment.

### Claim 17 (depends on 16)

The fiber optic cable of claim 16, wherein the sensor components are operable to measure at least one of a pressure, a temperature, a resistivity, an electromagnetic field strength and direction, an acoustic field strength, a radioactive flux, water content, and a pH of the downhole environment.

### Claim 18 (depends on 11)

The fiber optic cable of claim 11, further comprising an intermediary layer having material properties that strengthen the optical fiber optic cable.

### Claim 19 (depends on 11)

The fiber optic cable of claim 11, wherein the layer of graphene inhibits hydrogen ions from penetrating the carbon based coating.

### Claim 20 (depends on 11)

The fiber optic cable of claim 11, wherein the graphene layer is electrically conductive.
