# US 10,865,525 B2 · Biopolymer sizing agents

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- Number: US 10,865,525 B2
- Document ID: US10865525B2
- Status: Granted
- Kind: B2
- Application number: 15/493,773
- Filed: 2017-04-21
- Published: 2017-11-23
- Granted: 2020-12-15
- Earliest claimed: 2016-05-03
- Assignees: Solenis Technologies, L.P.
- Applicants: Solenis Technologies, L.P.
- Inventors: Susan M Ehrhardt; Daniel F Varnell
- Web page: https://patentgrep.com/patent/US10865525B2

## CPC

- D21H 21/16: Sizing or water-repelling agents
- D21H 17/23: Lignins
- D21H 17/24: Polysaccharides
- D21H 17/25: Cellulose
- D21H 17/26: Ethers thereof
- D21H 17/27: Esters thereof
- D21H 17/28: Starch
- D21H 19/12: applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
- D21H 19/52: Cellulose; Derivatives thereof
- D21H 19/54: Starch
- D21H: PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR

## Abstract

A composition and method for imparting paper and paperboard with resistance to aqueous penetrants using renewable biopolymers, and the resulting paper and paperboard, are disclosed. The renewable biopolymers when combined with water-soluble, hydroxylated polymers or water-soluble salts and applied to the surface of paper or paperboard, results in resistance to aqueous penetrants.

## Claims

### Claim 1

A composition for treating the surface of a paper product comprising:
a water-soluble, hydroxylated polymer provided the hydroxylated polymer is not a cationic starch; and
an alkaline solution or dispersion of isolated lignin that is only soluble under alkaline conditions; wherein the composition has a pH of from about 7 to about 11; and wherein the composition is applied to the surface of the paper product providing the paper product resistance to aqueous penetrants.

### Claim 2 (depends on 1)

The composition of claim 1, wherein the water-soluble, hydroxylated polymer is selected from the group consisting of carbohydrates, modified cellulosic, and synthetic water-soluble hydroxylated polymers.

### Claim 3 (depends on 1)

The composition of claim 1, wherein the isolated lignin is a purified isolated lignin.

### Claim 4 (depends on 1)

The composition of claim 1, further comprising one or more sizing agents.

### Claim 5

A composition for treating the surface of a paper product comprising:
a. a water-soluble zirconium or aluminum salt selected from the group consisting of ammonium zirconium carbonate (AZC), ammonium zirconium sulfate, ammonium zirconium lactate, ammonium zirconium glycolate, zirconium oxynitrate, zirconium nitrate, zirconium hydroxychloride, zirconium orthosulfate, zirconium acetate, potassium zirconium carbonate, sodium aluminate, potassium aluminate and combinations thereof, and
b. an alkaline solution or dispersion of non-sulfonated lignin or lignin that is only soluble under alkaline conditions; wherein the composition has a pH of from about 7 to about 11; and wherein the composition is applied to the surface of the paper product thereby providing resistance to aqueous penetrants.

### Claim 6 (depends on 5)

The composition of claim 5, further comprising one or more sizing agents.

### Claim 7 (depends on 5)

The composition of claim 5, wherein the water-soluble zirconium or aluminum salt is added in an amount of from about 1% to about 100% based on the amount of lignin.

### Claim 8

A composition for treating the surface of a paper product comprising:
a. one or more of a sizing agent selected from the group consisting of salts of styrene maleic anhydride polymers, styrene acrylic acid polymers, ethylene acrylic acid polymers, methacrylic acid polymers, and anionic styrene acrylic latex; and
b. an alkaline solution or dispersion of isolated lignin that is only soluble under alkaline conditions; wherein the composition provides resistance to aqueous penetrants; wherein the composition has a pH of from about 7 to about 11; and the composition is applied to the surface of a paper product.

### Claim 9

A composition for treating the surface of a paper product comprising:
a water-soluble, hydroxylated polymer provided the hydroxylated polymer is not a cationic starch; and
an alkaline solution or dispersion of non-sulfonated lignin or lignin that is only soluble under alkaline conditions; and
a water-soluble zirconium or aluminum salt;
wherein the composition is applied to the surface of the paper product providing the paper product resistance to aqueous penetrants.

### Claim 10 (depends on 9)

The composition according to claim 9, wherein the zirconium or aluminum water-soluble salt is selected from the group consisting of ammonium zirconium carbonate (AZC), ammonium zirconium sulfate, ammonium zirconium lactate, ammonium zirconium glycolate, zirconium oxynitrate, zirconium nitrate, zirconium hydroxychloride, zirconium orthosulfate, zirconium acetate, potassium zirconium carbonate, sodium aluminate, potassium aluminate and combinations thereof.