# US 10,865,523 B2 · Method of producing a fibrous web containing natural and synthetic fibres > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,865,523 B2 - Document ID: US10865523B2 - Status: Granted - Kind: B2 - Application number: 16/087,693 - Filed: 2017-03-24 - Published: 2019-04-11 - Granted: 2020-12-15 - Earliest claimed: 2016-03-24 - Assignees: Paptic Oy - Applicants: Paptic Ltd - Inventors: Karita Kinnunen-Raudaskoski; Esa Torniainen; Tuomas Mustonen; Marja Juvonen - Web page: https://patentgrep.com/patent/US10865523B2 ## CPC - D21H 13/24: Polyesters - D21H 13/10: Organic non-cellulose fibres - D21H 13/26: Polyamides; Polyimides - D21H 13/36: Inorganic fibres or flakes - D21H 13/50: Carbon fibres - D21H 17/28: Starch - D21H 17/34: obtained by reactions only involving carbon-to-carbon unsaturated bonds - D21H 23/26: by selecting point of addition or moisture content of the paper - D21H 17/35: Polyalkenes, e.g. polystyrene - D21H 17/37: Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates - D21H: PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR ## Abstract The present invention relates to a method of manufacturing a fibre web which includes a fibre matrix that is comprised of natural fibres and possibly synthetic fibres. According to the present method, an aqueous, planar fibre layer is prepared from the natural fibres and possible synthetic fibres, which layer comprises an aqueous phase and a fibrous phase, and which layer is dried in order to remove the aqueous phase, in which case the natural fibres and possible synthetic fibres together form a fibre matrix. According to the present invention, binder is applied onto the water-containing fibre layer, which binder is allowed to penetrate via the aqueous phase at least partially in between the fibres, before the hydrogen bonds between the fibres form. With the present invention, it is possible to manufacture such cellulose or lignocellulose-based fibre products which have plastic-like properties, such as good fracture toughness, tear resistance and stretching. ## Claims ### Claim 1 A method of manufacturing a fibre web comprising a fibre matrix formed by natural fibres and optionally synthetic fibres, the method comprising: providing a water-containing, planar fibre layer comprised of at least one of: natural fibres or a combination of natural and synthetic fibres, which layer comprises an aqueous phase and a fibrous phase, applying onto the water-containing, planar fibre layer a binder, which is allowed to penetrate via the aqueous phase at least partially in between the fibres before removing the aqueous phase from the fibre layer and before hydrogen bonds are formed between the fibres, and drying the fibre layer in order to remove the aqueous phase, whereby the natural fibres and possible synthetic fibres together form the fibre matrix, wherein the penetration of the binder into the fibre layer, during the application or immediately thereafter, is facilitated by directing suction to the binder from the opposite side of the fibre layer to which the binder is applied. ### Claim 2 (depends on 1) The method according to claim 1, wherein the binder is applied onto the water-containing fibre layer when the dry matter percentage of the fibre layer is 10-65%. ### Claim 3 (depends on 1) The method according to claim 1, wherein the binder is applied onto the water-containing fibre layer by a contactless application method. ### Claim 4 (depends on 1) The method according to claim 1, wherein the binder is applied by using foam coating, spray coating or curtain coating. ### Claim 5 (depends on 1) The method according to claim 1, wherein the binder is applied onto the water-containing fibre layer in the form of a solution or a gel, an aqueous solution, or an aqueous dispersion. ### Claim 6 (depends on 1) The method according to claim 1, wherein a sufficient amount of binder is added to ensure that its percentage of the dry weight of the dried fibre web is 5-40%. ### Claim 7 (depends on 1) The method according to claim 1, wherein the elongation of the dried fibre web in the machine direction is at least 5% and in the cross-direction at least 5%. ### Claim 8 (depends on 1) The method according to claim 1, wherein the fibre layer is planar and is comprised of two opposite planar surfaces, in which case the binder is applied onto at least one of its planar surfaces. ### Claim 9 (depends on 1) The method according to claim 1, wherein to the binder are added substances for modifying the properties of the fibre web selected from the group consisting of pigments, fine material or nano-cellulose, synthetic fibres or plasticisers. ### Claim 10 (depends on 1) The method according to claim 1, wherein to the fibre web are brought additives for improving the mechanical and thermal properties of the fibre web. ### Claim 11 (depends on 1) The method according to claim 1, wherein the natural fibres are cellulose or lignocellulose, and the optional synthetic fibres are thermoplastic polymer fibres selected from the group consisting of polylactide, glycolic acid polymer, polyolefin, polyamide, polyethylene terephthalate, polyester, polyvinyl alcohol, and bicomponent (bico) fibres, or are regenerated cellulose fibres selected from the group consisting of viscose, rayon, Lyocell, and Tencel fibres. ### Claim 12 (depends on 1) The method according to claim 1, wherein the binder is a natural binder or a biopolymer selected from the group consisting of starch or starch modificate or derivative, chitosan, alginate, a latex binder, polyvinyl alcohol or polyvinyl acetate, and mixtures and copolymers of these binders. ### Claim 13 (depends on 1) The method according to claim 1, wherein the latex is brought onto the surface of the fibre layer in the form of a binder foam, a latex percentage of which is 10-30% by weight. ### Claim 14 (depends on 1) The method according to claim 1, wherein the water-containing, planar fibre layer comprises a combination of natural and synthetic fibres, and wherein an amount of natural fibres is 70-90 parts by weight and the synthetic fibres 10-30 parts by weight, and a grammage of the fibre web is 20-200 g/m2. ### Claim 15 (depends on 14) The method according to claim 14, wherein the web is formed at the paper machine and the binder is brought to the fibre layer at a point which is between the wire and the drying sections of the paper machine. ### Claim 16 (depends on 1) The method according to claim 1, wherein: a fibre suspension is formed of the natural fibres and optional synthetic fibres, the fibre suspension is formed into a smooth fibre layer by web-formation, and the fibre layer is dried in order to prepare the fibre matrix, the binder being applied onto the fibre layer when the dry matter percentage of the fibre layer is 20-50%. ### Claim 17 (depends on 1) The method according to claim 1, wherein the fibre web is formed by using foam forming. ### Claim 18 (depends on 1) The method according to claim 1, wherein the binder penetrates, in the z-direction of the fibre layer, from the application surface to a depth which is least 50% of the total thickness of the fibre layer, and, preferably, at least part of the binder is made to penetrate through the fibre layer. ### Claim 19 (depends on 1) The method according to claim 1, wherein the natural fibres are cellulose or lignocellulose fibres, in particular, the natural fibres are fibres which are prepared from cellulose or lignocellulose raw materials, by using chemical or semi-chemical defibering, or they are fibres prepared by using mechanical defibering. ### Claim 20 (depends on 19) The method according to claim 19, wherein the natural fibres comprise unrefined cellulose or lignocellulose fibres, wherein a freeness of the semi-chemical and mechanical fibres is at least 300 ml/min and, correspondingly, a Schopper-Riegler number of the chemical fibres is less than 35.