# US 10,865,495 B2 · Multicorrosion protection system for decorative parts with chrome finish

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- Number: US 10,865,495 B2
- Document ID: US10865495B2
- Status: Granted
- Kind: B2
- Application number: 15/762,403
- Filed: 2016-09-23
- Published: 2018-09-20
- Granted: 2020-12-15
- Earliest claimed: 2015-09-25
- Assignees: MacDermid Enthone Inc.
- Applicants: MacDermid Enthone GmbH
- Inventors: Andreas Konigshofen; Ronny Kiefer
- Web page: https://patentgrep.com/patent/US10865495B2

## CPC

- C25D 15/00: Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
- C25D 3/06: from solutions of trivalent chromium
- C25D 3/562: {containing more than 50% by weight of iron or nickel or cobalt}
- C25D 5/14: two or more layers being of nickel or chromium, e.g. duplex or triplex layers
- C25D 5/617: {Crystalline layers}
- C25D 5/619: {Amorphous layers}
- C25D 5/623: {Porosity of the layers}
- C25D 5/625: {Discontinuous layers, e.g. microcracked layers}
- C25D 5/627: {Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance}
- Y10T 428/24917: including metal layer
- C25D: PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

The invention relates to a corrosion protection layer system for metal surfaces, said layer system comprising as the two top most layers: a) a discontinuous nickel-phosphorus layer and b) a chromium layer plated from a trivalent chromium electrolyte solution, and method of producing such a corrosion protection layer system. The corrosion protection layer system provides corrosion resistance of the nickel-phosphorus layer against sodium chloride with the protection of the chromium layer produced from a trivalent process again magnesium salts, without the need for any post-treatment.

## Claims

### Claim 1

A corrosion protection layer system for metal surfaces, said layer system comprising as the two top most layers:
a) a discontinuous nickel-phosphorus layer deposited by electroplating and
b) a chromium layer over the discontinuous nickel-phosphorus, plated from a trivalent chromium electrolyte solution by electroplating,
wherein said discontinuous nickel-phosphorus layer comprises phosphorus in an amount between 2.0 wt. % and 20 wt. %, where the total weight of the nickel-phosphorus is 100 wt. %, and wherein the discontinuous nickel-phosphorus layer comprises micropores and/or microcracks between 100 and 1,000,000 micropores per cm2 and/or between 10 and 10,000 cracks per cm and wherein said discontinuous nickel-phosphorus layer comprises inorganic solids co-plated from the nickel electrolyte solution.

### Claim 2 (depends on 1)

The corrosion protection layer system according to claim 1, wherein said discontinuous nickel-phosphorus layer comprises phosphorus in an amount between 3.0 weight-% and 15.0 weight-%, where the total weight of the nickel-phosphorus layer is 100 weight-%.

### Claim 3 (depends on 2)

The corrosion protection layer system according to claim 2, wherein said discontinuous nickel-phosphorus layer comprises phosphorus in an amount between 5.0 weight-% and 12.0 weight-%, where the total weight of the nickel-phosphorus layer is 100 weight-%.

### Claim 4 (depends on 1)

The corrosion protection layer system according to claim 1, wherein said inorganic solids are chosen from the group comprising talcum, china clay, aluminum oxides, silicon oxides, titanium oxide, zirconium oxide, carbides and nitrides of silicon, boron and titanium, and mixtures thereof.

### Claim 5 (depends on 1)

The corrosion protection layer system according to claim 1, wherein said chromium layer plated from a trivalent chromium electrolyte solution comprises between 50 weight-% and 98 weight-% chromium and between 2 weight-% and 50 weight-% of an element chosen from the group consisting of C, N, O, S, P, B, Fe, Ni, Mo, Co, and mixtures thereof, wherein the weight-% adds up to 100% of the total weight of the plated chromium layer.

### Claim 6 (depends on 1)

The corrosion protection layer system according to claim 1, wherein said chromium layer plated from a trivalent chromium electrolyte solution is amorphous, crystalline, microporous, or microcracked.