# US 10,865,291 B2 · Rubber compositions containing viscosity modifier and related methods

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- Number: US 10,865,291 B2
- Document ID: US10865291B2
- Status: Granted
- Kind: B2
- Application number: 16/686,658
- Filed: 2019-11-18
- Published: 2020-03-12
- Granted: 2020-12-15
- Earliest claimed: 2015-06-11
- Assignees: Bridgestone Americas Tire Operations, LLC
- Applicants: Bridgestone Americas Tire Operations, LLC
- Inventors: Emily W. Demeter; Michael P. Singleton; Amy M. Randall
- Web page: https://patentgrep.com/patent/US10865291B2

## CPC

- C08L 7/00: Compositions of natural rubber
- B60C 1/00: Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C 1/0016: {Compositions of the tread}
- C08K 3/04: Carbon
- C08K 3/36: Silica
- C08L 9/00: Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L 9/06: Copolymers with styrene
- C08L 23/16: Ethylene-propylene or ethylene-propylene-diene copolymers
- C08L 23/22: Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
- C08L 101/00: Compositions of unspecified macromolecular compounds
- C08K 2003/2296: {of zinc}
- C08K 2201/014: Additives containing two or more different additives of the same subgroup in C08K
- C08L 91/00: Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L 2310/00: Masterbatches
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- B60C: VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)

## Abstract

Disclosed herein are rubber compositions containing a viscosity modifier and related methods such as for preparing a rubber composition containing a viscosity modifier. The viscosity modifier is an olefin copolymer and may be utilized in a neat or in an oil-extended form. Use of the olefin copolymer viscosity modifier can improve both high and low temperature E′ of the rubber composition.

## Claims

### Claim 1

A tire rubber composition comprising:
a. 100 parts of at least one rubber;
b. at least 5 phr of at least one olefin copolymer viscosity modifier having a Mn of 2,000 to 10,000 grams/mole;
c. at least one reinforcing filler in an amount of 5 to 200 phr; and
d. a cure package.

### Claim 2 (depends on 1)

The tire rubber composition of claim 1, wherein the at least one reinforcing filler comprises at least 50 phr of silica filler which is present in a majority amount by weight of the total amount of reinforcing filler and carbon black which is present in a minority amount by weight of the total amount of reinforcing filler.

### Claim 3 (depends on 2)

The tire rubber composition of claim 2, wherein the silica filler has a BET surface area of 100 to 400 m2/g.

### Claim 4 (depends on 2)

The tire rubber composition of claim 2, wherein the silica filler has a BET surface area of 100 to 220 m2/g.

### Claim 5 (depends on 2)

The tire rubber composition of claim 2, wherein the silica filler has a BET surface area of 220 to 400 m2/g.

### Claim 6 (depends on 1)

The tire rubber composition of claim 1, wherein at least a majority by weight of the at least one rubber comprises natural rubber.

### Claim 7 (depends on 1)

The tire rubber composition of claim 1, wherein at least a majority by weight of the at least one rubber comprises polyisoprene.

### Claim 8 (depends on 1)

The tire rubber composition of claim 1, wherein at least a majority by weight of the at least one rubber comprises polybutadiene.

### Claim 9 (depends on 1)

The tire rubber composition of claim 1, wherein at least a majority by weight of the at least one rubber comprises styrene-butadiene copolymer.

### Claim 10 (depends on 9)

The tire rubber composition of claim 9, wherein the styrene-butadiene copolymer is functionalized with a silica-reactive functional group.

### Claim 11 (depends on 8)

The tire rubber composition of claim 8, wherein the polybutadiene has a cis-1,4-bond content of at least 92%.

### Claim 12

A tire rubber composition comprising:
a. 100 parts of at least one rubber;
b. at least 5 phr of at least one olefin copolymer viscosity modifier having a Mn of 2,000 to 10,000 grams/mole;
c. 50 to 200 phr of reinforcing filler comprising a majority amount by weight of silica and a minority amount by weight of carbon black; and
d. a cure package.

### Claim 13 (depends on 12)

The tire rubber composition of claim 12, wherein the silica filler has a BET surface area of 100 to 220 m2/g.

### Claim 14 (depends on 12)

The tire rubber composition of claim 12, wherein the silica filler has a BET surface area of 220 to 400 m2/g.

### Claim 15 (depends on 12)

The tire rubber composition of claim 12, wherein at least a majority by weight of the at least one rubber comprises natural rubber.

### Claim 16 (depends on 12)

The tire rubber composition of claim 12, wherein at least a majority by weight of the at least one rubber comprises polyisoprene.

### Claim 17 (depends on 12)

The tire rubber composition of claim 12, wherein at least a majority by weight of the at least one rubber comprises polybutadiene.

### Claim 18 (depends on 12)

The tire rubber composition of claim 12, wherein at least a majority by weight of the at least one rubber comprises styrene-butadiene copolymer.

### Claim 19 (depends on 18)

The tire rubber composition of claim 18, wherein the styrene-butadiene copolymer is functionalized with a silica-reactive functional group.

### Claim 20 (depends on 17)

The tire rubber composition of claim 17, wherein the polybutadiene has a cis-1,4-bond content of at least 92%.

### Claim 21 (depends on 1)

A tire comprising a tire tread comprising the tire rubber composition of claim 1.

### Claim 22 (depends on 12)

A tire comprising a tire tread comprising the tire rubber composition of claim 12.
