# US 10,865,279 B2 · Methods and systems for generating aqueous polymer solutions > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,865,279 B2 - Document ID: US10865279B2 - Status: Granted - Kind: B2 - Application number: 16/441,851 - Filed: 2019-06-14 - Published: 2019-12-05 - Granted: 2020-12-15 - Earliest claimed: 2016-12-07 - Assignees: Chevron U.S.A. Inc. - Applicants: Chevron U.S.A. Inc. - Inventors: Do Hoon Kim; Dennis A. Alexis; Varadarajan Dwarakanath; David R. Espinosa; Taimur Malik; Peter G. New; Adam C. Jackson; Christopher Michael Niemi - Web page: https://patentgrep.com/patent/US10865279B2 ## CPC - C08J 3/005: {Processes for mixing polymers} - C08J 3/03: in aqueous media - C09K 8/588: characterised by the use of specific polymers {(polymeric surfactants C09K8/584)} - E21B 43/16: Enhanced recovery methods for obtaining hydrocarbons - C08J 2300/00: Characterised by the use of unspecified polymers - C08J 2333/26: Homopolymers or copolymers of acrylamide or methacrylamide - E21B 43/26: by forming crevices or fractures - C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29) - C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE - E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS ## Abstract Provided herein are liquid polymer (LP) compositions comprising a synthetic (co)polymer (e.g., an acrylamide (co)polymer), as well as methods for preparing aqueous polymer solutions by combining these LP compositions with an aqueous fluid. The resulting aqueous polymer solutions can have a concentration of a synthetic (co)polymer (e.g., an acrylamide (co)polymer) of from 50 to 15,000 ppm, and a filter ratio of 1.5 or less at 15 psi using a 1.2 μm filter. Also provided are methods of using these aqueous polymer solutions in oil and gas operations, including enhanced oil recovery. ## Claims ### Claim 1 A single-stage polymer mixing system, the system comprising: (i) a main polymer feed line diverging to a plurality of polymer supply branches; (ii) a main aqueous feed line diverging to a plurality of aqueous supply branches; and (iii) a plurality of mixer arrangements, each of which comprises an in-line mixer having a mixer inlet and a mixer outlet; wherein each of the plurality of mixer arrangements is supplied by one of the plurality of polymer supply branches and one of the plurality of aqueous supply branches; and wherein the main polymer feed line is fluidly connected to a liquid polymer (LP) supply; wherein the aqueous feed line is fluidly connected to an aqueous supply; and wherein the mixer outlet of each of the plurality of mixer arrangements is fluidly connected to at least one injection well. ### Claim 2 (depends on 1) The single-stage polymer mixing system of claim 1, wherein the main polymer feed line is fluidly connected to the plurality of polymer supply branches via a polymer distribution manifold. ### Claim 3 (depends on 2) The single-stage polymer mixing system of claim 2, wherein the polymer distribution manifold independently controls the fluid flow rate through each of the plurality of polymer supply branches. ### Claim 4 (depends on 1) The single-stage polymer mixing system of claim 1, wherein the polymer mixing system further comprises a flow control valve operably coupled to each the plurality of polymer supply branches to control fluid flow rate through each of the plurality of polymer supply branches. ### Claim 5 (depends on 1) The single-stage polymer mixing system of claim 1, wherein the polymer mixing system further comprises a flow control valve operably coupled to each the plurality of aqueous supply branches to control fluid flow rate through each of the plurality of aqueous supply branches. ### Claim 6 (depends on 1) The single-stage polymer mixing system of claim 1, wherein the in-line mixer of each of the plurality of mixer arrangements comprises a dynamic mixer. ### Claim 7 (depends on 1) The single-stage polymer mixing system of claim 1, wherein the plurality of mixer arrangements mix a liquid polymer (LP) composition provided from the liquid polymer (LP) supply and an aqueous fluid provided from the aqueous supply. ### Claim 8 (depends on 7) The single-stage mixing system of claim 7, wherein a specific mixing energy of at least 0.10 kJ/kg is applied to the LP composition and the aqueous fluid while passing through the plurality of mixer arrangements. ### Claim 9 (depends on 7) The single-stage mixing system of claim 7, wherein the LP composition and the aqueous fluid are passed through the plurality of mixer arrangements at a velocity of from 1 m/s to 4 m/s. ### Claim 10 (depends on 7) The single-stage polymer mixing system of claim 7, wherein a difference in pressure between the mixer inlet and the mixer outlet as the LP composition and the aqueous fluid are passed through each of the plurality of mixer arrangements is from 15 psi to 400 psi. ### Claim 11 (depends on 7) The single-stage polymer mixing system of claim 7, wherein the liquid polymer (LP) composition is dissolved to a concentration of from 50 to 15,000 ppm in the aqueous fluid in less than five minutes. ### Claim 12 A single-stage polymer mixing system, the system comprising: (i) a main polymer feed line diverging to a plurality of polymer supply branches; (ii) a main aqueous feed line diverging to a plurality of aqueous supply branches; and (iii) a plurality of mixer arrangements, each of which comprises a first in-line mixer having a first mixer inlet and a first mixer outlet in series with a second in-line mixer having a second mixer inlet and a second mixer outlet; wherein each of the plurality of mixer arrangements is supplied by one of the plurality of polymer supply branches and one of the plurality of aqueous supply branches; and wherein the main polymer feed line is fluidly connected to a liquid polymer (LP) supply; wherein the aqueous feed line is fluidly connected to an aqueous supply; and wherein the second mixer outlet of each of the plurality of mixer arrangements is fluidly connected to at least one injection well. ### Claim 13 (depends on 12) The single-stage polymer mixing system of claim 12, wherein the main polymer feed line is fluidly connected to the plurality of polymer supply branches via a polymer distribution manifold. ### Claim 14 (depends on 13) The single-stage polymer mixing system of claim 13, wherein the polymer distribution manifold independently controls the fluid flow rate through each of the plurality of polymer supply branches. ### Claim 15 (depends on 12) The single-stage polymer mixing system of claim 12, wherein the mixing system further comprises a flow control valve operably coupled to each the plurality of polymer supply branches to control fluid flow rate through each of the plurality of polymer supply branches. ### Claim 16 (depends on 12) The single-stage polymer mixing system of claim 12, wherein the mixing system further comprises a flow control valve operably coupled to each the plurality of aqueous supply branches to control fluid flow rate through each of the plurality of aqueous supply branches. ### Claim 17 (depends on 12) The single-stage polymer mixing system of claim 12, wherein the first in-line mixer of each of the plurality of mixer arrangements comprises a dynamic mixer and the second in-line mixer of each of the plurality of mixer arrangements comprises a static mixer. ### Claim 18 (depends on 12) The single-stage mixing system of claim 12, wherein a specific mixing energy of at least 0.10 kJ/kg is applied to a LP composition provided from the liquid polymer (LP) supply and an aqueous fluid provided from the aqueous supply while passing through the plurality of mixer arrangements.