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US 10,829,580 B2Granted
Noncovalent soft elastomer and method for manufacturing the same
AssigneeNational University Corporation Tokai National Higher Education and Research System
InventorsAtsushi Noro, Maho Ohno
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Abstract
A noncovalent soft elastomer includes a binary block copolymer composed of an A block and a B block and a solvent, wherein the B block has a noncovalent-bonding functional group, and the solvent is a nonvolatile liquid which has a property of dissolving the B block but not dissolving the A block and which forms a functional group capable of noncovalent-bonding of the B block.
Claims10
A noncovalent elastomer composition comprising:
- a block copolymer having:
- an A block that is a polymer having a glass transition temperature (Tg) of 35° C. or higher and comprises at least one selected from the group consisting of polystyrenes, polyacrylic acid esters, polymethacrylic acid esters, and polyolefins;
- a B block comprising:
- (i) at least one selected from the group consisting of polyvinylpyridines, poly(meth)acrylic acids, polyacrylamides, and polyhydroxyalkyl (meth)acrylates, or
- (ii) at least one selected from the group consisting of polystyrene derivatives, polydiene derivatives, and polyolefin derivatives, into which a functional group has been introduced, the functional group being capable of non-covalent bonding selected from hydrogen bonding, coordination bonding, and ionic bonding;
- and
- a solvent having a vapor pressure of 1 mmHg or less and having a property of dissolving the B block but not dissolving the A block, wherein the solvent is an alcohol-based solvent selected from the group consisting of (i) glycol-based solvents selected from trimers to tricontamers of alkylene glycol, and (ii) non-glycol-based solvents selected from monoalcohol-based solvents, diol-based solvents, and polyol-based solvents,
- wherein a strip specimen formed of the noncovalent elastomer composition, and having a thickness of 0.6 mm and a width of 4 mm, has a stress at 300% elongation in the range of from 0.044 MPa to 1.42 MPa.
5 more elements
Dependencies are inferred from the claim text.