Pressure-sensitive adhesive sheet
AssigneeNitto Denko Corporation
InventorsHiroki Kigami, Yasushi Buzojima, Kenta Jozuka, Midori Segawa
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Abstract
Provided is a pressure-sensitive adhesive (PSA) sheet having a low relative dielectric constant, satisfactory metal corrosion preventing property, and excellent member holding performance. The present invention provides a PSA sheet having a PSA layer including a base polymer and a rust inhibitor. The base polymer is an acrylic polymer, and monomeric components constituting the acrylic polymer comprise a (meth)acrylate having an alkyl group having 5 or more carbon atoms at an ester end at 50% by weight or more of the monomeric components. The PSA layer has a relative dielectric constant of 3 or less at 300 kHz.
Claims18
A pressure-sensitive adhesive sheet comprising a pressure-sensitive adhesive layer comprising a base polymer and a rust inhibitor, wherein:
- the base polymer is an acrylic polymer;
- monomeric components constituting the acrylic polymer comprise:
- a carboxy group-containing monomer, and
- a C5-20 alkyl (meth)acrylate at 85% by weight or more and 99% by weight or less of the monomeric components;
- the amount of the carboxy group-containing monomer among the monomeric components is more than 3% by weight,
- the monomeric components constituting the acrylic polymer include an alkyl (meth)acrylate in an amount of 85% by weight or more and 99% by weight or less of the monomeric components, and
- the alkyl (meth)acrylate is at least one monomer selected from the group consisting of pentyl (meth)acrylate, isopentyl (meth)acrylate, hexyl (meth)acrylate, heptyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, octyl (meth)acrylate, isooctyl (meth)acrylate, nonyl (meth)acrylate, and isononyl (meth)acrylate,
- the pressure-sensitive adhesive layer has a relative dielectric constant of 3 or less at 300 kHz,
- the pressure-sensitive adhesive layer is formed from a pressure-sensitive adhesive composition comprising a crosslinking agent, the crosslinking agent comprises an isocyanate-based crosslinking agent and a nonisocyanate-based crosslinking agent, the amount of the non-isocyanate-based crosslinking agent is 1/1000 or more and 1/100 or less of the amount of the isocyanate-based crosslinking agent on weight basis, and the rust inhibitor is a compound having a structure represented by the following formula (2):
- wherein, R1 is a substituent on the benzene ring, and R1 is selected from an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an aryl group having 6 to 14 carbon atoms, a carboxy group, a carboxyalkyl group having 2 to 6 carbon atoms, an amino group, a mono- or di-C1-10 alkylamino group, an amino-C1-6 alkyl group, a mono- or di-C1-10 alkylamino-C1-6 alkyl group, a mercapto group, and an alkoxycarbonyl group having 1 to 6 carbon atoms;
- n is an integer of 0 to 4, and when n is 2 or more, the n substituents R1 may be the same or different R2 is selected from a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 12 carbon atoms, an aryl group having 6 to 14 carbon atoms, an amino group, a mono- or di-C1-10 alkylamino group, an amino-C1-6 alkyl group, a mono- or di-C1-10 alkylamino-C1-6 alkyl group, a mercapto group, and an alkoxycarbonyl group having 1 to 12 carbon atoms;
- R1 and R2 may be the same or different.
Dependencies are inferred from the claim text.