# US 10,772,218 B2 · React-on-demand (ROD) fabrication method for high performance printed electronics

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- Number: US 10,772,218 B2
- Document ID: US10772218B2
- Status: Granted
- Kind: B2
- Application number: 15/723,887
- Filed: 2017-10-03
- Published: 2019-07-04
- Granted: 2020-09-08
- Earliest claimed: 2017-10-03
- Assignees: The University of Western Ontario
- Applicants: Tengyuan Zhang
- Inventors: Tengyuan Zhang; Jun Yang
- Web page: https://patentgrep.com/patent/US10772218B2

## CPC

- H05K 3/4644: {by building the multilayer layer by layer, i.e. build-up multilayer circuits (making via holes in the insulating layers H05K3/0011; special circuit boards as base or core whereon the multilayer is built H05K3/4602)}
- H05K 1/028: {Bending or folding regions of flexible printed circuits (H05K1/0283 takes precedence)}
- H05K 1/0373: {containing additives, e.g. fillers (H05K1/036 takes precedence)}
- H05K 1/092: {Dispersed materials, e.g. conductive pastes or inks}
- H05K 3/1208: {Pretreatment of the circuit board, e.g. modifying wetting properties; Patterning by using affinity patterns (providing shape patterns H05K3/1258; adhesion treatments H05K3/38)}
- B05D 1/26: performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
- B05D 3/002: {Pretreatement}
- B05D 5/12: to obtain a coating with specific electrical properties
- B05D 7/50: {Multilayers}
- B05D 7/56: {Three layers or more}
- H05K 1/0393: {Flexible materials (H05K1/038 takes precedence; specific organic compositions are classified in H05K1/0313 and subgroups)}
- H05K 3/1216: {by screen printing or stencil printing}
- H05K 3/125: {by ink-jet printing}
- H05K 3/1275: {by other printing techniques, e.g. letterpress printing, intaglio printing, lithographic printing, offset printing}
- H05K 2201/0145: Polyester, e.g. polyethylene terephthalate [PET], polyethylene naphthalate [PEN]
- H05K 2201/0154: Polyimide
- H05K 2203/0126: Dispenser, e.g. for solder paste, for supplying conductive paste for screen printing or for filling holes
- H05K 2203/1157: Using means for chemical reduction
- H05K: PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- B05D: PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL (conveying articles or workpieces through baths of liquid B65G, e.g. B65G49/02)

## Abstract

A one-step react-on-demand (RoD) method for fabricating flexible circuits with ultra-low sheet resistance, enhanced safety and durability. With the special functionalized substrate, a real-time three-dimensional synthesize of silver plates in micro scale was triggered on-demand right beneath the tip in the water-swelled PVA coating, forming a three-dimensional metal-polymer (3DMP) hybrid structure of ˜7 μm with one single stroke. The as-fabricated silver traces show an enhanced durability and ultralow sheet resistance down to 4 mΩ/sq which is by far the lowest sheet resistance reported in literatures achieved by direct writing. Meanwhile, PVA seal small particles inside the film, adding additional safety to this technology. Since neither nanomaterials nor a harsh fabrication environment are required, the proposed method remains low-cost, user friendly and accessible to end-users. the RoD approach can be extended to various printing systems, offering a particle-free, sintering-free solution for high resolution, high speed production of flexible electronics.

## Claims

### Claim 1

A react-on-demand (RoD) method of fabricating a three-dimensional electrically conductive hybrid metal-polymer structure on a substrate, the method comprising:
(i) coating the substrate with an ink-absorption coating to form an ink absorption layer on the substrate, followed by
(ii) coating the substrate with polyvinyl alcohol (PVA) solution to form a PVA layer having PVA polymers on the ink absorption layer, followed by
(iii) functionalizing the PVA layer with a first solvent containing a reducing agent and evaporating the first solvent to induce formation of crystals of the reducing agent located in between polymer chains of the PVA polymers as well as on the surface of the PVA layer, followed by
(iv) printing or writing a second solvent containing water and a metal salt onto the PVA layer wherein the second solvent dissolves the reducing agent and at the same time the reducing agent reduces the metal salt to produce metal particles to form a three-dimensional electrically conductive hybrid metal-polymer structure in which the metal particles are located on the surface of the PVA layer as well as in between the polymer chains in an interior of the PVA layer.

### Claim 2 (depends on 1)

The method of claim 1, wherein the substrate is a flexible substrate and the substrate is any one of polyimide (PI), polyethylene terephthalate film (PET), polyethylenimine (PEI), polydimethylsiloxane (PDMS) and paper.

### Claim 3 (depends on 1)

The method of claim 1, wherein the substrate is a rigid substrate and the substrate is any one of FR-4, Polyvinyl chloride (PVC), acrylonitrile butadiene styrene (ABS) and polylactic acid (PLA).

### Claim 4 (depends on 1)

The method of claim 1, wherein the PVA polymers of the PVA layer have a molecular weight in a range from 40,000 g/mol to 100,000 g/mol.

### Claim 5 (depends on 1)

The method of claim 1, wherein the concentration of the PVA solution is in a range from 10% to 30 w/v % in water.

### Claim 6 (depends on 1)

The method of claim 1, wherein the coating method of coating with said ink-absorption coating and with said polyvinyl alcohol (PVA) solution is any one of spin coating, dip-coating, spray coating and printing.

### Claim 7 (depends on 1)

The method of claim 1, wherein the reducing agent is one of ascorbic acid and glucose.

### Claim 8 (depends on 1)

The method of claim 1, wherein in the first solvent the concentration of the reducing agent is in a range from 20% to 30% w/v %.

### Claim 9 (depends on 1)

The method of claim 1, wherein the printing method is any one of inkjet printing, gravure printing, off-set printing, aerosol jet printing and screen printing.

### Claim 10 (depends on 1)

The method of claim 1, wherein the metal salt is silver nitrate.

### Claim 11 (depends on 1)

The method of claim 1, wherein the concentration of the metal salt is in a range from 0.2 g/mL to 2.0 g/mL.